Category: 101-84-8

Authors Pelse, I; Hernandez, JL; Engmann, S; Herzing, AA; Richter, LJ; Reynolds, JR in AMER CHEMICAL SOC published article about TO-ROLL FABRICATION; LOW-BANDGAP POLYMER; X-RAY-SCATTERING; SOLAR-CELLS; PHASE-SEPARATION; HIGH-EFFICIENCY; DOMAIN PURITY; FIBRIL WIDTH; BLEND FILMS; MORPHOLOGY in [Pelse, Ian; Hernandez, Jeff L.; Reynolds, John R.] Georgia Inst Technol, Sch Chem & Biochem, Sch Mat Sci & Engn, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA; [Engmann, Sebastian] NIST, Nanoscale Device Characterizat Div, Gaithersburg, MD 20899 USA; [Herzing, Andrew A.; Richter, Lee J.] NIST, Mat Measurement Sci Div, Gaithersburg, MD 20899 USA in 2020.0, Cited 50.0. SDS of cas: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

The adoption of solution-processed active layers in the production of thin-alm photovoltaics is hampered by the transition from research fabrication techniques to scalable processing. We report a detailed study of the role of processing in determining the morphology and performance of organic photovoltaic devices using a commercially available, low-solubility, high-molar mass diketopyrrolopyrrole-based polymer donor. Ambient blade coating of thick layers in an inverted architecture was performed to best model scalable processing. Device performance was strongly dependent on the introduction of either o-dichlorobenzene (DCB), 1,8-diiodooctane, or diphenyl ether cosolvent into the chloroform (CHCl3) solution, which were all shown to drastically improve the morphology. To understand the origin of these morphological changes as a result of the addition of the cosolvent, in situ studies with grazing-incidence X-ray scattering and optical reflection interferometry were performed. Use of any of the cosolvents decreases the domain size relative to the single solvent system and moved the drying mechanism away from what is likely liquid-liquid phase separation to solid-liquid phase separation driven by polymer aggregation. Comparing the CHCl3 + DCB cast films to the CHCl3-only cast films, we observed both the formation of small domains and an increase in crystallinity during the evaporation of DCB due to a high nucleation rate from supersaturation. This resulted in percolated bulk heterojunction networks that performed similarly well with a wide range of film thicknesses from 180 to 440 nm, making this system amenable to continuous roll-to-roll processing methods.

SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Pelse, I; Hernandez, JL; Engmann, S; Herzing, AA; Richter, LJ; Reynolds, JR or concate me.

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Quality Control of Diphenyl oxide. In 2020.0 RSC ADV published article about VAN-DER-WAALS; MINIMUM ENERGY CONFORMATIONS; PHOTOFRAGMENTATION DYNAMICS; NONCOVALENT INTERACTIONS; PROTON-TRANSFER; STATE; BONDS; WATER; METHYLTHIOPHENOL; SPECTROSCOPY in [Wang, Lian; Zhang, Song; Wang, Ye; Zhang, Bing] Chinese Acad Sci, Innovat Acad Precis Measurement Sci & Technol, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China; [Wang, Lian; Zhang, Song; Wang, Ye; Zhang, Bing] Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2020.0, Cited 46.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Dispersion interactions are omnipresent in large aromatic systems and influence the dynamics as intermolecular forces. The structural preference induced by dispersion interactions is demonstrated to influence the excited state dynamics of diphenyl ether (DPE) using femtosecond time-resolved transient absorption (TA) associated with quantum chemical calculations. The experimental results in aprotic solvents show that the S-1 state is populated upon irradiation at 267 nm with excess vibrational energy dissipating to solvent molecules in several picoseconds, and then decays via internal conversion (IC) within 50 ps as well as intersystem crossing (ISC) and fluorescence with a lifetime of nanoseconds. The polarity of the solvent disturbs the excited state energies and enhances the energy barriers of the ISC channel. Furthermore, the intermolecular dispersion interactions with protic solvents result in the OH-pi isomer dominating in methanol and the OH-O isomer is slightly preferred in t-butanol in the ground state. The hydrogen bonded isomer measurements show an additional change from OH-O to OH-pi geometry in the first 1 ps besides the relaxation processes in aprotic solvents. The time constants measured in the TA spectra suggest that the OH-O isomer facilitates IC. The results show that the OH-pi isomer has a more rigid structure and a higher barrier for IC, making it harder to reach the geometric conical intersection through conformer rearrangement. This work enables us to have a good knowledge of how the structural preference induced by dispersion interactions affects excited state dynamics of the heteroaromatic compounds.

Quality Control of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Wang, L; Zhang, S; Wang, Y; Zhang, B or concate me.

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Recommanded Product: 101-84-8. I found the field of Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences very interesting. Saw the article Formation of brown carbon on Fe-bearing clay from volatile phenol under simulated atmospheric conditions published in 2020.0, Reprint Addresses Jin, X; Gu, C (corresponding author), Nanjing Univ, Sch Environm, State Key Lab Pollut Control & Resource Reuse, Nanjing 210023, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

Atmospheric brown carbon (BrC) has recently attracted great concerns due to its potential contribution to climate change. It was reported that dissolved Fe(III) species can act as an efficient oxidant to catalyze the polymerization of volatile phenol substances, subsequently forming atmospheric BrC in aerosols. Since Fe in the atmosphere is commonly associated with clay mineral dusts, the transformation of phenol substances on Fe-bearing clay mineral surface is potentially important for BrC formation. In this study, taking guaiacol as the model phenol substance, its brown carbon formation process was investigated on Fe(III) modified montmorillonite under different relative humidities (RHs). The spectroscopic features and compositions of the produced BrC were systematically characterized. The results demonstrated that the interface FeOH2+ is the key species to promote the polymerization of guaiacol, and RH plays a significant role to influence the surface acidity of clay and the gas-to-particle adsorption of guaiacol. The BrC was produced with the most abundance and variety under moderate RH (similar to 33%), while higher RH (similar to 100%) accelerated the polymerization rate. Since aerosol moisture content might not largely influence the hydroxylation states of the surface bearing Fe(III) species, it signifies the importance of clay associated Fe(III) to catalyze the BrC formation in varied conditions Our study highlights the importance of clay mineral dust on the formation of BrC, and reveals the brown carbon formation pathways under environmentally relevant conditions.

Recommanded Product: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Ling, JY; Sheng, F; Wang, Y; Peng, AP; Jin, X; Gu, C or concate me.

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Recommanded Product: 101-84-8. In 2020.0 J NANOSCI NANOTECHNO published article about SOLVOTHERMAL SYNTHESIS; CATALYTIC-ACTIVITY; COLORIMETRIC DETERMINATION; OPTICAL-PROPERTIES; HYDROGEN-PEROXIDE; MIMIC PEROXIDASE; MIMETIC ACTIVITY; LOW-TEMPERATURE; CUS; NANOCRYSTALS in [Sharma, Vanita; Jeevanandam, P.] Indian Inst Technol Roorkee, Dept Chem, Roorkee 247667, Uttar Pradesh, India in 2020.0, Cited 89.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Copper sulfide nanoparticles have been employed as artificial mimics for peroxidase-like activity. In the present study, copper sulfide nanoparticles with four different morphologies have been synthesized by thermal decomposition of cyclo-tri-mu-thioacetamide-tris(chlorocopper(I)) complex ([Cu(3)TAA(3)Cl(3)]) at 200 degrees C in different solvents such as diphenyl ether, ethylene glycol, 1-octadecene and also without any solvent. Hierarchical copper sulfide nanostructures are formed when the complex is decomposed in the absence of solvent, in diphenyl ether, and 1-octadecene while in the case of ethylene glycol, randomly agglomerated nanoparticles are formed. The precursor complex ([Cu(3)TAA(3)Cl(3)]) as well as copper sulfide nanoparticles were characterized using an array of techniques and after characterization, the peroxidase-like activity of copper sulfide nanoparticles was investigated. Morphologically different copper sulfide nanoparticles possess different exposed facets and due to this, the peroxidase-like activity was different among different morphologies.

Recommanded Product: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Sharma, V; Jeevanandam, P or concate me.

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Authors Xu, YY; Liang, CH; Zhang, TP; Tao, XQ; Wang, R; Huang, KB; Pan, ZX; Dang, Z; Yin, H; Lu, GN in PERGAMON-ELSEVIER SCIENCE LTD published article about BROMINATED FLAME RETARDANTS; REDUCTIVE DEBROMINATION; DECHLORINATION; KINETICS; SOIL; BIODEGRADATION; DEGRADATION; CORROSION; EXPOSURE; SYSTEMS in [Xu, Yongye; Liang, Chenghao; Zhang, Taiping; Wang, Rui; Huang, Kaibo; Dang, Zhi; Yin, Hua; Lu, Guining] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China; [Zhang, Taiping; Dang, Zhi; Yin, Hua; Lu, Guining] Minist Educ, Key Lab Pollut Control & Ecosyst Restorat Ind Clu, Guangzhou 510006, Peoples R China; [Tao, Xueqin; Pan, Zhaoxi] Zhongkai Univ Agr & Engn, Sch Environm Sci & Engn, Guangzhou 510225, Peoples R China in 2020.0, Cited 40.0. HPLC of Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

We synthesized a novel material, namely palladized zero-valent zinc (Pd/ZVZ), and investigated its efficiency for the degradation of polybrominated diphenyl ethers (PBDEs). The plated Pd significantly enhances the degradation rate of PBDEs by ZVZ at the optimum loading of 1% by weight. In the Pd/ZVZ system, very few lower BDEs were accumulated during the degradation of 2,2′,4,4′- tetrabromodiphenyl ether (BDE-47) and the final product is diphenyl ether, whereas the ZVZ system only debrominates BDE-47 to di-BDE and further debromination becomes very difficult. The degradation rates of BDEs by ZVZ greatly decreased with decreased bromination level, while in Pd/ZVZ system, the degradation rates of PBDEs did not show a significant difference. These indicate different mechanisms. This was confirmed by investigating the debromination pathways of the PBDEs in both systems. We determined that a H-transfer was the dominant mechanism in the Pd/ZVZ system. In addition, the reactivity of Pd/ZVZ to BDE-47 is pH-independent, which has a great advantage for various applications over ZVZ alone. Our study provides a new approach for the remediation of the PBDEs pollution. (C) 2020 Elsevier Ltd. All rights reserved.

HPLC of Formula: C12H10O. About Diphenyl oxide, If you have any questions, you can contact Xu, YY; Liang, CH; Zhang, TP; Tao, XQ; Wang, R; Huang, KB; Pan, ZX; Dang, Z; Yin, H; Lu, GN or concate me.

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An article Ni-Catalyzed reductive amination of phenols with ammonia or amines into cyclohexylamines WOS:000529203600006 published article about SELECTIVE HYDROGENATION; NITROARENE HYDROGENATION; NICKEL-CATALYST; ARYL ETHERS; CONVERSION; LIGNIN; HYDROGENOLYSIS; CYCLOHEXANONE; ALKYLATION; ALCOHOLS in [Cuypers, Thomas; Morias, Thomas; Windels, Simon; Marquez, Carlos; Van Goethem, Cedric; Vankelecom, Ivo; De Vos, Dirk E.] Univ Leuven, KU Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect cM, Celestijnenlaan 200F,Post Box 2461, B-3001 Heverlee, Belgium in 2020.0, Cited 69.0. Quality Control of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Phenol and its derivatives, which naturally occur in lignocellulose, can be considered as a renewable feedstock not only for aromatic, but also for alicyclic compounds, such as primary and N-substituted cyclohexylamines. So far, the latter are mostly produced from non-renewable starting materials like benzene via problematic nitration/reduction or cross-coupling routes. Herein, an efficient reductive amination of phenol with ammonia or amines is demonstrated, for the first time without the need for rare and expensive noble metals and without using any additives. Various supported Ni catalysts were screened and we elucidated the influence of the key parameters, including the acid-base properties of the supporting material. Acquired knowledge was then applied to different phenol-ammonia/amine combinations, resulting in the synthesis of various primary, secondary and tertiary cyclohexylamines in fair to very high yields.

About Diphenyl oxide, If you have any questions, you can contact Cuypers, T; Morias, T; Windels, S; Marquez, C; Van Goethem, C; Vankelecom, I; De Vos, DE or concate me.. Quality Control of Diphenyl oxide

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An article Hydrodebromination of Aromatic Bromides Catalyzed by Unsupported Nanoporous Gold: Heterolytic Cleavage of Hydrogen Molecule WOS:000565691700001 published article about HYDRODEHALOGENATION; HYDRODECHLORINATION; EFFICIENT; DEHALOGENATION; REACTIVITY; REDUCTION; TRANSFORMATION; CHLORINATION; HALOARENES; OXIDATION in [Zhao, Yuhui; Feng, Xiujuan; Zhang, Sheng; Yamamoto, Yoshinori; Bao, Ming] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China; [Yamamoto, Yoshinori] Ritsumeikan Univ, Res Org Sci & Technol, Kusatsu 5258577, Japan; [Bao, Ming] Dalian Univ Technol, Sch Chem Engn, Panjin 124221, Peoples R China in 2020, Cited 46. Recommanded Product: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Unsupported nanoporous gold (AuNPore) is a highly efficient, practically applicable, and recyclable catalyst for hydrodebromination of aromatic bromides. The AuNPore-catalyzed hydrodebromination of aromatic bromides proceeded smoothly at relatively low hydrogen pressure and temperature to achieve good to excellent yields of the corresponding non-bromine variants. The selective hydrodebromination reaction occurred exclusively in the coexistence of chlorine atom. For the first time, a mechanistic study revealed that the H-H bond splits in a heterolysis manner on the surface of AuNPore to generate Au-H hydride species.

Recommanded Product: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Zhao, YH; Feng, XJ; Zhang, S; Yamamoto, Y; Bao, M or concate me.

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Category: ethers-buliding-blocks. In 2020.0 SCI TOTAL ENVIRON published article about POLYCYCLIC AROMATIC-HYDROCARBONS; MUNICIPAL WASTE-WATER; LOWER NESTOS RIVER; GROUNDWATER QUALITY; PESTICIDE-RESIDUES; ORGANIC POLLUTANTS; RISK-ASSESSMENT; SURFACE WATERS; HEAVY-METALS; FRAMEWORK in [Gikas, G. D.; Sylaios, G. K.; Boskidis, I] Democritus Univ Thrace, Sch Engn, Dept Environm Engn, Lab Ecol Engn & Technol, Xanthi 67100, Greece; [Tsihrintzis, V. A.] Natl Tech Univ Athens, Ctr Assessment Nat Hazards & Proact Planning, Sch Rural & Surveying Engn, Athens 15780, Greece; [Tsihrintzis, V. A.] Natl Tech Univ Athens, Dept Infrastruct & Rural Dev, Lab Reclamat Works & Water Resources Management, Sch Rural & Surveying Engn, Athens 15780, Greece; [Konstantinou, I. K.; Albanis, T.] Univ Ioannina, Dept Chem, Ioannina 45110, Greece in 2020.0, Cited 87.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

The Water Framework Directive (WFD) methodology, proposed by the Ministry of Environment and Energy of Greece (WFD-MEEG), and the Canadian Council of Ministers of Environment Water Quality Index (CCME-WQI) are comparatively applied to evaluate the chemical status of a major transboundary river. Water quality parameters were monitored at 11 sites along the main stream of the river and its main tributaries, and at five sites in the reservoirs, on a monthly frequency, in the period from May 2008 to May 2009. Water temperature (T), dissolved oxygen (DO), pH, and electrical conductivity (EC) were measured in-situ, while water samples were collected for the determination of total suspended solids (TSS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), nitrite-, nitrate- and ammonium-nitrogen, total Kjeldahl nitrogen (TKN), ortho-phosphates (OP), total phosphorus (TP), and chlorophyll-a (Chl-a). The water samples were also analyzed for the determination of seven heavy metals (i.e., Cd, Pb, Hg, Ni, Cr, Cu, Zn) and 33 priority substances, as listed in Annex II of EU Directive 2008/105/EC. The results showed that the physicochemical parameters (i.e., T. DO, pH, EC, inorganic nitrogen, MN, OP, TP, TSS, and Chia) were within the natural range. The mean concentration of the measured heavy metals did not exceed the limits set by WHO (2003, 2017) for drinking water. Regarding the priority substances, some of them ( i.e., anthracene, fluoranthene, and polyaromatic hydrocarbons) were measured in various stations at higher concentrations than the Annual Average Environmental Quality Standards (AA-EQS). Based on the WFD-MEEG methodology, the river water was in the ‘good’ quality class, while according to CCME-WQI the river quality ranged from ‘marginal’ to ‘good’ category. It seems that CCME-WQI is stricter than WFD-MEEG but could be a WQI appropriate for use. (C) 2020 Elsevier B.V. All rights reserved.

About Diphenyl oxide, If you have any questions, you can contact Gikas, GD; Sylaios, GK; Tsihrintzis, VA; Konstantinou, IK; Albanis, T; Boskidis, I or concate me.. Category: ethers-buliding-blocks

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Name: Diphenyl oxide. Recently I am researching about STRUCTURE-PROPERTY RELATIONSHIPS; FIELD-EFFECT TRANSISTORS; HETEROJUNCTION SOLAR-CELLS; THIN-FILM TRANSISTORS; MOLECULAR DESIGN; HIGH-MOBILITY; ORGANIC TRANSISTORS; BUILDING-BLOCK; PERFORMANCE; SEMICONDUCTORS, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [61574077, 61704080]; National Key R&D Program of Strategic Advanced Electronic Materials [2016YFB0401100]; Natural Science Foundation of Jiangsu ProvinceNatural Science Foundation of Jiangsu Province [BK20170961]; Shenzhen Peacock Plan Project [KQTD20140630110339343]; Shenzhen Basic Research Fund [JCYJ20160530185244662]; Macau Science and Technology Development Fund [FDCT-116/2016/A3, FDCT-091/2017/A2]; University of Macau [SRG2016-00087-FST, MYRG2018-00148-IAPME]; Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [91733302, 61605073, 2015CB932200]; Young 1000 Talents Global Recruitment Program of China. Published in ELSEVIER in AMSTERDAM ,Authors: Yu, JW; Tang, YM; Miao, CY; Yang, K; Zhou, X; Yu, SM; Sun, HL; Huang, J; Guo, H; Guo, XG; Xing, GC; Zhang, SM. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

High-performance polymer semiconductors generally should have wide absorption, good solution processability, and fine-tuned physicochemical properties in order to achieve satisfying photovoltaic performance. Herein, two new alkynyl-functionalized electron donor units, 3-alkyl-3′-alkynyl-2,2′-bithiophene (TRTRy) and 3-alkoxy-3′-alkynyl-2,2′-bithiophene (TORTRy), were invented through the combination of the alkynyl side chain with the alkyl or alkoxy side chain, respectively. Copolymerization of these bithiophenes with difluorobenzothiadiazole (ffBT) afforded polymers ffBT-TRTRy and ffBT-TORTRy, respectively. When applied into polymer solar cells (PSCs), devices using ffBT-TRTRy donor polymer display a maximum power conversion efficiency (PCE) of 2.34% with a short-circuit current (J(sc)) of 7.46 mA cm(-2), an open circuit voltage (V-oc) of 0.93 V, and a fill factor (FF) of 34.0%. The TORTRy containing polymer ffBT-TORTRy affords PSCs with a much improved PCE of 6.60% with a higher J(sc) of 15.09 mA cm(-2), a larger FF of 58.3%, and a V-oc of 0.75 V. The performance improvement of PSC devices using ffBT-TORTRy donor is mainly attributed to the simultaneous realization of higher J(sc) and FF, while maintaining a good V-oc. The results demonstrate that alkynyl-functionalized H-H bithiophenes are promising building blocks for efficient PSCs.

Name: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Yu, JW; Tang, YM; Miao, CY; Yang, K; Zhou, X; Yu, SM; Sun, HL; Huang, J; Guo, H; Guo, XG; Xing, GC; Zhang, SM or concate me.

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An article The occurrence of polybrominated diphenyl ether (PBDE) contamination in soil, water/sediment, and air WOS:000477958300002 published article about BROMINATED FLAME RETARDANTS; POLYCHLORINATED-BIPHENYLS PCBS; POLYCYCLIC AROMATIC-HYDROCARBONS; PERSISTENT ORGANIC POLLUTANTS; WATER TREATMENT PLANTS; YANGTZE-RIVER DELTA; SUSPENDED PARTICULATE MATTER; CENTRAL TIBETAN PLATEAU; WASTE RECYCLING AREA; SURFACE SEDIMENTS in [Wu, Zhineng; Han, Wei; Li, Yao; Wang, Yingying] Nankai Univ, Tianjin Key Lab Environm Remediat & Pollut Contro, Key Lab Pollut Proc & Environm Criteria, Minist Educ,Coll Environm Sci & Engn, Tianjin 300350, Peoples R China; [Yang, Xin] Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China in 2019.0, Cited 236.0. Product Details of 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

As a kind of brominatedflame retardants (BFRs), polybrominated diphenyl ethers (PBDEs) are extensively used in different types of electronic equipment, furniture, plastics, and textiles. PBDEs are ubiquitous environmental contaminants that may impact human health and ecosystems. Here we highlight recent findings on the occurrence, contamination status, and transport of PBDEs in soil, water/sediment, and air. Four aspects are discussed in detail: (1) sources of PBDEs to the environment; (2) occurrence and transport of PBDEs in soil; (3) PBDEs in aquatic ecosystems (water/sediment) and their water-sediment partitioning; and (4) the occurrence of PBDEs in the atmosphere and their gas-particle partitioning. Future prospects for the investigation on PBDEs occurrence are also discussed based on current scientific and practical needs.

About Diphenyl oxide, If you have any questions, you can contact Wu, ZN; Han, W; Yang, X; Li, Y; Wang, YY or concate me.. Product Details of 101-84-8

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