Category: 101-84-8

An article Organophosphate esters in house dust: A comparative study between Canada, Turkey and Egypt WOS:000447092700021 published article about BROMINATED FLAME RETARDANTS; POLYBROMINATED DIPHENYL ETHERS; HUMAN EXPOSURE ASSESSMENT; INDOOR DUST; ENDOCRINE DISRUPTION; MASS-SPECTROMETRY; ORGANIC CONTAMINANTS; PHTHALATE-ESTERS; PHOSPHATE TDCPP; PARTICLE-SIZE in [Shoeib, Tamer; Hassan, Yasmeen] Amer Univ Cairo, Dept Chem, New Cairo 11835, Egypt; [Webster, Glenys M.] Simon Fraser Univ, Fac Hlth Sci, Burnaby, BC, Canada; [Tepe, Sedef] Istanbul Tech Univ, Fac Civil Engn, Dept Environm Engn, TR-34469 Istanbul, Turkey; [Yalcin, Melis; Turgut, Cafer] Adnan Menderes Univ, Fac Agr, TR-09100 Aydin, Turkey; [Kurt-Karakus, Perihan Binnur] Bursa Tech Univ, Fac Engn & Nat Sci, Dept Environm Engn, TR-16310 Yildirim Bursa, Turkey; [Jantunen, Liisa] Environm & Climate Change Canada, Air Qual Proc Res Sect, 6248 Eighth Line, Egbert, ON, Canada in 2019.0, Cited 96.0. Computed Properties of C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Organophosphate esters (OPEs) are commonly used as flame retardants (FRs) and plasticizers. The usage of OPEs has increased recently due to the ban of several brominated flame retardants, but information on levels in the environment, including the indoor environment is still limited. We investigated the occurrence and distribution of 12 OPEs in urban house dust from Vancouver, Canada; Istanbul, Turkey; and Cairo, Egypt. The medianSOPE concentration was 41.4 mu g/g in the Vancouver samples while median levels in Istanbul and Cairo were significantly lower. The median composition profiles of OPEs in Vancouver and Cairo were dominated by tris (2-butoxyethyl) phosphate (TBOEP), accounting for 56 and 92% of total OPEs respectively while it showed a detection frequency of only 14% in Istanbul. Tris (2-chloropropyl) phosphate (TCPP) was the most abundant chlorinated OPE representing 20 and 36% of the total OPEs in Vancouver and Istanbul respectively, but was below the detection limit in the Cairo dust samples. Consistent with other studies, SOPE concentrations were similar to 1 to 2 orders of magnitude higher than PBDEs and currently used flame retardants in the same dust samples. The mean estimated daily intakes (EDI) of SOPE from dust were 115, 38 and 9 ng/kg/bw/day in Vancouver, Cairo and Istanbul respectively for toddlers where adults were similar to 10 times lower. The total toddler OPE intake ranged from 115 to 2900, 38 to 845 and from9 to 240 ng/kg bw/day across the three cities. TBOEP had the largest contribution to the EDI in both toddler and adults, where toddler TBOEP exposures via dust represented 4% to 80%, 2% to 44% and 0.1% to 6% of the Reference Doses (RfD) in the mean and high intake scenarios for toddlers in Vancouver, Cairo and Istanbul respectively. Crown Copyright (C) 2018 Published by Elsevier B.V. All rights reserved.

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An article High-efficiency electrochemical hydrodeoxygenation of bio-phenols to hydrocarbon fuels by a superacid-noble metal particle dual-catalyst system WOS:000524490200011 published article about MILD ELECTROCATALYTIC HYDROGENATION; SELECTIVE HYDROGENATION; CYCLOHEXANONE; DEOXYGENATION; LIGNIN; OILS in [Deng, Yulin] Georgia Inst Technol, Sch Chem & Biomol Engn, 500 10th St NW, Atlanta, GA 30332 USA; Georgia Inst Technol, RBI, 500 10th St NW, Atlanta, GA 30332 USA in 2020.0, Cited 33.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Category: ethers-buliding-blocks

Electrocatalytic hydrogenation (ECH) provides a green route to upgrade oxygenated bio-oil under mild conditions, but is still challenged with the issues of low working current density (<60 mA cm(-2)) and low faradaic efficiency (usually 20-60%) that seriously hinder its practical applications. Herein, we present a dual-catalyst electrochemical route that achieves extremely high faradaic efficiency (>99% for many chemicals) and high working current density (up to 800 mA cm(-2)) in the hydrogenation of model bio-oil compounds. More importantly, efficient deoxygenation to alkanes, often thought to be very difficult in conventional ECH, was achieved in the aqueous electrolysis. The dual-catalyst system consists of a suspended noble-metal catalyst and soluble polyoxometalate (POM). The theoretical calculations indicate that the POM functions as a superacid, changing the common hydrogenation route to a carbocation mechanism and resulting in effective electrolytic deoxygenation of oxygenates. Because no current flows through the catalyst, even a non-conductive catalyst can be used, which provides a great opportunity for extension to general applications.

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Recently I am researching about REGIOSELECTIVE IODINATION; NITROSYLSULFURIC ACID; AROMATIC-COMPOUNDS; EFFICIENT METHOD; NITROGEN-OXIDE; C-13 NMR; MILD; CONVENIENT; BROMINATION; 3,5-DIARYLISOXAZOLES, Saw an article supported by the Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-33-01109, 20-33-90030]; M.V. Lomonosov Moscow State University Program of Development. Safety of Diphenyl oxide. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Bondarenko, OB; Karetnikov, GL; Komarov, AI; Pavlov, AI; Nikolaeva, SN. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

A new convenient and versatile halogenating system (R(4)NHal/NOHSO4), giving straightforward and general access to halogenated 3,5-diaryl- and alkylarylisoxazoles, pyrazoles and electron-rich benzenes from the corresponding scaffolds, is suggested. The method provides excellent regioselectivity, scalability to the gram scale, and a broad scope for both aromatics and halogens. A three-step, one-pot reaction protocol was developed, and a series of 3,5-diaryl-4-haloisoxazoles has been efficiently synthesized from 1,2-diarylcyclopropanes under suggested nitrosating-halogenating conditions.

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Guan, WX; Chen, X; Zhang, J; Hu, HQ; Liang, CH in [Guan, Weixiang; Chen, Xiao; Zhang, Jie; Liang, Changhai] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China; [Hu, Haoquan] Dalian Univ Technol, Sch Chem Engn, Inst Coal Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China published Catalytic transfer hydrogenolysis of lignin alpha-O-4 model compound 4-(benzyloxy)phenol and lignin over Pt/HNbWO6/CNTs catalyst in 2020.0, Cited 45.0. Quality Control of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Cleavage of C-O bonds in aryl ether through the catalytic transfer hydrogenolysis (CTH) is an encouraging method for the valorization of lignin into fine chemicals and liquid fuels. In this contribution, the CTH of typical lignin alpha-O-4 model compound 4-(benzyloxy)phenol (BOP) and lignin extracted from ash wood have been explored over 0.45 wt% Pt/HNbWO6/CNTs catalyst. The effect of solvents was elaborated and the highest catalytic activity was achieved in the CTH of BOP using isopropanol as the solvent (98.1%). This was because isopropanol can provide more hydrogen atoms to promote CTH reaction due to the weakest interaction between isopropanol and BOP among all H-donor solvents. The favorable results obtained in the model compound study inspired us to afford Pt/HNbWO6/CNTs catalyst in the CTH of lignin. The relative oxygen content of lignin was sharply decreased after the CTH process, and the higher heating value (HHV) significantly increased from 21.4 MJ/kg to 30.8 MJ/kg. GPC, FT-IR, GC-MS, and 2D-NMR results revealed that lignin was successfully depolymerized into small molecule compounds over Pt/HNbWO6/CNTs catalyst through the CTH process. Thereinto, phenolic compounds were the major components in the liquid products in which most of them were monophenols. The results obtained in this work shed light on that Pt/HNbWO6/CNTs was a favorable catalyst in the depolymerization of lignin into valuable phenolic compounds via the CTH method. (C) 2020 Elsevier Ltd. All rights reserved.

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I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Highly Efficient Cleavage of Ether Bonds in Lignin Models by Transfer Hydrogenolysis over Dual-Functional Ruthenium/Montmorillonite published in 2020.0. SDS of cas: 101-84-8, Reprint Addresses Xue, ZM (corresponding author), Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China.; Mu, TC (corresponding author), Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Cleavage of ether bonds is a crucial but challenging step for lignin valorization. To efficiently realize this transformation, the development of robust catalysts or catalytic systems is required. In this study, montmorillonite (MMT)-supported Ru (denoted as Ru/MMT) is fabricated as a dual-functional heterogeneous catalyst to cleave various types of ether bonds through transfer hydrogenolysis without using any additional acids or bases. The prepared Ru/MMT material is found to efficiently catalyze the cleavage of various lignin models and lignin-derived phenols; cyclohexanes (fuels) and cyclohexanols (key intermediates) are the main products. The synergistic effect between electron-enriched Ru and the acidic sites on MMT contributes to the excellent performance of Ru/MMT. Systematic studies reveal that the reaction proceeds through two possible reaction pathways, including the direct cleavage of ether bonds and the formation of intermediates with one hydrogenated benzene ring, for all examined types of ether bonds, namely, 4-O-5, alpha-O-4, and beta-O-4.

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An article Psoralen Derivatives with Enhanced Potency WOS:000542397500001 published article about WAVELENGTH DEPENDENCE; FUROCOUMARIN DERIVATIVES; ACID PHOTOREACTION; CROSS-LINKING; DNA; 8-METHOXYPSORALEN; CELLS; PHOTOCHEMOTHERAPY; MONOADDUCTS; INHIBITION in [Buhimschi, Alexandru D.] Northwestern Univ, Feinberg Sch Med, Med Scientist Training Program, Chicago, IL 60611 USA; [Buhimschi, Alexandru D.; Gasparro, Francis P.] Hamden Hall Country Day Sch, Photobiol Lab, Hamden, CT 06517 USA; [Gooden, David M.] Duke Univ, Dept Chem, Durham, NC 27706 USA; [Jing, Hongwu] Univ Illinois, Coll Med, Dept Obstet & Gynecol, Chicago, IL 60612 USA; [Fels, Diane R.; Hansen, Katherine S.; Dewhirst, Mark W.] Duke Univ, Med Ctr, Dept Radiat Oncol, Durham, NC USA; [Fels, Diane R.; Hansen, Katherine S.; Dewhirst, Mark W.] Duke Univ, Med Ctr, Duke Canc Inst, Durham, NC USA; [Beyer, Wayne F., Jr.; Walder, Harold] Immunolight LLC, Detroit, MI USA in 2020.0, Cited 58.0. Application In Synthesis of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Psoralen is a furocoumarin natural product that intercalates within DNA and forms covalent adducts when activated by ultraviolet radiation. It is well known that this property contributes to psoralen’s clinical efficacy in several disease contexts, which include vitiligo, psoriasis, graft-versus-host disease and cutaneous T-cell lymphoma. Given the therapeutic relevance of psoralen and its derivatives, we attempted to synthesize psoralens with even greater potency. In this study, we report a library of 73 novel psoralens, the largest collection of its kind. When screened for the ability to reduce cell proliferation, we identified two derivatives even more cytotoxic than 4 ‘-aminomethyl-4,5 ‘,8-trimethylpsoralen (AMT), one of the most potent psoralens identified to date. Using MALDI-TOF MS, we studied the DNA adduct formation for a subset of novel psoralens and found that in most cases enhanced DNA binding correlated well with cytotoxicity. Generally, our most potent derivatives contain positively charged substituents, which we believe increase DNA affinity and enhance psoralen intercalation. Thus, we provide a rational approach to guide efforts toward further optimizing psoralens to fully capitalize on this drug class’ therapeutic potential. Finally, the structure-activity insights we have gained shed light on several opportunities to study currently underappreciated aspects of psoralen’s mechanism.

Application In Synthesis of Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Buhimschi, AD; Gooden, DM; Jing, HW; Fels, DR; Hansen, KS; Beyer, WF; Dewhirst, MW; Walder, H; Gasparro, FP or send Email.

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An article The photodynamic antimicrobial chemotherapy of Stapphylococcus aureus using an asymmetrical zinc phthalocyanine conjugated to silver and iron oxide based nanoparticles WOS:000582481800014 published article about PHOTOCHEMICAL PROPERTIES; METAL-PHTHALOCYANINES; QUANTUM YIELDS; SINGLET; SILICA; OXYGEN; PHOTOSENSITIZERS; SUBSTITUENTS; THERAPY; COLI in [Mapukata, Sivuyisiwe; Nwahara, Nnamdi; Nyokong, Tebello] Rhodes Univ, Inst Nanotechnol Innovat, Dept Chem, ZA-6140 Makhanda, South Africa in 2020.0, Cited 46.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Recommanded Product: 101-84-8

The synthesis and characterisation of asymmetrical zinc(II) 2(3)-mono-isophthalic acid-9(10),16(17),23 (24)-tri (tert-butylphenoxy) phthalocyanine (complex 4) are reported. The phthalocyanine is conjugated to cysteamine capped silver nanoparticles (Cys-Ag NPs), amine functionalised iron oxide magnetic nanoparticles (NH2-Fe3O4 NPs) and a core-shell composite of the two (Cys-Fe3O4@Ag) via amide bonds. The photo-physico-chemical properties of complex 4 and its respective nanoconjugates (4-Ag, 4-Fe3O4 NPs and 4-Fe3O4@Ag NPs) are also reported. The nanoconjugates showed improved triplet and singlet oxygen quantum yields compared to complex 4. The antibacterial activity of complex 4 and its nanoconjugates were also evaluated on S. aureus wherein their activity was found to be mainly visible light driven with the best catalyst being 4-Fe3O4@Ag. The work therefore demonstrates the feasibility of phthalocyanine-nanoparticle based compounds as potential agents in real life antibacterial treatment.

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Recommanded Product: 101-84-8. In 2019.0 J ELECTROCHEM SOC published article about 25TH ANNIVERSARY ARTICLE; OPEN-CIRCUIT VOLTAGE; SIDE-CHAINS; POLYMER; EFFICIENCY; DONOR; PERFORMANCE; ENHANCEMENT; COPOLYMERS; ACCEPTORS in [Goksu, Kardelen; Cevher, Sevki Can; Akrema; Toppare, Levent; Cirpan, Ali] Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkey; [Hizalan, Gonul; Toppare, Levent; Cirpan, Ali] Middle East Tech Univ, Ctr Solar Energy Res & Applicat GUNAM, TR-06800 Ankara, Turkey; [Udum, Yasemin Arslan] Gazi Univ, Vocat High Sch, Tech Sci, TR-06374 Ankara, Turkey; [Hacioglu, Serife Ozdemir] Iskenderun Tech Univ, Dept Basic Sci Engn, TR-31200 Antakya, Turkey; [Toppare, Levent; Cirpan, Ali] Middle East Tech Univ, Dept Polymer Sci & Technol, TR-06800 Ankara, Turkey; [Toppare, Levent] Middle East Tech Univ, Dept Biotechnol, TR-06800 Ankara, Turkey; [Cirpan, Ali] Middle East Tech Univ, Dept Micro & Nanotechnol, TR-06800 Ankara, Turkey in 2019.0, Cited 74.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Two random terpolymers bearing alkoxy-benzodithiophene as an electron-rich unit and N-octylthieno[3,4,c]pyrrole-4,6-dione (TPD) as an electron deficient group with thiophene and selenophene pi bridges, were synthesized and characterized. Electrochemical, optical properties of the polymers were analyzed to get an insight on the effect of different p bridges. Photovoltaic performances of the polymers were investigated with a conventional device architecture. PBTS, PBTSe based polymer solar cells (PSCs) exhibited power conversion efficiency of 3.32% and 3.19%. PCE of PBTS:PC71BM based PSCs were improved to 4.30% with the addition of 1% (vol/vol) 1,8-diiodooctane (DIO) as a solution processing additive. With the introduction of diphenyl ether (DPE) as the solvent additive, PBTSe based polymer solar cells attained 5.15% PCE value due to the formation of the interpenetrated network structure of domains. (C) 2019 The Electrochemical Society.

Welcome to talk about 101-84-8, If you have any questions, you can contact Goksu, K; Hizalan, G; Udum, YA; Hacioglu, SO; Cevher, SC; Akrema; Toppare, L; Cirpan, A or send Email.. Recommanded Product: 101-84-8

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In 2019.0 CHIRALITY published article about LIQUID-CHROMATOGRAPHY; PERIODATE-OXIDATION; CONGO RED; ENANTIOSEPARATION; ANTIBODIES; RESOLUTION; REMOVAL; DRUGS; FILM in [Gao, Jie; Chen, Lixiao; Wu, Qi; Li, Hui; Dong, Shuqing; Zhao, Liang] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Gansu, Peoples R China; [Gao, Jie; Chen, Lixiao; Wu, Qi; Li, Hui; Dong, Shuqing; Zhao, Liang] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Gansu, Peoples R China; [Gao, Jie; Chen, Lixiao; Wu, Qi] Univ Chinese Acad Sci, Beijing, Peoples R China; [Qin, Peng; Yang, Fang] Lanzhou Petrochem Res Ctr, Lanzhou, Gansu, Peoples R China in 2019.0, Cited 39.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Name: Diphenyl oxide

A novel high-performance liquid chromatography (HPLC) multifunctional immobilized chiral stationary phase was prepared by bonding dialdehyde microcrystalline cellulose to aminosilica via Schiff base reaction and then derivatized with 3,5-dimethylphenyl isocyanate. The HPLC multifunctional immobilized chiral stationary phase could not only achieve chiral separation but also achieve achiral separation. Chiral separation evaluation showed that 1-(1-naphthyl)ethanol and mandelonitrile got separation in normal phase (NP) mode. Ranolazine, benzoin ethyl ether, metalaxyl, and diclofop were successfully separated in reversed phase (RP) mode. Aromatic compounds such as polycyclic aromatic hydrocarbons (PAHs), anilines, and aromatic acids were selected as analytes to investigate the achiral separation performance of the multifunctional immobilized chiral stationary phase in NP and RP modes. The achiral separation evaluation showed that six PAHs could get good separation within 10 minutes in NP mode. Four aromatic acids were well separated in RP mode. The retention mechanism of aromatic compounds on the stationary phase was discussed, founding that pi-pi interaction, pi-pi electron-donor-acceptor (EDA) interaction, and hydrogen bonding interaction played important roles during the achiral separation process. This multifunctional immobilized chiral stationary phase had the advantages of simple bonding steps, short reaction time, and no need for space arm.

Name: Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Gao, J; Chen, LX; Wu, Q; Li, H; Dong, SQ; Qin, P; Yang, F; Zhao, L or send Email.

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Recommanded Product: 101-84-8. In 2020.0 ENVIRON POLLUT published article about POLYBROMINATED DIPHENYL ETHERS; INHALATION RISK-ASSESSMENT; WATER FOOD-WEB; POLYCHLORINATED-BIPHENYLS; ORGANOCHLORINE PESTICIDES; EMISSION INVENTORY; CONGENER PATTERNS; HEALTH-RISKS; INDOOR AIR; E-WASTE in [Niu, Shan; Hai, Reti] Beijing Univ Chem Technol, Beijing Engn Res Ctr Environm Mat Water Purificat, Beijing 10029, Peoples R China; [Niu, Shan; Dong, Liang; Huang, Yeru] Natl Res Ctr Environm Anal & Measurement, Beijing 100029, Peoples R China; [Chen, Ruiwen] Agilent Technol China Co LTD, Beijing 100102, Peoples R China; [Zou, Yun] Shimadzu China Co LTD, China MS Ctr, Beijing 100020, Peoples R China in 2020.0, Cited 55.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Research on the atmospheric occurrence of short chain chlorinated paraffins (SCCPs) in industrialized areas is scarce. In this study, we investigated the concentrations, profile, and spatial distribution of SCCPs in the highly industrialized and developed areas of the Yangtze River Delta (YRD) in China using polyurethane foam passive air samplers. Sampling was performed during two separate periods in 2011. The concentrations of atmospheric SCCPs ranged from 6.1 to 63 ng m(-3) in summer and 6.2-42 ng m(-3) in winter. The C-10 and C-11 groups were the predominant carbon groups in all the samples. Different congener patterns between summer and winter were found, indicating that congeners in the air in winter may be influenced by local and external sources. The highest level of SCCPs was found in Suzhou, which is a highly industrialized area with many manufactories including electronic industries and plastic factories. Higher levels of SCCPs were found in the air than polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ether (PBDEs), suggesting that the production and use of SCCPs were much higher than prohibited or restricted persistent organic pollutants (e.g., PCBs, OCPs, and PBDEs). Future studies should investigate the different sources of atmospheric SCCPs by conducting a comprehensive assessment of SCCP exposure. (C) 2020 Elsevier Ltd. All rights reserved.

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Ether – Wikipedia,
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