Month: November 2021

Ma, HJ; Zhou, YY; Gao, T; Li, HF; Yan, PF in [Ma, Hongjian; Zhou, Yanyan; Gao, Ting; Li, Hongfeng; Yan, Pengfei] Heilongjiang Univ, Lab Funct Inorgan Mat Chem, Minist Educ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China published The role of ancillary ligand on regulating photoluminescence properties of Eu(III) helicates in 2021.0, Cited 59.0. COA of Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Three binuclear Eu3+ helicates, [Eu2(OBTA)3(H2O)3(CH3COCH3)]center dot 1.5CH3COCH3 center dot H2O (1), [Eu2(OBTA)3(Bpy)2]center dot 2CH3COCH3 center dot CH2Cl2 (2), [Eu2(OBTA)3(Phen)2]center dot 2CH3COCH3 (3) based a new bis-beta-diketone, 4,4 ‘-bis(4,4,4-trifluoro-1,3-butanedione) diphenyl ether (OBTA) was prepared in order to insight into the effects of complexes structure on Ln3+ ion emission properties. X-ray single crystal diffraction analyses confirmed the formation of binuclear triple-stranded helicates. The introduction of different ancillaries (Solvent molecular H2O and CH3COCH3; 2,2 ‘-bipyridine, Bpy and 1,10-phenanthroline, Phen) to helicates regulate the coordination environments around Eu3+ ions, and lead to the obvious variations of photophysical properties. Combination the structural analyses and photophysical experiment results, the significance of spatial tension of helicate is emphasized.

COA of Formula: C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Ma, HJ; Zhou, YY; Gao, T; Li, HF; Yan, PF or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Li, TT; Yu, RB; Zhao, DD in [Li, Tingting; Yu, Ruobing] East China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China; [Zhao, Dandan] East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China published Effective Halogen- and Phosphorus-Free Polyphenylene Ether Resin Based Flame-Retardant Foam in 2021.0, Cited 45.0. HPLC of Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

A novel halogen- and phosphorus-free intrinsic flame-retardant foam is fabricated from curable phenol-terminated polyphenylene ether resin with a high molecular weight using phenol, formaldehyde, and diphenyl ether as starting materials. The limiting oxygen index (LOI) of the pure foam is 24.90% +/- 0.28. When 0.5 wt % silica sol is added, the LOI of the foam (SPF-0.5) is up to 28.5% +/- 0.15 and both the combustion heat release rate and total combustion heat are low. Moreover, the SPF-0.5 foam exhibits high carbon residue, high compressive strength, and low pulverization rate and is superior to some previously reported phenolic foam. The flame-retardant mechanism includes the condensed-phase flame retardation and the gas-phase flame retardation, with the former being the main step, which is based on the high cross-linking density, the higher strength and smaller size of foam cells, and the formation of a carbon-silicon compound in the foam. This halogen- and phosphorous-free flame-retardant foam is also environmentally benign.

HPLC of Formula: C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Computed Properties of C12H10O. In 2019.0 APPL ORGANOMET CHEM published article about CATALYZED HECK REACTION; RECYCLABLE CATALYST; PD NANOPARTICLES; ARYL HALIDES; SUZUKI; EFFICIENT; SONOGASHIRA; LIGANDS; STABILIZATION; ETHERS in [Bahrami, Kiumars; Targhan, Homa] Razi Univ, Fac Chem, Dept Organ Chem, Kermanshah 6714967346, Iran; [Bahrami, Kiumars] Razi Univ, NNRC, Kermanshah 6714967346, Iran in 2019.0, Cited 75.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

The palladium nanoparticles were successfully stabilized with an average diameter of 6-7 nm through the coordination of palladium and terpyridine-based ligands grafted on graphene oxide surface. The graphene oxide supported palladium nanoparticles were thoroughly characterized and applied as an efficient heterogeneous catalyst in carbon-carbon (Suzuki-Miyaura, Mizoroki-Heck coupling reactions) and carbon-heteroatom (C-N and C-O) bond-forming reactions. The catalyst was simply recycled from the reaction mixture and was reused consecutive four times with small drop in catalytic activity.

Computed Properties of C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Hafnium-Doped Mesoporous Silica as Efficient Lewis Acidic Catalyst for Friedel-Crafts Alkylation Reactions WOS:000483604500094 published article about BENZYLATION; AROMATICS; DIPHENYLMETHANE; ALCOHOLS; BENZENE; ARENES in [Huang, Yao-Bing; Wang, Fei] Nanjing Forestry Univ, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Jiangsu, Peoples R China; [Huang, Yao-Bing; Luo, Yu-Jia] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China; [Huang, Yao-Bing] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94706 USA in 2019, Cited 23. Computed Properties of C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The development of an efficient solid catalyst for Friedel-Crafts (FC) reactions is of great importance to organic synthetic chemistry. Herein, we reported the hafnium-doped mesoporous silica catalyst Hf/SBA-15 and its first use for Friedel-Crafts alkylation reactions. Catalysts with different Si/Hf ratios were prepared and characterized, among which Hf/SBA-15(20) (Si/Hf = 20:1) was the most active catalyst, offering up to 99.1% benzylated product under mild reaction conditions. The influences of reaction conditions on the product were systematically investigated and compared. Pyridine-IR characterization of the catalyst showed that Lewis acid formed the primary active sites for the Friedel-Crafts alkylation reaction. X-ray photoelectron spectroscopy (XPS) characterization revealed that the electron shift from the Hf center to the silica framework resulted in a more active Lewis metal center for FC reactions. Moreover, the catalyst was successfully applied to the alkylation reaction with different alcohols and aromatic compounds. Finally, the Hf/SBA-15(20) catalyst also showed good recyclability in the recycling runs, demonstrating its high potential of being used for large scale FC reactions in the industry.

Welcome to talk about 103-50-4, If you have any questions, you can contact Huang, YB; Luo, YJ; Wang, F or send Email.. Computed Properties of C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Safety of Diphenyl oxide. Recently I am researching about BIO-OILS; PYROLYSIS; ALDEHYDES; KINETICS; THERMOCHEMISTRY; DECOMPOSITION; HYDROCARBON; SOOT, Saw an article supported by the European Union H2020 (H2020-SPIRE-04-2016) [723706]; COST Action Chemistry of smart energy carriers and technologies [CM1404]. Published in ELSEVIER SCIENCE INC in NEW YORK ,Authors: Namysl, S; Pelucchi, M; Maffei, LP; Herbinet, O; Stagni, A; Faravelli, T; Battin-Leclerc, F. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Benzaldehyde is an aromatic aldehyde commonly considered in bio-oil surrogate formulation, and an important intermediate in the oxidation of other aromatic reference fuels such as toluene. However, its oxidation has never been previously investigated experimentally and no product formation profiles were reported in the very limited pyrolysis studies available in the literature. In this study, the gas-phase oxidation of benzaldehyde was investigated in a jet-stirred reactor. 48 species were detected using gas chromatography, mainly CO, CO2 and phenol. The important formation of CO and phenol indicates a rapid formation of phenyl radicals. This was confirmed by a kinetic analysis performed using the current version of the CRECK kinetic model, in which the reactions of phenyl radicals and oxygenated aromatic compounds have been updated. (C) 2019 The Authors. Published by Elsevier Inc. on behalf of The Combustion Institute.

Safety of Diphenyl oxide. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Qian, CW; Zhu, WQ; Liu, JL; Wang, XM; Qiu, LG in [Qian, Cunwei; Zhu, Wenqian; Liu, Junlong; Wang, Xuemin; Qiu, Ligan] Yancheng Teachers Coll, Sch Chem & Environm Engn, Yancheng 224051, Peoples R China published Chitosan@Cu2O as A Facile, Efficient and Reusable Catalyst for Ligand-Free C-O and C-N Coupling in 2019.0, Cited 60.0. SDS of cas: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

The coupling reactions of phenols and nitrogen hetereocycles with aryl halide were catalyzed by a highly active, readily available and easily recoverable heterogeneous Cu catalyst which was prepared by simply stirring an suspension of chitosan in solvent with copper compound. The result showed that chitosan@Cu2O catalyst catalyzed the coupling reactions of aryl halides with phenols and nitrogen hetereocycles to readily give the corresponding products in moderate to excellent yields. The highly active catalyst can be reused many times without losing its catalytic activity.

Welcome to talk about 101-84-8, If you have any questions, you can contact Qian, CW; Zhu, WQ; Liu, JL; Wang, XM; Qiu, LG or send Email.. SDS of cas: 101-84-8

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recently I am researching about ACETIC-ACID; NANOCLUSTER NUCLEATION; OXIDE NANOPARTICLES; ETHYLENE-GLYCOL; GROWTH; SURFACE; ADSORPTION; CRYSTALLIZATION; HYDROGENATION; DECOMPOSITION, Saw an article supported by the ETH ZurichETH Zurich; Swiss National Science FoundationSwiss National Science Foundation (SNSF)European Commission [200021_165888]. Published in SPRINGER in NEW YORK ,Authors: Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Formula: C14H14O

Benzyl alcohol is a versatile reaction medium for the synthesis of different types of nanoparticles. Its ability to act as an oxygen source gave access to metal oxide nanoparticles, while its reducing properties can be harnessed for the preparation of metals. Here we report the synthesis of Pd and PdCu nanoparticles in benzyl alcohol supplemented by a detailed mechanistic study for both systems. To elucidate the chemical formation mechanism of the Pd nanoparticles, we performed in situ attenuated total reflection ultraviolet-visible (ATR-UV-vis) and Fourier transform infrared spectroscopy (ATR-FTIR), providing information on the organic as well as on the inorganic side of the reaction. Potential gaseous products were analyzed by in situ gas chromatography (GC) and mass spectrometry (MS). We observed the formation of benzaldehyde, toluene, and dibenzyl ether as the three main organic products. The formation of the PdCu alloy nanoparticles was studied by ex situ powder X-ray diffraction (PXRD). A time-resolved study of the synthesis at 100 degrees C indicated that initially three types of particles formed, composed of an alloy with high Pd content, an alloy with high content of copper, and palladium particles, and only later in the reaction course they transformed into an alloy with a Pd-to-Cu ratio close to 1. [GRAPHICS] .

Formula: C14H14O. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Thermo-kinetics and gaseous product analysis of banana peel pyrolysis for its bioenergy potential WOS:000459461800021 published article about TG-FTIR; ENERGY-BALANCE; BEHAVIOR; BIOMASS; WASTE; COMBUSTION; DEGRADATION; TEMPERATURE; PERFORMANCE; CELLULOSE in [Tahir, Mudassir Hussain] Univ Sci & Technol China, Dept Polymer Sci & Engn, CAS Key Lab Soft Matter Chem, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China; [Zhao, Zilong] Harbin Inst Technol Shenzhen, Sch Civil & Environm Engn, Grad Sch, Shenzhen 518055, Peoples R China; [Ren, Jianmin] Chongqing Technol & Business Univ, Coll Environm & Resource, Chongqing 400067, Peoples R China; [Rasool, Tanveer] Natl Inst Technol, Dept Chem Engn, Srinagar, Jammu & Kashmir, India; [Naqvi, Salman Raza] Natl Univ Sci & Technol, Sch Chem & Mat Engn, H-12, Islamabad, Pakistan in 2019, Cited 41. Product Details of 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

This study illustrated the pyrolysis of banana peel (BP) as a potential waste management solution. Samples were characterized through Fourier transform infrared spectrometry (FTIR), elemental analysis, and high heating value (HHV) calculation. After pyrolysis experiments were performed at different heating rates (10, 20, 30, and 40 degrees C min(-1)) by using a thermogravimetric analyzer coupled with FTIR (TG-FTIR), the apparent activation energies were computed with Friedman, Kissinger-Akahira-Sunose (KAS), and Flynn-Wall-Ozawa (FWO) methods, and the evolved gaseous products were analyzed simultaneously. During pyrolysis, BP underwent three devolatilization steps accompanied by the evolution of some major gaseous products, including CO2, CH4, H2O, CH3COOH, C=C, C6H5OH, HCOOH, and CH3CH2OH. Among them, C=C, CH3COOH, and CO2 accounted for approximately 71.56% of the total gaseous products. Gas evolution was more significantly influenced by the pyrolysis temperature than by the heating rate. Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) analysis confirmed the presence of some high-energy compounds and valuable chemicals containing aromatic, aldehyde, ketone, and other functional groups. In terms of preliminary energy balance, more than 70% of the total energy output was attributed to the liquid pyrolytic products followed by the solid and gaseous products. The energy recovery ratio of BP pyrolysis was superior to that of other fuel feedstocks. This work provided insights into resolving environmental problems associated with BP management by pyrolyzing BP as a potential source of renewable bioenergy.

Welcome to talk about 103-50-4, If you have any questions, you can contact Tahir, MH; Zhao, ZL; Ren, JM; Rasool, T; Naqvi, SR or send Email.. Product Details of 103-50-4

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Application In Synthesis of Benzyl ether. I found the field of Energy & Fuels; Engineering very interesting. Saw the article Dissociation behaviors of coal-related model compounds in ionic liquids published in 2019, Reprint Addresses Lei, ZP; Shui, HF (corresponding author), Anhui Univ Technol, Sch Chem & Chem Engn, Anhui Prov Key Lab Coal Clean Convers & High Valu, Maanshan 243002, Anhui, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

Ionic liquids have demonstrated to be promising solvents for processing coal and biomass. Aiming to exploit ionic liquids (ILs) as media for degradation of coal, diphenylmethane (DPM), diphenyl ether (DPE), and diphenyl ketone (DPK) were used as coal-related compounds to study the degradation behaviors of weak-bond structures of coal in ionic liquids in this work. It was found that 1-sulfonic acid butyl-3-methylimidazolium 14 trifluoromethanesulfonate ([B(SO3H)mim]OTf), 1-ethyl-3-methylimidazolium acetate ([Emim]Ac) and 1-butyl-3-methyl-imidazolium chloride ([Bmim] Cl) have a significant effect on the thermal dissociation of the model compounds. [B(SO3H) mim] OTf has a significant effect on the cleavage of DPM and DPK. [Bmim] Cl promotes the cleavage of the DPE. The dissociation effect of the model compound under the action of ionic liquid increases with the increase of reaction temperature. The interaction between the oxygen-containing functional groups in the model compound promotes the respective thermal dissociation of the model compounds. Ionic liquids promote the dissociation interaction of bridge bonds in model compounds. Under the action of ionic liquids, the carbonyl bond promotes the cleavage of the methylene and ether bond cleavage, and the ether bond promotes the methylene bond cleavage.

Application In Synthesis of Benzyl ether. Welcome to talk about 103-50-4, If you have any questions, you can contact Lei, ZP; Dong, L; Kang, SG; Huang, YQ; Li, ZK; Yan, JC; Shui, HF; Wang, ZC; Ren, SB; Pan, CX or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Padervand, M; Lichtfouse, E; Robert, D; Wang, CY in [Padervand, Mohsen; Wang, Chuanyi] Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Peoples R China; [Padervand, Mohsen] Univ Maragheh, Fac Sci, Dept Chem, Maragheh, Iran; [Lichtfouse, Eric] Aix Marseille Univ, CNRS, IRD, INRAE,Coll France,CEREGE, F-13100 Aix En Provence, France; [Robert, Didier] Univ Lorraine, ICPEES, 12 Rue Victor Demange, F-57500 St Avold, France published Removal of microplastics from the environment. A review in 2020.0, Cited 123.0. Computed Properties of C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

The production of fossil fuel-derived, synthetic plastics is continually increasing, while poor plastic waste management has recently induced severe pollution issues. Microplastics are plastic particles smaller than 5 mm. Microplastics are ubiquitous and slowly-degrading contaminants in waters and soils. Microplastics have long residence time, high stability, high potential of being fragmented and can adsorb other contaminants. Many aquatic species contain microplastics, which are in particular easily accumulated by planktonic and invertebrate organisms. Then, microplastics are transferred along food chains, leading to physical damages, decrease in nutritional diet value and exposure of the living organism to pathogens. Raw plastics contain chemical additives such as phthalates, bisphenol A and polybrominated diphenyl ethers that may induce toxic effects after ingestion by living organisms. Furthermore, the adsorption capability of microplastics makes them prone to carry several contaminants. Methods to remove microplastics from water and other media are actually needed. Here, we review microplastics occurrence, transport, raw polymers and additives, toxicity and methods of removal. Removal methods include physical sorption and filtration, biological removal and ingestion, and chemical treatments. Mechanisms, efficiency, advantages, and drawbacks of various removal methods are discussed.

Computed Properties of C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Padervand, M; Lichtfouse, E; Robert, D; Wang, CY or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem