Month: January 2022

An article Novel mesoporous TiO2(B) whisker-supported sulfated solid superacid with unique acid characteristics and catalytic performances WOS:000460831500003 published article about BIODIESEL PRODUCTION; ZIRCONIA CATALYSTS; SURFACE-STRUCTURE; CRYSTAL PHASE; CO ADSORPTION; TIO2-B 100; TITANIA; ESTERIFICATION; NANOCOMPOSITES; CONDENSATION in [Li, Licheng; Yue, Haiqin; Wang, Lei; She, Jie; Gu, Xiaoli; Li, Xiaobao] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China; [Ji, Tuo] Univ Akron, Dept Chem & Biomol Engn, Akron, OH 44325 USA; [Li, Wei] Aston Univ, Aston Inst Mat Res, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England; [Zhao, Xuejuan] Nanjing Inst Technol, Sch Mat Engn, Nanjing 211167, Jiangsu, Peoples R China; [Li, Licheng; Li, Wei] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China; [Wang, Lei] CNOOC Changzhou Paint & Coatings Ind Res Inst Co, Changzhou 213016, Jiangsu, Peoples R China in 2019, Cited 66. Safety of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Mesoporous TiO2(B) whisker was firstly applied as a support for synthesizing the novel sulfated solid superacid (SO42-/TiO2(B)). According to NH3-TPD, TG and Py-IR characterization results, it was found that the similar amount of sulfate group on TiO2(B) and anatase showed significantly different acid characteristics and catalytic performances. The total acid amount of SO42-/TiO2(B) was about 1.8 times as anatase-supported sulfated solid superacid (SO42-/Anatase). Simultaneously, the SO42-/TiO2(B) possessed higher percentage of Bronsted acid and more weak-medium acid strength than SO42-/Anatase. These acidic properties endowed SO42-/TiO2(B) with the increased esterification reaction rate and decreased alkylation byproduct selectivity compared with that of SO42-/Anatase. Structure-performance analysis exhibited that there were more bridged bidentate sulfate groups coordinated to the TiO2(B) in SO42-/TiO2(B), which could induce more Ti cations than that of the chelating one. This was the key factor to be responsible for the unique acid characteristics of SO42-/TiO2(B). The present work provides a novel solid superacid and might open a strategy to mediate the acid characteristic for sulfated solid superacid.

Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.. Safety of Benzyl ether

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Cleavage of ethers and demethylation of lignin in acidic concentrated lithium bromide (ACLB) solution WOS:000589891500027 published article about MOLTEN-SALT HYDRATE; LIGNOCELLULOSIC BIOMASS; VANILLIC ACID; ARYL ETHERS; WOOD; DEPOLYMERIZATION; CONVERSION; DEFICIENT; METHOXYL; GUAIACOL in [Li, Zheng; Sutandar, Eka; Goihl, Thomas; Pan, Xuejun] Univ Wisconsin, Dept Biol Syst Engn, 460 Henry Mall, Madison, WI 53704 USA; [Zhang, Xiao] Washington State Univ, Sch Chem Engn & Bioengn, 2710 Univ Dr, Richland, WA 99354 USA in 2020.0, Cited 59.0. Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

The methoxyl group is the most abundant functional group of lignin and affects the properties, reactivity, and application of lignin. Efficient demethylation is always of interest in the area of lignin chemistry and application. This study demonstrated a new method for cleaving ether compounds and demethylating lignin in acidic concentrated lithium bromide (ACLB) solution under mild conditions. It was found that the ACLB system could universally cleave ether compounds except for diaryl ethers. The study on lignin model compounds (creosol, syringol, and 1,2,3-trimethoxybenzene) verified that ACLB could demethylate them to corresponding phenols. Four real lignin samples produced from various sources by different methods were also efficiently demethylated by 69-82% in ACLB. The lignin demethylation resulted in more phenolic hydroxyl groups, which benefits some downstream applications of lignin. This study also provided new insights into the cleavage of the ether bonds in lignin. In addition to the methyl-aryl ether bond, ACLB could cleave other ether bonds of lignin in beta-O-4, beta-5, and beta-beta structures except for the 4-O-5 bond in the diphenyl structure. The ether bonds were cleaved via the S(N)2 substitution except for the beta-O-4 bond, which was primarily cleaved via the benzyl cation and enol ether intermediates, leading to Hibbert’s ketones. Some of the beta-O-4 structures were transformed into benzodioxane (BD) structures, which were stable in the ACLB system.

Formula: C12H10O. About Diphenyl oxide, If you have any questions, you can contact Li, Z; Sutandar, E; Goihl, T; Zhang, X; Pan, XJ or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Liu, SJ; Bai, LC; van Muyden, AP; Huang, ZJ; Cui, XJ; Fei, ZF; Li, XH; Hu, XL; Dyson, PJ in [Liu, Sijie; van Muyden, Antoine P.; Huang, Zhangjun; Cui, Xinjiang; Fei, Zhaofu; Dyson, Paul J.] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn ISIC, CH-1015 Lausanne, Switzerland; [Liu, Sijie; Li, Xuehui] South China Univ Technol, State Key Lab Pulp & Paper Engn, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China; [Bai, Lichen; Hu, Xile] Ecole Polytech Fed Lausanne, LSCI, ISIC, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland published Oxidative cleavage of -O-4 bonds in lignin model compounds with a single-atom Co catalyst in 2019.0, Cited 48.0. Recommanded Product: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Single-atom catalysts are emerging as primary catalysts for many reactions due to their 100% utilization of active metal centers leading to high catalytic efficiencies. Herein, we report the use of a single-atom Co catalyst for the oxidative cleavage of the -O-4 bonds of lignin model compounds at a low oxygen pressure. Under the optimized reaction conditions, the conversion of 2-(2-methoxyphenoxy)-1-phenylethanol up to 95% with high selectivities was achieved with a variety of substrates investigated. The reusability of the Co catalyst with a high catalytic efficiency indicates its potential application in the oxidative cleavage of C-O bonds.

Recommanded Product: 101-84-8. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. Recently I am researching about C-H CYANATION; ARYL NITRILES; CONVERSION; DERIVATIVES; AMIDES; AMIDATION; CATALYST; ANALOGS; ESTERS, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [JP15K05418]; Ministry of Education, Culture, Sports, Science, and Technology in JapanMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT). Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Uchida, K; Togo, H. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Various aromatic nitriles could be obtained in good yields by the treatment of aryl bromides with n-butyllithium and then pivalonitrile, followed by the treatment with molecular iodine at 70 degrees C, without metal cyanides under transition-metal-free conditions. The present reaction proceeds through the radical beta-elimination of imino-nitrogen-centered radicals formed from the reactions of imines and N-iodoimines under warming conditions. (c) 2019 Elsevier Science. All rights reserved. (C) 2019 Elsevier Ltd. All rights reserved.

Recommanded Product: Diphenyl oxide. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2020 J ELECTROANAL CHEM published article about CATALYSTS; IDENTIFICATION; OXIDATION in [Tang, Fei; Liu, Tian; Jiang, Wulv; Gan, Lin] Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China in 2020, Cited 29. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Safety of Benzyl ether

In-situ Raman spectroelectrochemistry is a powerful tool to understand the structures and reaction mechanisms of electrochemical interfaces yet usually suffers from a low sensitivity and detection efficiency. Herein, we develop a windowless thin layer electrochemical cell design to improve the detection efficiency of in-situ Raman spectroscopy for practical nanoscale electrocatalysts. This was achieved by perforating a hole in the optical window of the cell, which not only eliminates the refraction of light by the window but also induces a meniscus thin electrolyte layer on the working electrode, thus significantly improving the detection efficiency of Raman spectra. We successfully applied thismethod to conduct in-situ Raman spectroscopy of structural evolutions of two representative Ni-Fe oxide catalysts (layered double hydroxides and spinel oxides) during oxygen evolution reaction (OER) electrocatalysis. It was shown that both catalysts underwent surface transformation to oxyhydroxides and formed active oxygen species at OER relevant potentials. However, the extent of the surface transformation was much lower on the Ni-Fe spinel catalyst, accounting for its lower OER activity. We further show that adding a carbon support can promote the surface transformation of Ni-Fe spinel to oxyhydroxides, thus significantly increasing the electrocatalytic activities. The established windowless thin layer method provides a new way to conduct in-situ electrochemical Raman spectroscopy of a wide range of materials and may be also combined with surface-enhanced Raman spectroscopic methods.

Safety of Benzyl ether. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article A new route to triphenylpyridines utilizing ketoximes as building blocks via cascade reactions under iron-organic framework catalysis WOS:000464452800069 published article about ONE-POT SYNTHESIS; OXIME ACETATES; METAL; PYRIDINES; CYCLIZATION; ACTIVATION; FUNCTIONALIZATION; NANOPARTICLES; PERFORMANCE; ADSORPTION in [Nguyen, Vu H. H.; Doan, Son H.; Van, Tram T.; Pham, Phuc H.; Nguyen, Tran T. N.; Phan, Nam T. S.] HCMC Univ Technol, VNU HCM, Fac Chem Engn, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam; [Nguyen, Ngoc N.; Tu, Thach N.] VNU HCM, Ctr Innovat Mat & Architectures, Linh Trung Ward, Quarter 6, Ho Chi Minh City, Vietnam in 2019, Cited 44. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Category: ethers-buliding-blocks

Iron-based metal-organic framework VNU-20 was utilized as a heterogeneous catalyst for cascade reactions between ketoximes and dibenzyl ether to produce 2,4,6-triphenylpyridines. Additionally, benzyl alcohol and (dimethoxymethyl) benzene could be used as an alternative starting materials for the transformation. The oxidant exhibited a remarkable impact on the reactions, and di-tertbutylperoxide was the most appropriate candidate. The VNU-20 displayed higher efficiency than many homogeneous and heterogeneous catalysts. The catalyst was reusable for the cascade reactions without a noticeable deterioration in catalytic activity. This transformation is new, and would offer alternative routes to triphenylpyridines utilizing ketoximes as building blocks.

About Benzyl ether, If you have any questions, you can contact Nguyen, VHH; Doan, SH; Van, TT; Pham, PH; Nguyen, TTN; Nguyen, NN; Tu, TN; Phan, NTS or concate me.. Category: ethers-buliding-blocks

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

I found the field of Engineering; Environmental Sciences & Ecology very interesting. Saw the article Integrating Exposure Knowledge and Serum Suspect Screening as a New Approach to Biomonitoring: An Application in Firefighters and Office Workers published in 2020.0. Safety of Diphenyl oxide, Reprint Addresses Rudel, RA (corresponding author), Silent Spring Inst, Newton, MA 02460 USA.; Morello-Frosch, R (corresponding author), Univ Calif Berkeley, Sch Publ Hlth, Berkeley, CA 94720 USA.; Morello-Frosch, R (corresponding author), Univ Calif Berkeley, Dept Environm Sci Policy & Management, Berkeley, CA 94720 USA.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Firefighters (FF) are exposed to recognized and probable carcinogens, yet there are few studies of chemical exposures and associated health concerns in women FFs, such as breast cancer. Biomonitoring often requires a priori selection of compounds to be measured, and so, it may not detect relevant, lesser known, exposures. The Women FFs Biomonitoring Collaborative (WFBC) created a biological sample archive and conducted a general suspect screen (GSS) to address this data gap. Using liquid chromatography-quadrupole time-of-flight tandem mass spectrometry, we sought to identify candidate chemicals of interest in serum samples from 83 women FFs and 79 women office workers (OW) in San Francisco. We identified chemical peaks by matching accurate mass from serum samples against a custom chemical database of 722 slightly polar phenolic and acidic compounds, including many of relevance to firefighting or breast cancer etiology. We then selected tentatively identified chemicals for confirmation based on the following criteria: (1) detection frequency or peak area differences between OW and FF; (2) evidence of mammary carcinogenicity, estrogenicity, or genotoxicity; and (3) not currently measured in large biomonitoring studies. We detected 620 chemicals that matched 300 molecular formulas in the WFBC database, including phthalate metabolites, phosphate flame-retardant metabolites, phenols, pesticides, nitro and nitroso compounds, and per- and polyfluoroalkyl substances. Of the 20 suspect chemicals selected for validation, 8 were confirmed-including two alkylphenols, ethyl paraben, BPF, PFOSAA, benzophenone-3, benzyl p-hydroxybenzoate, and triphenyl phosphate-by running a matrix spike of the reference standards and using m/z, retention time, and the confirmation of at least two fragment ions as criteria for matching. GSS provides a powerful highthroughput approach to identify and prioritize novel chemicals for biomonitoring and health studies.

Safety of Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Grashow, R; Bessonneau, V; Gerona, R; Wang, A; Trowbridge, J; Lin, T; Buren, H; Rudel, RA; Morello-Frosch, R or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Simultaneous acquisition of Fe3O4 monocrystals: Tunable magnetic properties with various morphologies WOS:000522647100006 published article about IRON-OXIDE NANOPARTICLES; FACILE SYNTHESIS; STABILIZER in [Zheng, Zemin; Li, Huiyong; Hu, Dafeng; Jiang, Hao; Geng, Xuemin; Lu, Jiangwei; Zhang, Xudong; Yang, Peng; Wan, Yanfen] Yunnan Univ, Sch Mat Sci & Engn, Yunnan Key Lab Micro Nano Mat & Technol, Kunming 650091, Yunnan, Peoples R China; [Cao, Yiming; Li, Zhe] Qujing Normal Univ, Ctr Magnet Mat & Devices, Qujing 655011, Yunnan, Peoples R China; [Cao, Yiming; Li, Zhe] Qujing Normal Univ, Key Lab Adv Funct & Low Dimens Mat, Yunnan Higher Educ Inst, Qujing 655011, Yunnan, Peoples R China in 2020, Cited 26. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. HPLC of Formula: C14H14O

Fe3O4 nanoparticles (NPs) with a face-centered cubic (fcc) structure and two different morphologies (nanospheres and nanoprisms) were synthesized by a facile one-step method. The synthesized Fe3O4 nanospheres and nanoprisms were monocrystalline and separable in a magnetic field. In different volume ratios of oleylamine (OAm) to dibenzyl ether, the sizes of the prepared Fe3O4 NPs ranged from 5 to 21 nm. The OAm amount in the synthesis can significantly control the morphology of Fe3O4 NPs. As the OAm content increased from 10 ml to 30 ml, the faceted nanoprisms shrank while the nanospheres enlarged. At an OAm content of 25 ml, the nanoprisms diminished while more hexagonal and sphere-like particles appeared, implying a critical point of morphology transition from triangle to hexagon. The magnetic properties also depended on the NP morphology and size. The prepared Fe3O4 NPs are promising candidates in medical applications such as magnetic resonance imaging, targeted drug delivery, blood purification, and tumor hyperthermia.

HPLC of Formula: C14H14O. Welcome to talk about 103-50-4, If you have any questions, you can contact Zheng, ZM; Cao, YM; Li, Z; Li, HY; Hu, DF; Jiang, H; Geng, XM; Lu, JW; Zhang, XD; Yang, P; Wan, YF or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

HPLC of Formula: C12H10O. In 2019.0 ACTA CHROMATOGR published article about TRACE AMOUNTS; NANOPARTICLES; CHROMATOGRAPHY; SORBENT; URINE; CU in [Noori, Arezoo Hassan; Kazemipour, Maryam] Islamic Azad Univ, Kerman Branch, Dept Chem, Kerman, Iran; [Rezaee, Mohammad] Atom Energy Org Iran, Nucl Sci & Technol Res Inst, Mat & Nucl Fuel Res Sch, POB 14395-836, Tehran, Iran; [Mashayekhi, Hossein Ali] Islamic Azad Univ, Tonekabon Branch, Dept Chem, Tonekabon, Iran in 2019.0, Cited 35.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

A new and sensitive method, termed magnetic solid phase extraction combined with dispersive liquid-liquid micro-extracton (MSPE-DLLME), has been developed for the simultaneous determination of biphenyl and biphenyl oxide in water samples. Different parameters influencing the extraction efficiency, including the amount of sorbent, sorption time, type of elution solvent and its volume, type of extraction solvent and its volume, and elution time were optimized. The calibration curves were linear in the range of 0.5-100 mu g/L for both of them. The limits of detection (LODs) were achieved, 0.03 mu g/L for biphenyl and 0.07 mu g/L for biphenyl oxide, respectively. Ultimately, the applicability of the method was successfully confirmed by the extraction and determination of biphenyl and biphenyl oxide in sea, river, tap, and water well.

Welcome to talk about 101-84-8, If you have any questions, you can contact Noori, AH; Rezaee, M; Kazemipour, M; Mashayekhi, HA or send Email.. HPLC of Formula: C12H10O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

SDS of cas: 101-84-8. Authors Pang, BL; Zhang, ML; Zhou, C; Dong, HZ; Ma, S; Feng, JG; Chen, YJ; Yu, LY; Dong, LF in ELSEVIER SCIENCE SA published article about in [Pang, Beili; Zhang, Meili; Zhou, Cheng; Dong, Hongzhou; Feng, Jianguang; Chen, Yingjie; Yu, Liyan; Dong, Lifeng] Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266042, Peoples R China; [Ma, Shuai] Qingdao Univ Sci & Technol, Sch Math & Phys, Qingdao 266061, Peoples R China; [Dong, Lifeng] Hamline Univ, Dept Phys, St Paul, MN 55104 USA in 2021.0, Cited 57.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

The development of low cost electrocatalysts with excellent I-/I-3(-) redox reaction efficiency is critically important for practical applications of dye-sensitized solar cells (DSSCs). Nevertheless, it is difficult to simultaneously improve the activity and stability of catalysts. Herein, heterogeneous FeNi3/NiFe2O4 nanoparticles are successfully embedded in modified graphene (mGr) matrix with network structure. As-prepared FeNi3/NiFe2O4@mGr shows excellent electrocatalytic activities and high stability. The DSSCs with FeNi3/NiFe2O4@mGr as counter electrodes demonstrate a high power conversion efficiency of 12.14%, which is superior to that of platinum (Pt, 8.31%). Also, the FeNi3/NiFe2O4@mGr device remains 90% efficiency up to 42 days under ambient conditions without encapsulation. Therefore, the FeNi3/NiFe2O4@mGr composite can be further developed as an environmentally friendly, inexpensive, and efficient counter electrode material for DSSCs.

Welcome to talk about 101-84-8, If you have any questions, you can contact Pang, BL; Zhang, ML; Zhou, C; Dong, HZ; Ma, S; Feng, JG; Chen, YJ; Yu, LY; Dong, LF or send Email.. SDS of cas: 101-84-8

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem