Category: 101-84-8

In 2020.0 ACS CATAL published article about CATALYTIC REDUCTIVE FRACTIONATION; SELECTIVE HYDRODEOXYGENATION; OXIDATIVE CLEAVAGE; ALCOHOL OXIDATION; AROMATIC MONOMERS; MODEL COMPOUNDS; BIOMASS; CONVERSION; VALORIZATION; CHEMICALS in [Li, Lingxiao; Dong, Lin; Li, Didi; Guo, Yong; Liu, Xiaohui; Wang, Yanqin] East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China in 2020.0, Cited 59.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. SDS of cas: 101-84-8

Lignin is constructed from methoxylated phenylpropanoid with plenty of hydroxys and methoxys. Its conversion to valuable products is extremely attractive but especially challenging without additional hydrogen sources. Herein we report a hydrogen-free production of 4-alkylphenols directly from native lignin via self-reforming-driven depolymerization and hydrogenolysis over Pt/NiAl2O4. This is the first example of acquiring 4-alkylphenols from native lignin. Using this strategy, high yields of 4-alkylphenols, 17.3 wt %, were obtained from birch lignin. Reaction pathway and mechanism studies revealed that this strategy initiates from the reforming of aliphatic hydroxys, followed by the cleavage of C-O linkages, and ends via demethoxylation over Pt/NiAl2O4. Moreover, the subsequent aqueous phase reforming of the as-formed methanol accelerates the whole process. This strategy realizes the one-pot production of 4-alkylphenols from lignin by fully utilizing the structural hydrogen in lignin and H2O, providing a low-cost and safe method of lignin valorization.

About Diphenyl oxide, If you have any questions, you can contact Li, LX; Dong, L; Li, DD; Guo, Y; Liu, XH; Wang, YQ or concate me.. SDS of cas: 101-84-8

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Quality Control of Diphenyl oxide. Recently I am researching about VAPOR-PRESSURES; VAPORIZATION; ENTHALPIES; CARBAZOLE; LIGNIN, Saw an article supported by the Government of Russian Federation [220, 14, Z50.31.0038]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Verevkin, SP; Siewert, R; Emel’yanenko, VN; Bara, JE; Cao, HD; Pimerzin, AA. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

The liquid organic hydrogen carriers (LOHCs) are promising materials for hydrogen storage. The standard molar enthalpies of formation, Delta H-f(m)o (liq/cr) of diphenyl ether substituted with methyl, methoxy, and hydroxyl substituents were measured by the high-precision combustion calorimetry. Enthalpies of vaporization/sublimation Delta(g)(l,cr) H-o(m) (298.15 K) of these compounds were obtained by the transpiration method. Enthalpies of fusion of 2- and 4-hydroxy-diphenyl ether were measured by differential scanning calorimeter. Gas-phase enthalpies of formation Delta H-f(o)m (g, 298.15 K) of substituted diphenyl ethers calculated by the G4 method were in an excellent agreement with the experimental results. Enthalpies of the hydrogenation/dehydrogenation reactions of diphenyl ether derivatives were estimated and compared with the data available for other potential LOHC. A set of thermodynamic properties of diphenyl ether derivatives of benchmark quality was recommended for thermochemical calculations. Equilibrium temperatures of hydrogenation/dehydrogenation processes were calculated and compared with those of benzene derivatives. Because of their high hydrogen storage capacity, as well as very low volatility, these compounds could be considered as seminal candidates for LOHC.

Quality Control of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Verevkin, SP; Siewert, R; Emel’yanenko, VN; Bara, JE; Cao, HD; Pimerzin, AA or concate me.

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An article Asymmetric Alkoxy- and Hydroxy-Carbonylations of Functionalized Alkenes Assisted by beta-Carbonyl Groups WOS:000669117800001 published article about PALLADIUM-CATALYZED CARBONYLATION; ALLYLIC ALCOHOLS; ENANTIOSELECTIVE CYCLOCARBONYLATION; BASIS-SETS; ALKOXYCARBONYLATION; COMPLEXES; HYDROESTERIFICATION; CO; MECHANISM; OLEFINS in [Ren, Xinyi; Wang, Zhen; Shen, Chaoren; Tang, Lin; Ji, Xiaolei; Dong, Kaiwu] E China Normal Univ, Sch Chem & Mol Engn, Chang Kung Chuang Inst, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China; [Tian, Xinxin] Shanxi Univ, Inst Mol Sci, Key Lab Mat Energy Convers & Storage Shanxi Prov, Taiyuan 030006, Peoples R China in 2021.0, Cited 46.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. SDS of cas: 101-84-8

As a fundamental type of carbonylation reaction, the alkoxy- and hydroxy-carbonylation of unsaturated hydrocarbons constitutes one of the most important industrial applications of homogeneous catalysis. However, owing to the difficulties in controlling multi-selectivities for asymmetric hydrocarbonylation of alkenes, this reaction is typically limited to vinylarenes and analogues. In this work, a highly efficient asymmetric alkoxy- and hydroxy-carbonylation of beta-carbonyl functionalized alkenes was developed, providing practical and easy access to various densely functionalized chiral molecules with high optical purity from broadly available alkenes, CO, and nucleophiles (>90 examples, 84-99 % ee). This protocol features mild reaction conditions and a broad substrate scope, and the products can be readily transformed into a diverse array of chiral heterocycles. Control experiments revealed the key role of the beta-carbonyl group in determining the enantioselectivity and promoting the activity, which facilitates chiral induction by coordination to the transition metal as rationalized by DFT calculations. The strategy of utilizing an innate functional group as the directing group on the alkene substrate might find further applications in catalytic asymmetric hydrocarbonylation reactions.

SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Ren, XY; Wang, Z; Shen, CR; Tian, XX; Tang, L; Ji, XL; Dong, KW or concate me.

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Computed Properties of C12H10O. I found the field of Chemistry very interesting. Saw the article Molecular Design of Stable Sulfamide- and Sulfonamide-Based Electrolytes for Aprotic Li-O-2 Batteries published in 2019.0, Reprint Addresses Feng, ST (corresponding author), MIT, Dept Chem Engn, Cambridge, MA 02139 USA.; Johnson, JA (corresponding author), MIT, Dept Chem, Cambridge, MA 02139 USA.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

Electrolyte instability is one of the most challenging impediments to enabling lithium-oxygen (Li-O-2) batteries for practical use. The use of physical organic chemistry principles to rationally design new molecular components may enable the discovery of electrolytes with stability profiles that cannot be achieved with existing formulations. Here, we report on the development of sulfamide- and sulfonamide-based small molecules that are liquids at room temperature, capable of dissolving reasonably high concentration of Li salts (e.g., lithium bis(trifluoromethane)sulfonimide [LiTFSI]), and exceptionally stable under the harsh chemical and electrochemical conditions of aprotic Li-O-2 batteries. In particular, N,N-dimethyl-trifluoromethanesulfonamide was found to be highly resistant to chemical degradation by peroxide and superoxide, stable against electrochemical oxidation up to 4.5 V-Li, and stable for >90 cycles in a Li-O-2 cell when cycled at <4.2 V-Li. This study provides guiding principles for the development of next-generation electrolyte components based on sulfamides and sulfonamides. Computed Properties of C12H10O. About Diphenyl oxide, If you have any questions, you can contact Feng, ST; Huang, MJ; Lamb, JR; Zhang, WX; Tatara, R; Zhang, YR; Zhu, YG; Perkinson, CF; Johnson, JA; Shao-Horn, Y or concate me.

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An article Inhibition of the Vesicular Glutamate Transporter (VGLUT) with Congo Red Analogs: New Binding Insights WOS:000604793600004 published article about SYNAPTIC VESICLES; NEUROTRANSMITTER TRANSPORTERS; QUINOLINE-2,4-DICARBOXYLIC ACIDS; GLYCEROL-3-PHOSPHATE TRANSPORTER; COMPETITIVE-INHIBITION; PRESYNAPTIC REGULATION; QUANTAL SIZE; PHARMACOLOGY; SITES; TRANSMISSION in [Hitt, David M.; Zwicker, Jeffery D.; Chao, Chih-Kai; Patel, Sarjubhai A.; Gerdes, John M.; Bridges, Richard J.; Thompson, Charles M.] Univ Montana, Coll Hlth Profess & Biomed Sci, Ctr Struct & Funct Neurosci, Dept Biomed & Pharmaceut Sci, Missoula, MT 59812 USA; [Hitt, David M.] Carroll Coll, Dept Chem, 1601 N Benton Ave, Helena, MT 59625 USA; [Zwicker, Jeffery D.] Deciphera Pharmaceut, 643 Massachusetts St, Lawrence, KS 66044 USA in 2021, Cited 55. Product Details of 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

The vesicular glutamate transporter (VGLUT) facilitates the uptake of glutamate (Glu) into neuronal vesicles. VGLUT has not yet been fully characterized pharmacologically but a body of work established that certain azo-dyes bearing two Glu isosteres via a linker were potent inhibitors. However, the distance between the isostere groups that convey potent inhibition has not been delineated. This report describes the synthesis and pharmacologic assessment of Congo Red analogs that contain one or two glutamate isostere or mimic groups; the latter varied in the interatomic distance and spacer properties to probe strategic binding interactions within VGLUT. The more potent inhibitors had two glutamate isosteres symmetrically linked to a central aromatic group and showed IC50 values similar to 0.3-2.0 mu M at VGLUT. These compounds contained phenyl, diphenyl ether (PhOPh) or 1,2-diphenylethane as the linker connecting 4-aminonaphthalene sulfonic acid groups. A homology model for VGLUT2 using d-galactonate transporter (DgoT) to dock and identify R88, H199 and F219 as key protein interactions with Trypan Blue, Congo Red and selected potent analogs prepared and tested in this report.

Product Details of 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Hitt, DM; Zwicker, JD; Chao, CK; Patel, SA; Gerdes, JM; Bridges, RJ; Thompson, CM or concate me.

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Ether – Wikipedia,
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Zhang, SJ; Qiu, YL; Li, Y in [Zhang, Shujing; Qiu, Youli; Li, Yu] North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China published Detection Method of Environmentally Friendly Non-POP PBDEs by Derivatization-Enhanced Raman Spectroscopy Using the Pharmacophore Model in 2019.0, Cited 33.0. Recommanded Product: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Background: Polybrominated diphenyl ethers (PBDEs) are dangerous for the environment and human health because of their persistent organic pollutant (POP) characteristics, which have attracted extensive research attention. Raman spectroscopy is a simple highly sensitive detection operation. This study was performed to obtain environmentally friendly non-POP PBDE derivatives with simple detection-based molecular design and provide theoretical support for establishing enhanced Raman spectroscopic detection techniques. Methods: A three-dimensional quantitative structure-activity relationship (3DQSAR) pharmacophore model of characteristic PBDE Raman spectral was established using 20 and 10 PBDEs as training and test sets, respectively. Full-factor experimental design was used to modify representative commercial PBDEs, and their flame retardancy and POP characteristics were evaluated. Results: The pharmacophore model (Hypol) exhibited good predictive ability with the largest correlation coefficient (R-2) of 0.88, the smallest root mean square (RMS) value of 0.231, and total cost of 81.488 with a configuration value of 12.56 (<17).74 monosubstituted and disubstituted PBDE derivatives were obtained based on the Hypo 1 pharmacophore model and full-factor experimental design auxiliary. Twenty PBDE derivatives were screened, and their flame-retardant capabilities were enhanced and their migration and bio-concentration were reduced (log(K-OW) <5), with unchanged toxicity and high biodegradability. The Raman spectral intensities increased up to 380%. In addition, interference analysis of the Raman peaks by group frequency indicated that the 20 PBDE derivatives were easily detected with no interference in gaseous environments. Conclusion: Nine pharmacophore models were constructed in this study; Hypo 1 was the most accurate. Twenty PBDE derivatives showed Raman spectral intensities increased up to 380%; these were classified as new non-POP environmentally friendly flame retardants with low toxicity, low migration, good biodegradability, and low bio-concentrations. 2D QSAR analysis showed that the most positive Milliken charge and lowest occupied orbital energy were the main contributors to the PBDE Raman spectral intensities. Raman peak analysis revealed no interference between the derivatives in gaseous environments. About Diphenyl oxide, If you have any questions, you can contact Zhang, SJ; Qiu, YL; Li, Y or concate me.. Recommanded Product: 101-84-8

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In 2019.0 J MAGN MAGN MATER published article about DESIGN; GOLD; SIZE in [Goswami, Madhuri Mandal] SN Bose Natl Ctr Basic Sci, Sect 3,Block JD, Kolkata 700106, India; [Das, Arpita; De, Debarati] Univ Calcutta, CRNN, Sect 3,Block JD, Kolkata 700106, India in 2019.0, Cited 33.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Recommanded Product: Diphenyl oxide

This work reports a new approach of synthesis of FePt nanoparticles in aqueous medium using cetyl trimethylammonium bromide (CTAB) surfactant as a capping agent and the influence of change of its concentration on the size of the particles. Tuning of magnetic properties has also been done by changing the CTAB concentrations. Here at higher CTAB concentration, particles formed are of smaller size compared to the size prepared in lower micellar concentration. The ordering parameter of the particles after annealing at 550 degrees C with the variation of particle size is also studied. The magnetic properties of these particles are studied and the effect of particle phase and size on magnetic property is also investigated. The particles are prepared in aqueous medium because water soluble particles are useful for hyperthermia therapy. Heating abilities of the particles under AC magnetic field are also checked with change in their size. The studies on interaction of particles with cancer cell line was also performed with probing the cell by fluorescence imaging technique after bio-functionalization of the particles by sodium oleate and fluorescent dye rhodamine-B-isothiocyanate (RITC). All these preliminary studies indicate a promising applicability of the particles for localized cancer treatment by magnetic field induced hyperthermia therapy.

Recommanded Product: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Goswami, MM; Das, A; De, D or concate me.

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Name: Diphenyl oxide. I found the field of Polymer Science very interesting. Saw the article Synthesis and characterization of bio-based aromatic polyketones and polyetherketones derived from divanillic acid published in 2021.0, Reprint Addresses Enomoto, Y (corresponding author), Univ Tokyo, Grad Sch Agr & Life Sci, Sci Polymer Mat,Dept Biomat Sci, Bunkyo Ku, 1-1-1 Yayoi, Tokyo 1138657, Japan.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

Bio-based aromatic polyketones (PKs) and polyetherketones (PEKs) were synthesized by the electrophilic substitution reaction of alkoxylated divanillic acid (R-DVA) and 2,2′-dimethoxybiphenyl or diphenylether. Alkoxy side-chains were introduced at the hydroxyl groups of DVA prior to polymerization. Polymerizations were carried out in a phosphorus pentoxide (P2O5)/methanesulfonic acid (MsOH) system. DVA-based PKs and PEKs were soluble in common organic solvents including chloroform and dimethylsulfoxide, and their chemical structures were determined by H-1 and C-13 NMR. The weight-average molecular weights (M-w) of the PKs were 2.6-15.0 x 10(3) g/mol, and those of all PEKs were approximately 1.0 x 10(3). The 10% degradation temperatures of the PKs and PEKs were 340-400 degrees C. Dynamic mechanical analysis showed that the PKs and PEKs were amorphous. The PKs with methyl to butyl side-chains exhibited high glass transition temperatures (T-g) in the range 250-297 degrees C, while T-g of PK (octyl side-chain) was 157 degrees C and those of the PEKs were 73-127 degrees C.

Name: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Enomoto, Y; Iwata, T or concate me.

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Recommanded Product: 101-84-8. Authors Fui, CJ; Ting, TX; Sarjadi, MS; Amin, Z; Sarkar, SM; Musta, B; Rahman, M in AMER CHEMICAL SOC published article about in [Fui, Choong Jian; Ting, Tang Xin; Sarjadi, Mohd Sani; Musta, Baba; Rahman, MdLutfor] Univ Malaysia Sabah, Fac Sci & Nat Resources, Kota Kinabalu 88400, Sabah, Malaysia; [Amin, Zarina] Univ Malaysia Sabah, Biotechnol Res Inst, Kota Kinabalu 88400, Sabah, Malaysia; [Sarkar, Shaheen M.] Univ Limerick, Bernal Inst, Dept Chem Sci, Limerick V94 T9PX, Ireland in 2021, Cited 80. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Highly active natural pandanus-extracted cellulose-supported poly(hydroxamic acid)-Cu(II) complex 4 was synthesized. The surface of pandanus cellulose was modified through graft copolymerization using purified methyl acrylate as a monomer. Then, copolymer methyl acrylate was converted into a bidentate chelating ligand poly(hydroxamic acid) via a Loosen rearrangement in the presence of an aqueous solution of hydroxylamine. Finally, copper species were incorporated into poly(hydroxamic acid) via the adsorption process. Cu(II) complex 4 was fully characterized by Fourier transform infrared (FTIR), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX), transmission electron microscopy (TEM), inductively coupled plasma optical emission spectrometry (ICP-OES), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) analyses. The cellulose-supported Cu(II) complex 4 was successfully applied (0.005 mol %) to the Ullmann etherification of aryl, benzyl halides, and phenacyl bromide with a number of aromatic phenols to provide the corresponding ethers with excellent yield [benzyl halide (70-99%); aryl halide (20-90%)]. Cu(II) complex 4 showed high stability and was easily recovered from the reaction mixture. It could be reused up to seven times without loss of its original catalytic activity. Therefore, Cu(II) complex 4 can be commercially utilized for the preparation of various ethers, and this synthetic technique could be a part in the synthesis of natural products and medicinal compounds.

Recommanded Product: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Fui, CJ; Ting, TX; Sarjadi, MS; Amin, Z; Sarkar, SM; Musta, B; Rahman, M or concate me.

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Ether – Wikipedia,
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SDS of cas: 101-84-8. In 2021.0 ACS OMEGA published article about ENHANCED MECHANICAL-PROPERTIES; PHENOLIC FOAM; THERMAL-STABILITY; EPOXY-RESIN; PROPERTY in [Li, Tingting; Yu, Ruobing] East China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China; [Zhao, Dandan] East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China in 2021.0, Cited 45.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

A novel halogen- and phosphorus-free intrinsic flame-retardant foam is fabricated from curable phenol-terminated polyphenylene ether resin with a high molecular weight using phenol, formaldehyde, and diphenyl ether as starting materials. The limiting oxygen index (LOI) of the pure foam is 24.90% +/- 0.28. When 0.5 wt % silica sol is added, the LOI of the foam (SPF-0.5) is up to 28.5% +/- 0.15 and both the combustion heat release rate and total combustion heat are low. Moreover, the SPF-0.5 foam exhibits high carbon residue, high compressive strength, and low pulverization rate and is superior to some previously reported phenolic foam. The flame-retardant mechanism includes the condensed-phase flame retardation and the gas-phase flame retardation, with the former being the main step, which is based on the high cross-linking density, the higher strength and smaller size of foam cells, and the formation of a carbon-silicon compound in the foam. This halogen- and phosphorous-free flame-retardant foam is also environmentally benign.

SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Li, TT; Yu, RB; Zhao, DD or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem