Category: 101-84-8

Category: ethers-buliding-blocks. Recently I am researching about OPEN-CIRCUIT VOLTAGE; CONJUGATED POLYMERS; PHOTOVOLTAIC PERFORMANCE; FLUORINE SUBSTITUTION; SIDE-CHAINS; DIKETOPYRROLOPYRROLE; ACCEPTOR; COPOLYMER; TRANSPORT; MOLECULE, Saw an article supported by the Fundamental Research Foundation of Shenzhen [JCYJ20170818101906654]; Kongque Technology Innovation Foundation of Shenzhen [KQJSCX20170727101037551]. Published in SPRINGER in NEW YORK ,Authors: Shah, MN; Yang, YT; Sohail, M; Pathipati, SR; Pan, XF. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

In this study, we have designed and synthesized a low-bandgap polymer, DPP-Qx, using quinoxaline (Qx), a non-alkylated weak acceptor, with diketopyrrolopyrrole (DPP) as an electron donor. The incorporation of Qx into DPP leads to the highest occupied molecular orbital level at -5.1 eV with a narrow optical bandgap (1.25 eV). The synthesized polymer is utilized in photovoltaics, and the photovoltaic properties are studied. This DPP-Qx with fullerene acceptors in polymer solar cells (PSCs) exhibits efficiency of 3.26%. Moreover, a minimum energy loss of 0.57 eV along with high extended external quantum efficiency is achieved with the DPP-Qx electron donor. The thermal, electrical and optical properties, energy levels and hole mobility of the synthesized polymer are studied and discussed.

Welcome to talk about 101-84-8, If you have any questions, you can contact Shah, MN; Yang, YT; Sohail, M; Pathipati, SR; Pan, XF or send Email.. Category: ethers-buliding-blocks

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Authors Oleszek, S; Kumagai, S; Grabda, M; Shiota, K; Yoshioka, T; Takaoka, M in ELSEVIER published article about in [Oleszek, Sylwia; Shiota, Kenji; Takaoka, Masaki] Kyoto Univ, Grad Sch Engn, Dept Environm Engn, Nishikyo Ku, Katsura C-1-3, Kyoto 6158540, Japan; [Oleszek, Sylwia; Grabda, Mariusz] Polish Acad Sci, Inst Environm Engn, M Sklodowska Curie 34, PL-41819 Zabrze, Poland; [Kumagai, Shogo; Yoshioka, Toshiaki] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, 6-6-07 Aoba, Sendai, Miyagi 9808579, Japan in 2021.0, Cited 44.0. Recommanded Product: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Polycarbonate (PC) is an engineering thermoplastic that is widely used in electrical and electronic equipment. This plastic often contains tetrabromobisphenol A (TBBA), the most common brominated flame retardant. Thermal degradation of the PC-TBBA leads to generation of numerous bromo-organic products in the pyrolytic oil, hindering its appropriate utilization, as well as corrosive hydrogen bromide gas. The purpose of this study was to experimentally investigate and compare the pyrolysis products of PC-TBBA and PC-TBBA + Cu2O at various temperatures, with an emphasis on the yield and distribution of brominated compounds. In pyrolysis of PC-TBBA + Cu2O, at the maximum degradation temperature (600 degrees C), as much as 86% of total Br was trapped in the residue, while 3% and 11% were distributed in the condensate and gas fractions, respectively. In contrast, the distribution of Br from non-catalytic pyrolysis of PC-TBBA (600 degrees C) was 0.5% residue, 40% condensate, and 60% gas. The results of this study revealed that in the presence of Cu2O, organo-bromine products were most likely involved in Ullman-type coupling reactions, leading to early cross-linking of the polymer network that efficiently hinders their vaporization. HBr in the gas fraction was suppressed due to effective fixation of bromine in residue in the form of CuBr.

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Ether – Wikipedia,
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In 2020.0 ORG BIOMOL CHEM published article about ENERGY-ADJUSTED PSEUDOPOTENTIALS; DENSITY FUNCTIONALS; BASIS-SETS; PALLADIUM; ACTIVATION; BROMIDES; ELEMENTS; CARBON; TRIPHENYLPHOSPHINE; THERMOCHEMISTRY in [Wu, Shao-Qi; Zhang, Shuo-Qing; Hong, Xin] Zhejiang Univ, Dept Chem, Hangzhou 310058, Peoples R China; [Hong, Xin] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Zheda Rd 38, Hangzhou 310027, Peoples R China in 2020.0, Cited 56.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Computed Properties of C12H10O

Transition metal-catalyzed single bond metathesis has recently emerged as a useful strategy for functional group transfer. In this work, we explored the mechanism and reactivity profile of Pd/PhI-cocatalyzed C-P bond metathesis between aryl phosphines using density functional theory (DFT) calculations. The overall single bond metathesis involves two Pd(ii)-catalyzed C-P reductive eliminations and two Pd(0)-catalyzed C-P oxidative additions, which allows the reversible C-P bond cleavage and formation of the phosphonium cation. Distortion/interaction analysis indicates that the facile C-P bond cleavage and formation of the phosphonium cation are due to the involvement of coordinating aryl phosphine in the process. In addition, the substituent effects on the reaction kinetics and thermodynamics of metathesis were computed, which provides helpful mechanistic information for the design of related single bond metathesis reactions.

Welcome to talk about 101-84-8, If you have any questions, you can contact Wu, SQ; Zhang, SQ; Hong, X or send Email.. Computed Properties of C12H10O

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Name: Diphenyl oxide. In 2019.0 APPL SURF SCI published article about FACILE APPROACH; WATER; NANOPARTICLES; SEPARATION; GRAPHENE; AREA in [Talukdar, Meenakshi; Behera, Sushant Kumar; Bhattacharya, Kakoli; Deb, Pritam] Cent Univ, AFML, Dept Phys, Tezpur Univ, Tezpur 784028, India in 2019.0, Cited 44.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Efficient oil adsorption and recovery is a generous universal importance for future energy demand and environmental protection. Adsorbents based on 2D flatland with engineered surfaces can overcome the limitations of conventional methods for selective oil adsorption. Here, we report magnetic hydrophobic/oleophilic graphitic C3N4 nanosheets that exhibit excellent oil sorption performance and rapid removal of adsorbed oil using an external magnet. Combining porous and nanosheets structure along with magnetic FeNi3 and fatty acid surface functionalization make the system an efficient adsorbent for adsorbing and separating crude oil from water. The graphitic sheets selectively adsorb crude oil with enhancement of thickness up to 9 folds and mass by 4.5 times than the pristine nanocomposite system. The smart adsorption property of g-C3N4@FeNi3 has been realized through comprehensive adsorption kinetics and inclusive isotherm studies. The nanocomposite can be further recycled and reused in an eco-friendly manner for oil adsorption and recovery.

Name: Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Talukdar, M; Behera, SK; Bhattacharya, K; Deb, P or concate me.

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Ether – Wikipedia,
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Recently I am researching about INHIBITORS; PET; SUBSTITUTION; ARYL; SITE; F-18-FLUORINATION; INFLAMMATION; DERIVATIVES; METABOLISM; REAGENT, Saw an article supported by the National Institutes of Health (NIGMS)United States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [RO1GM12018, 5R01EB014354]; UNC Department of Radiology, Biomedical Research Imaging Center; UNC Lineberger Comprehensive Cancer Center; NSF Graduate Research FellowshipNational Science Foundation (NSF); NIH High-End Instrumentation GrantUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [IS100D023611-01]; NATIONAL INSTITUTE OF BIOMEDICAL IMAGING AND BIOENGINEERINGUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of Biomedical Imaging & Bioengineering (NIBIB) [R01EB014354] Funding Source: NIH RePORTER; NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCESUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [R01GM120186] Funding Source: NIH RePORTER. Published in AMER ASSOC ADVANCEMENT SCIENCE in WASHINGTON ,Authors: Chen, W; Huang, Z; Tay, NES; Giglio, B; Wang, MZ; Wang, H; Wu, ZH; Nicewicz, DA; Li, ZB. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Application In Synthesis of Diphenyl oxide

Positron emission tomography (PET) plays key roles in drug discovery and development, as well as medical imaging. However, there is a dearth of efficient and simple radiolabeling methods for aromatic C-H bonds, which limits advancements in PET radiotracer development. Here, we disclose a mild method for the fluorine-18 (F-18)-fluorination of aromatic C-H bonds by an [F-18]F- salt via organic photoredox catalysis under blue light illumination. This strategy was applied to the synthesis of a wide range of F-18-labeled arenes and heteroaromatics, including pharmaceutical compounds. These products can serve as diagnostic agents or provide key information about the in vivo fate of the labeled substrates, as showcased in preliminary tracer studies in mice.

Welcome to talk about 101-84-8, If you have any questions, you can contact Chen, W; Huang, Z; Tay, NES; Giglio, B; Wang, MZ; Wang, H; Wu, ZH; Nicewicz, DA; Li, ZB or send Email.. Application In Synthesis of Diphenyl oxide

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Ether – Wikipedia,
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I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Nucleophilic Thiols Reductively Cleave Ether Linkages in Lignin Model Polymers and Lignin published in 2020. Name: Diphenyl oxide, Reprint Addresses Jackson, JE (corresponding author), Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA.; Hegg, EL (corresponding author), Michigan State Univ, Dept Biochem & Mol Biol, E Lansing, MI 48824 USA.; Hegg, EL (corresponding author), Michigan State Univ, DOE Great Lakes Bioenergy Res Ctr, E Lansing, MI 48824 USA.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Lignin may serve as a renewable feedstock for the production of chemicals and fuels if mild, scalable processes for its depolymerization can be devised. The use of small organic thiols represents a bioinspired strategy to cleave the beta-O-4 bond, the most common linkage in lignin. In the present study, synthetic beta-O-4 linked polymers were treated with organic thiols, yielding up to 90 % cleaved monomer products. Lignin extracted from poplar was also treated with organic thiols resulting in molecular weight reductions as high as 65 % (M-n) in oxidized lignin. Thiol-based cleavage of other lignin linkages was also explored in small-molecule model systems to uncover additional potential pathways by which thiols might depolymerize lignin. The success of thiol-mediated cleavage on model dimers, polymers, and biomass-derived lignin illustrates the potential utility of small redox-active molecules to penetrate complex polymer matrices for depolymerization and subsequent valorization of lignin into fuels and chemicals.

Welcome to talk about 101-84-8, If you have any questions, you can contact Klinger, GE; Zhou, YT; Foote, JA; Wester, AM; Cui, YB; Alherech, M; Stahl, SS; Jackson, JE; Hegg, EL or send Email.. Name: Diphenyl oxide

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2020.0 CHEMOSPHERE published article about BROMINATED FLAME RETARDANTS; REDUCTIVE DEBROMINATION; DECHLORINATION; KINETICS; SOIL; BIODEGRADATION; DEGRADATION; CORROSION; EXPOSURE; SYSTEMS in [Xu, Yongye; Liang, Chenghao; Zhang, Taiping; Wang, Rui; Huang, Kaibo; Dang, Zhi; Yin, Hua; Lu, Guining] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China; [Zhang, Taiping; Dang, Zhi; Yin, Hua; Lu, Guining] Minist Educ, Key Lab Pollut Control & Ecosyst Restorat Ind Clu, Guangzhou 510006, Peoples R China; [Tao, Xueqin; Pan, Zhaoxi] Zhongkai Univ Agr & Engn, Sch Environm Sci & Engn, Guangzhou 510225, Peoples R China in 2020.0, Cited 40.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Safety of Diphenyl oxide

We synthesized a novel material, namely palladized zero-valent zinc (Pd/ZVZ), and investigated its efficiency for the degradation of polybrominated diphenyl ethers (PBDEs). The plated Pd significantly enhances the degradation rate of PBDEs by ZVZ at the optimum loading of 1% by weight. In the Pd/ZVZ system, very few lower BDEs were accumulated during the degradation of 2,2′,4,4′- tetrabromodiphenyl ether (BDE-47) and the final product is diphenyl ether, whereas the ZVZ system only debrominates BDE-47 to di-BDE and further debromination becomes very difficult. The degradation rates of BDEs by ZVZ greatly decreased with decreased bromination level, while in Pd/ZVZ system, the degradation rates of PBDEs did not show a significant difference. These indicate different mechanisms. This was confirmed by investigating the debromination pathways of the PBDEs in both systems. We determined that a H-transfer was the dominant mechanism in the Pd/ZVZ system. In addition, the reactivity of Pd/ZVZ to BDE-47 is pH-independent, which has a great advantage for various applications over ZVZ alone. Our study provides a new approach for the remediation of the PBDEs pollution. (C) 2020 Elsevier Ltd. All rights reserved.

Safety of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Xu, YY; Liang, CH; Zhang, TP; Tao, XQ; Wang, R; Huang, KB; Pan, ZX; Dang, Z; Yin, H; Lu, GN or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Computed Properties of C12H10O. In 2019.0 SYNTHETIC MET published article about MOLECULAR ELECTRON-ACCEPTORS; PERYLENE DIIMIDE DIMERS; PERFORMANCE; EFFICIENCY; FUSION; BISIMIDE; BACKBONE; CORE; PCE in [Laventure, Audrey; Payne, Abby-Jo; Welch, Gregory C.] Univ Calgary, Dept Chem, 2500 Univ Dr NW, Calgary, AB T2N 1N4, Canada; [Stanzel, Samantha; Lessard, Benoit H.] Univ Ottawa, Dept Chem & Biol Engn, 161 Louis Pasteur, Ottawa, ON K1N 6N5, Canada in 2019.0, Cited 58.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

We report the synthesis and characterization of an arene-fused N-annulated perylene diimide dimer (F-NPDI2) and evaluate the new material’s suitability to be used as a non-fullerene acceptor for organic solar cells. Photovoltaic devices were fabricated using the donor polymer PTB7-Th. A direct comparison of bulk heterojunction active layers processed from halogenated and non-halogenated solvent/additive systems was made. Use of the solvent 1,2,4-trimethylbenzene (TMB) and the solvent additive 1,4-dimethylnaphthalene (DMN) led to best power conversion efficiency of ca. 2.5%. Photovoltaic devices had high open circuit voltages upwards of 1.12 V, representing one of the highest for perylene diimide based systems. The active layer morphology and subsequent device performance was insensitive to the nature and volume of solvent additive used for processing and type of coating method (spin vs slot-die) making for a robust bulk heterojunction for large area organic solar cell applications.

Computed Properties of C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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An article Synthesis, Biological Evaluation and Molecular Dynamics Simulation Studies of Novel Diphenyl Ethers WOS:000514850000010 published article about FATTY-ACID SYNTHASE; CRYSTAL-STRUCTURE; TRICLOSAN; INHIBITION; APOPTOSIS; CELLS; FAS in [Khade, Amol B.; Kar, Sidhartha S.; Alummoottil, Cinu T.; Tiwari, Ashutosh; Giliyar, Varadaraj B.; Shenoy, Gurupur G.] Manipal Acad Higher Educ, Manipal Coll Pharmaceut Sci, Dept Pharmaceut Chem, Manipal 576104, India; [Tiwari, Mradul] Manipal Acad Higher Educ, Manipal Coll Pharmaceut Sci, Dept Pharmaceut Biotechnol, Manipal 576104, India; [Eshwara, Vandana K.] Manipal Acad Higher Educ, Kasturba Med Coll, Dept Microbiol, Manipal 576104, India; [Bhat, Pritesh] Schrodinger Inc, Near KMWA Vidya Niketan, Bangalore 560086, Karnataka, India in 2020.0, Cited 31.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Category: ethers-buliding-blocks

Background: The well-known antibacterial agent Triclosan (TCL) that targets bacterial enoylacyl protein reductase has been described to inhibit human fatty acid synthase (FASN) via the enoylacyl reductase domain. A Literature survey indicates that TCL is selectively toxic to cancer cells and furthermore might indeed reduce cancer incidence in vivo. A recent study found that TCL inhibits FASN by acting as an allosteric protein-protein interface (PPI) inhibitor. It induces dimer orientation changes that effect in a downstream reorientation of catalytic residues in the NADPH binding site proposing TCL as a viable scaffold to design a superior molecule that might have more inhibitory potential. This unveils tons of potential interaction space to take advantage of future inhibitor design. Objectives: Synthesis of TCL mimicking novel diphenyl ether derivatives, biological evaluation as potential antiproliferative agents and molecular docking and molecular dynamics simulation studies. Methods: A series of novel N-(1-(3-hydroxy-4-phenoxyphenyl)-3-oxo-3-phenylpropyl)acetamides (3a-n) and N-(3(3-hydroxy-4phenoxyphenyl)-3-oxo-1-phenylpropyl) acetamides (6a-n) were designed, synthesized, characterized and evaluated against HepG2, A-549, MCF-7 and Vero cell lines. The induction of antiproliferative activity of selected compounds (3d and 6c) was done by AO/EB (acridine orange/ethidium bromide) nuclear staining method, DNA fragmentation study, and cell cycle analysis was performed by flow cytometry. Molecular docking and dynamics simulation study was also performed. Results: Among the tested compounds, compound 3d was most active (IC50 13.76 +/- 0.43 mu M) against A-549 cell line. Compounds 3d and 3g were found to be moderately active with IC50 30.56 +/- 1.1 mu M and 25.05 +/- 0.8 mu M respectively against MCF-7 cell line. Morphological analysis of A-549 cells treated with 3d and 6c clearly demonstrated the reduction of cell viability and induction of apoptosis. DNA fragmentation was observed as a characteristic of apoptosis in treated cells. Further, cell cycle analysis by flow cytometry confirmed that compounds 3d and 6c significantly arrested the cell cycle at the G0/G1 phase. Molecular docking study demonstrated that these compounds exhibit high affinity for the human fatty acid synthase (hFASN) target. Molecular dynamics simulation study of the most active compound 3d was performed for calculating binding free energies using Molecular Mechanics-Generalized Born Surface Area (MM/GBSA). Conclusion: Compound 3d (IC50 13.76 +/- 0.43 mu M) has been identified as a potential lead molecule for anticancer activity against A-549 cells followed by 3l, 6c, and 3g. Thus, the design of diphenyl ether derivatives with enhanced affinity to the binding site of hER may lead to the discovery of potential anticancer agents.

Category: ethers-buliding-blocks. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: 101-84-8. In 2019.0 ENVIRON INT published article about POLYBROMINATED DIPHENYL ETHERS; PERSISTENT ORGANIC POLLUTANTS; INDOOR DUST; ASSOCIATION; PROFILE; SAMPLES in [Ongono, Jeanne Sandrine; Dow, Courtney; Gambaretti, Juliette; Severi, Gianluca; Boutron-Ruault, Marie-Christine; Bonnet, Fabrice; Fagherazzi, Guy; Mancini, Francesca Romana] Univ Paris Saclay, CESP, Fac Med, Univ Paris Sud,UVSQ,INSERM, F-94805 Villejuif, France; [Ongono, Jeanne Sandrine; Dow, Courtney; Gambaretti, Juliette; Severi, Gianluca; Boutron-Ruault, Marie-Christine; Fagherazzi, Guy; Mancini, Francesca Romana] Gustave Roussy, F-94805 Villejuif, France; [Bonnet, Fabrice] Univ Rennes 1, CHU Rennes, Dept Endocrinol Diabetol & Nutr, Rennes, France in 2019.0, Cited 34.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Introduction: The prevalence of type 2 diabetes (T2D) is increasing worldwide. Recent studies have suggested that environmental factors, such as exposure to brominated flame retardants (BFRs), could play a role in the epidemic of T2D. The aim of this study was to analyze the association between the dietary exposure to BFRs (Hexabromocyclododecane (HBCD) and Polybromodiphenylether (PBDE)) and T2D risk in the E3N prospective cohort of French women. Research design and methods: Overall, 71,415 women followed for 19 years were included in the study. We performed Cox regression models to analyze the association between dietary exposure to BFRs and T2D risk. Results: Overall 71,415 women were included and 3667 (5.13%) developed a T2D during follow-up. The mean dietary exposure to HBCD and to PBDE was 0.22 ng/kg body weight (BW)/day and 1.21 ng/kg bw/day, respectively. There was a positive linear association between dietary exposure to HBCD and T2D risk starting from the 2nd quintile group (HR: 1.18; 95% CI: 1.06-1.30) to the 5th quintile group (HR: 1.47; 95% CI: 1.29-1.67) when compared to the 1st quintile group. We also found positive although non-linear associations between dietary exposure to PBDE and T2D risk, with an increased HR only for the 2nd and 4th vs. 1st quintile groups (HR: 1.12; 95% CI: 1.02-1.24, and HR: 1.20; 95% CI: 1.08-1.34, respectively). Conclusion: The findings suggest an association between dietary exposure to BFRs and T2D risk, highlighting the importance of further investigating this association the long-term health effects of endocrine disruptors in the general population. Additional studies are needed to reproduce these findings in other populations and clarify the underlying biological mechanisms.

Recommanded Product: 101-84-8. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem