Category: 101-84-8

An article Hierarchical tumor acidity-responsive self-assembled magnetic nanotheranostics for bimodal bioimaging and photodynamic therapy WOS:000466361500013 published article about UP-CONVERSION NANOPARTICLES; METAL-ORGANIC FRAMEWORK; POLYMERIC MICELLES; QUANTUM DOTS; DRUG; PHOTOSENSITIZER; POLYPEPTIDE; OXIDE; EMISSION; DELIVERY in [Yang, Hong Yu; Fu, Yan] Jilin Inst Chem Technol, Coll Mat Sci & Engn, Jilin 132022, Jilin, Peoples R China; [Li, Yi; Wu, Te Peng; Lee, Doo Sung] Sungkyunkwan Univ, Theranost Macromol Res Ctr, Suwon 16419, Gyeonggi Do, South Korea; [Li, Yi; Wu, Te Peng; Lee, Doo Sung] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, Gyeonggi Do, South Korea; [Jang, Moon-Sun; Lee, Jung Hee] Sungkyunkwan Univ, Sch Med, Samsung Med Ctr, Dept Radiol, Seoul 06351, South Korea; [Jang, Moon-Sun; Lee, Jung Hee] Samsung Biomed Res Inst, Ctr Mol & Cellular Imaging, Seoul 06351, South Korea in 2019.0, Cited 52.0. SDS of cas: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Nanosized self-assemblies built from inorganic nanoparticles and polymer ligands have the potential to generate personalized theranostics systems for diagnostic imaging and cancer therapy. However, most of the theranostics systems suffer from poor targeting activity, insensitive diagnosis and drug leakage, leading to poor treatment results. In this study, a hierarchical tumor acidity-responsive magnetic nanobomb (termed HTAMN) was developed for photodynamic therapy and diagnostic imaging. The HTAMNs were formed through the self-assembly of chlorin e6 (Ce6)-functionalized polypeptide ligand, methoxy poly (ethyleneglycol)-block-poly (dopamineethylenediamine-2,3-dimethylmaleic anhydride)-L-glutamate-Ce6 [mPEG-b-P (Dopa-Ethy-DMMA)LG-Ce6] and superparamagnetic iron oxide nanoparticles (SPIONs). Negatively charged HTAMNs circulate in the blood for prolonged periods and promote tumor retention by passive targeting to the tumor. Once the HTAMNs arrive at the tumor location, the acidic extracellular tumor environment reverses the surface charge of the HTAMNs, resulting in tumor accumulation and cellular uptake. Moreover, in response to the more acidic environment inside cells, the photosensitizers are activated resulted in enhanced diagnostic imaging and cancer treatment. The in vitro and in vivo results indicate the effective tumor accumulation, internalization, diagnostic sensitivity and superior photodynamic therapy effect of the HTAMNs. Therefore, designing smart HTAMNs can promote the rapid development of cancer theranostics for clinical implementation.

Welcome to talk about 101-84-8, If you have any questions, you can contact Yang, HY; Jang, MS; Li, Y; Fu, Y; Wu, TP; Lee, JH; Lee, DS or send Email.. Recommanded Product: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Oxidative Photochlorination of Electron-Rich Arenes via in situ Bromination WOS:000519315900026 published article about CHLORINATION; CHEMISTRY; CHLORIDE; ALKYNES; SUBSTITUTION; HALOGENATION; ACTIVATION; CATALYSIS; EFFICIENT; ALPHA in [Duesel, Simon Josef Siegfried; Koenig, Burkhard] Univ Regensburg, Inst Organ Chem, Univ Str 31, D-93053 Regensburg, Germany in 2020, Cited 41. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Recommanded Product: Diphenyl oxide

Electron-rich arenes are oxidatively photochlorinated in the presence of catalytic amounts of bromide ions, visible light, and 4CzIPN as organic photoredox catalyst. The substrates are brominated in situ in a first photoredox-catalyzed oxidation step, followed by a photocatalyzed ipso-chlorination, yielding the target compounds in high ortho/para regioselectivity. Dioxygen serves as a green and convenient terminal oxidant. The use of aqueous hydrochloric acid as the chloride source reduces the amount of saline by-products.

Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. HPLC of Formula: C12H10O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. Wang, L; Zhang, S; Wang, Y; Zhang, B in [Wang, Lian; Zhang, Song; Wang, Ye; Zhang, Bing] Chinese Acad Sci, Innovat Acad Precis Measurement Sci & Technol, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China; [Wang, Lian; Zhang, Song; Wang, Ye; Zhang, Bing] Univ Chinese Acad Sci, Beijing 100049, Peoples R China published Dispersion-induced structural preference in the ultrafast dynamics of diphenyl ether in 2020.0, Cited 46.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Dispersion interactions are omnipresent in large aromatic systems and influence the dynamics as intermolecular forces. The structural preference induced by dispersion interactions is demonstrated to influence the excited state dynamics of diphenyl ether (DPE) using femtosecond time-resolved transient absorption (TA) associated with quantum chemical calculations. The experimental results in aprotic solvents show that the S-1 state is populated upon irradiation at 267 nm with excess vibrational energy dissipating to solvent molecules in several picoseconds, and then decays via internal conversion (IC) within 50 ps as well as intersystem crossing (ISC) and fluorescence with a lifetime of nanoseconds. The polarity of the solvent disturbs the excited state energies and enhances the energy barriers of the ISC channel. Furthermore, the intermolecular dispersion interactions with protic solvents result in the OH-pi isomer dominating in methanol and the OH-O isomer is slightly preferred in t-butanol in the ground state. The hydrogen bonded isomer measurements show an additional change from OH-O to OH-pi geometry in the first 1 ps besides the relaxation processes in aprotic solvents. The time constants measured in the TA spectra suggest that the OH-O isomer facilitates IC. The results show that the OH-pi isomer has a more rigid structure and a higher barrier for IC, making it harder to reach the geometric conical intersection through conformer rearrangement. This work enables us to have a good knowledge of how the structural preference induced by dispersion interactions affects excited state dynamics of the heteroaromatic compounds.

Recommanded Product: Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Wang, L; Zhang, S; Wang, Y; Zhang, B or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. Authors Oleszek, S; Kumagai, S; Grabda, M; Shiota, K; Yoshioka, T; Takaoka, M in ELSEVIER published article about in [Oleszek, Sylwia; Shiota, Kenji; Takaoka, Masaki] Kyoto Univ, Grad Sch Engn, Dept Environm Engn, Nishikyo Ku, Katsura C-1-3, Kyoto 6158540, Japan; [Oleszek, Sylwia; Grabda, Mariusz] Polish Acad Sci, Inst Environm Engn, M Sklodowska Curie 34, PL-41819 Zabrze, Poland; [Kumagai, Shogo; Yoshioka, Toshiaki] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, 6-6-07 Aoba, Sendai, Miyagi 9808579, Japan in 2021.0, Cited 44.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Polycarbonate (PC) is an engineering thermoplastic that is widely used in electrical and electronic equipment. This plastic often contains tetrabromobisphenol A (TBBA), the most common brominated flame retardant. Thermal degradation of the PC-TBBA leads to generation of numerous bromo-organic products in the pyrolytic oil, hindering its appropriate utilization, as well as corrosive hydrogen bromide gas. The purpose of this study was to experimentally investigate and compare the pyrolysis products of PC-TBBA and PC-TBBA + Cu2O at various temperatures, with an emphasis on the yield and distribution of brominated compounds. In pyrolysis of PC-TBBA + Cu2O, at the maximum degradation temperature (600 degrees C), as much as 86% of total Br was trapped in the residue, while 3% and 11% were distributed in the condensate and gas fractions, respectively. In contrast, the distribution of Br from non-catalytic pyrolysis of PC-TBBA (600 degrees C) was 0.5% residue, 40% condensate, and 60% gas. The results of this study revealed that in the presence of Cu2O, organo-bromine products were most likely involved in Ullman-type coupling reactions, leading to early cross-linking of the polymer network that efficiently hinders their vaporization. HBr in the gas fraction was suppressed due to effective fixation of bromine in residue in the form of CuBr.

Welcome to talk about 101-84-8, If you have any questions, you can contact Oleszek, S; Kumagai, S; Grabda, M; Shiota, K; Yoshioka, T; Takaoka, M or send Email.. Recommanded Product: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

I found the field of Thermodynamics; Energy & Fuels; Engineering very interesting. Saw the article Experimental and modeling study of benzaldehyde oxidation published in 2020.0. Recommanded Product: Diphenyl oxide, Reprint Addresses Battin-Leclerc, F (corresponding author), Univ Lorraine, CNRS, Lab React & Genie Proc, 1 Rue Grandville, F-54000 Nancy, France.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Benzaldehyde is an aromatic aldehyde commonly considered in bio-oil surrogate formulation, and an important intermediate in the oxidation of other aromatic reference fuels such as toluene. However, its oxidation has never been previously investigated experimentally and no product formation profiles were reported in the very limited pyrolysis studies available in the literature. In this study, the gas-phase oxidation of benzaldehyde was investigated in a jet-stirred reactor. 48 species were detected using gas chromatography, mainly CO, CO2 and phenol. The important formation of CO and phenol indicates a rapid formation of phenyl radicals. This was confirmed by a kinetic analysis performed using the current version of the CRECK kinetic model, in which the reactions of phenyl radicals and oxygenated aromatic compounds have been updated. (C) 2019 The Authors. Published by Elsevier Inc. on behalf of The Combustion Institute.

Recommanded Product: Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Namysl, S; Pelucchi, M; Maffei, LP; Herbinet, O; Stagni, A; Faravelli, T; Battin-Leclerc, F or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Sun, P; Yang, JJ; Chen, CX; Xie, KJ; Peng, JS in SPRINGER published article about SUPPORTED PALLADIUM NANOPARTICLES; SUZUKI-MIYAURA; C-C; SCHIFF-BASE; BACTERIAL CELLULOSE; REUSABLE CATALYST; HIGHLY EFFICIENT; HETEROGENEOUS CATALYST; GOLD NANOPARTICLES; ORGANIC FRAMEWORK in [Sun, Peng; Yang, Jiaojiao; Chen, Chunxia; Xie, Kaijun; Peng, Jinsong] Northeast Forestry Univ, Coll Chem Chem Engn & Resource Utilizat, Harbin 150040, Heilongjiang, Peoples R China; [Sun, Peng; Chen, Chunxia] Northeast Forestry Univ, Mat Sci & Engn Coll, Harbin 150040, Heilongjiang, Peoples R China in 2020.0, Cited 64.0. Computed Properties of C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

A green recyclable cellulose-supported Pd(salen)-type catalyst was synthesized through sequential three steps: chlorination with thionyl chloride, modification by ethylenediamine, and the formation of Schiff base with salicylaldehyde to immobilize palladium chloride through multiple binding sites. This novel heterogeneous cellulosic Pd(salen)-type catalytic complex was fully characterized by FT-IR, SEM, TEM, XPS, ICP-AES and TG. The traditional cross-coupling chemistry, such as Suzuki, Heck, Sonogashira, Buchwald-Hartwig amination and etherification, was then investigated in the presence of the above cellulose-palladium nanoparticle. Studies have shown that the synthesized catalyst shows high activity and efficiency for all types of transformations, providing the corresponding carbon-carbon or carbon-heteroatom coupling products in a general and mild manner. Furthermore, the catalyst demonstrates high to excellent yields and is easily recycled by simple filtration for up to twelve cycles without any significant loss of catalytic activity. [GRAPHICS] .

Computed Properties of C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recently I am researching about C-O BONDS; LIGNIN MODEL COMPOUNDS; TRANSFER HYDROGENATION; GAMMA-VALEROLACTONE; LEVULINIC ACID; ARYL ETHERS; BIOMASS; CONVERSION; HYDRODEOXYGENATION; DEPOLYMERIZATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21673249, 21733011]; National Key Research and Development Program of China [2017YFA0403103]; Beijing Municipal Science & Technology CommissionBeijing Municipal Science & Technology Commission [Z181100004218004]; Chinese Academy of SciencesChinese Academy of Sciences [QYZDY-SSW-SLH013]; Youth Innovation Promotion Association of CAS [2017043]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Hua, MT; Song, JL; Xie, C; Wu, HR; Hu, Y; Huang, X; Han, BX. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Category: ethers-buliding-blocks

Cleavage of aromatic ether bonds is a key step for lignin valorization, and the development of novel heterogeneous catalysts with high activity is crucial. Herein, bifunctional Ru/hydroxyapatite has been prepared via ion exchange and subsequent reduction. The obtained Ru/hydroxyapatite could efficiently catalyze the cleavage of various compounds containing aromatic ether bonds via transfer hydrogenolysis without additional bases. Systematic studies indicated that the basic nature of hydroxyapatite and electron-enriched Ru sites resulted in the high activity of the catalyst. A mechanism study revealed that the direct cleavage of aromatic ether bonds was the main reaction pathway.

Category: ethers-buliding-blocks. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Detection Method of Environmentally Friendly Non-POP PBDEs by Derivatization-Enhanced Raman Spectroscopy Using the Pharmacophore Model WOS:000488975800007 published article about POLYBROMINATED DIPHENYL ETHERS; MOLECULAR DOCKING; BIOLOGICAL TOXICITY; 3D QSAR; IDENTIFICATION; 3D-QSAR; EXTRACTION; INHIBITORS; SEDIMENTS; EXPOSURE in [Zhang, Shujing; Qiu, Youli; Li, Yu] North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China in 2019.0, Cited 33.0. Quality Control of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Background: Polybrominated diphenyl ethers (PBDEs) are dangerous for the environment and human health because of their persistent organic pollutant (POP) characteristics, which have attracted extensive research attention. Raman spectroscopy is a simple highly sensitive detection operation. This study was performed to obtain environmentally friendly non-POP PBDE derivatives with simple detection-based molecular design and provide theoretical support for establishing enhanced Raman spectroscopic detection techniques. Methods: A three-dimensional quantitative structure-activity relationship (3DQSAR) pharmacophore model of characteristic PBDE Raman spectral was established using 20 and 10 PBDEs as training and test sets, respectively. Full-factor experimental design was used to modify representative commercial PBDEs, and their flame retardancy and POP characteristics were evaluated. Results: The pharmacophore model (Hypol) exhibited good predictive ability with the largest correlation coefficient (R-2) of 0.88, the smallest root mean square (RMS) value of 0.231, and total cost of 81.488 with a configuration value of 12.56 (<17).74 monosubstituted and disubstituted PBDE derivatives were obtained based on the Hypo 1 pharmacophore model and full-factor experimental design auxiliary. Twenty PBDE derivatives were screened, and their flame-retardant capabilities were enhanced and their migration and bio-concentration were reduced (log(K-OW) <5), with unchanged toxicity and high biodegradability. The Raman spectral intensities increased up to 380%. In addition, interference analysis of the Raman peaks by group frequency indicated that the 20 PBDE derivatives were easily detected with no interference in gaseous environments. Conclusion: Nine pharmacophore models were constructed in this study; Hypo 1 was the most accurate. Twenty PBDE derivatives showed Raman spectral intensities increased up to 380%; these were classified as new non-POP environmentally friendly flame retardants with low toxicity, low migration, good biodegradability, and low bio-concentrations. 2D QSAR analysis showed that the most positive Milliken charge and lowest occupied orbital energy were the main contributors to the PBDE Raman spectral intensities. Raman peak analysis revealed no interference between the derivatives in gaseous environments. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Quality Control of Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recently I am researching about MICROENCAPSULATION, Saw an article supported by the ANRTFrench National Research Agency (ANR); Takasago Europe Perfumery Laboratory; CNRSCentre National de la Recherche Scientifique (CNRS)European Commission; Universite de Bordeaux; INP [2014/1309]. Published in SPRINGER in NEW YORK ,Authors: Stasse, M; Ribaut, T; Heroguez, V; Schmitt, V. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Application In Synthesis of Diphenyl oxide

We aim at encapsulating fragrances made of a variety of lipophilic species to slow down their diffusion. Our strategy is to develop capsules by polymerizing the water intermediate phase of an oil-in-water-in-oil double emulsion. In other terms, our system consists in a direct emulsion of fragrance (O1) in a water phase (W) containing monomer, initiator, and cross-linker. To obtain the double emulsion, this direct emulsion, stabilized by a hydrophilic surfactant, is itself dispersed in an external lipophilic solvent used in perfumery (O2) and stabilized by a lipophilic surfactant. Polymerization of the intermediate water phase aims at obtaining a 3D network. Differently from nowadays-proposed capsules, this strategy allows polymerization only taking place in the water phase rather in the phase containing the fragrance. Moreover, the obtained 3D network is supposed to play the role of an effective barrier limiting the diffusion of the inner lipophilic species towards either the external solvent or air. Such an approach implies the combination of a formulation step to elaborate the double emulsion using two antagonistic surfactants, a hydrophilic one and a lipophilic one, and of the polymerization of the intermediate phase. Insertion of the polymerizable species in the double emulsion shall not destabilize it. Some monomers exhibiting interfacial affinity and interfering with the formulation of the double emulsion have to be avoided. By varying the nature of the monomers and the cross-linker to monomer ratio, capsules with high encapsulation efficiencies and with various mechanical properties have been obtained.

Application In Synthesis of Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Stasse, M; Ribaut, T; Heroguez, V; Schmitt, V or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Safety of Diphenyl oxide. Issa, MY; Mohsen, E; Younis, IY; Nofal, ES; Farag, MA in [Issa, Marwa Y.; Mohsen, Engy; Younis, Inas Y.; Farag, Mohamed A.] Cairo Univ, Fac Pharm, Pharmacognosy Dept, Cairo 11562, Egypt; [Farag, Mohamed A.] Amer Univ Cairo, Sch Sci & Engn, Chem Dept, New Cairo, Egypt; [Nofal, Eman S.] MAG Co Essential Oils & Aromat, Mashal, Basyoun, Egypt published Volatiles distribution in jasmine flowers taxa grown in Egypt and its commercial products as analyzed via solid-phase microextraction (SPME) coupled to chemometrics in 2020.0, Cited 37.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Jasmine is one of the most valuable commercial oil bearing plants from family Oleaceae used for the production of jasmine scent mostly in the form of concrete and absolute. Being an export commodity, development of reliable analytical methods for its jasmine species and derived products authentication and or adulterants detection should now follow. A comparative volatiles profiling of Jasminum grandiflorum L., J. multiflorum (Burm. f.) Andrews and J. sambac (L.) Aiton flowers in addition to J. grandiflorum products viz., concrete and absolute at different time periods was performed using solid phase microextraction (SPME) coupled to GC/MS. A total of 77 volatiles were identified belonging to esters, alcohols, sesquiterpenes, ketones, aldehydes, phenols, hydrocarbons and nitrogenous compounds. The phenylpropanoid/benzenoid and terpenoid classes were the major volatile classes in jasmine. Benzyl acetate was the chief scent volatile whereas major terpenoids included linalool, nerolidol, alpha-farnesene and cis-jasmone. Results revealed aroma variation among different flowers and products obtained from J. grandiflorum at different months. This study provides the first comprehensive and comparative aroma profile for Egyptian Jasminum species along with its products that could be used for its future quality control in industry.

Safety of Diphenyl oxide. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem