Category: 101-84-8

In 2020.0 ENVIRON RES published article about BROMINATED FLAME RETARDANTS; POLYCHLORINATED-BIPHENYLS PCBS; THYROID-HORMONE LEVELS; POTENTIAL HEALTH-RISK; WASTE RECYCLING AREA; METABOLITES OH-PBDES; IN-HOUSE DUST; UK HUMAN-MILK; BREAST-MILK; CORD-BLOOD in [Wu, Zhineng; Song, Jie; Li, Huijun; Wu, Weidong] Xinxiang Med Univ, Sch Publ Hlth, Xinxiang 453003, Henan, Peoples R China; [He, Chang] Univ Queensland, QAEHS, Brisbane, Qld 4102, Australia; [Han, Wei] Northeast Agr Univ, Coll Resources & Environm, Harbin 150030, Peoples R China; [Zhang, Yadi] Nankai Univ, Tianjin Key Lab Environm Remediat & Pollut Contro, Key Lab Pollut Proc & Environm Criteria, Coll Environm Sci & Engn,Minist Educ, Tianjin 300350, Peoples R China; [Jing, Xiaohua] Anyang Normal Univ, Sch Chem & Chem Engn, Anyang 455002, Peoples R China in 2020.0, Cited 241.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Category: ethers-buliding-blocks

Polybrominated diphenyl ethers (PBDEs) are extensively used as brominated flame retardants (BFRs) in different types of materials, which have been listed as Persistent Organic Pollutants (POPs) by the Stockholm Convention in 2009 and 2017. Due to their ubiquities in the environment and toxicities, PBDEs have posed great threat to both human health and ecosystems. The aim of this review is to offer a comprehensive understanding of the exposure pathways, levels and trends and associated health risks of PBDEs in human body in a global scale. We systematically reviewed and described the scientific data of PBDE researches worldwide from 2010 to March 2020, focusing on the following three areas: (1) sources and human external exposure pathways of PBDEs; (2) PBDE levels and trends in humans; (3) human data of PBDEs toxicity. Dietary intake and dust ingestion are dominant human exposure pathways. PBDEs were widely detected in human samples, especially in human serum and human milk. Data showed that PBDEs are generally declining in human samples worldwide as a result of their phasing out. Due to the common use of PBDEs, their levels in humans from the USA were generally higher than that in other countries. High concentrations of PBDEs have been detected in humans from PBDE production regions and e-waste recycling sites. BDE-47, -153 and -99 were proved to be the primary congeners in humans. Human toxicity data demonstrated that PBDEs have extensively endocrine disruption effects, developmental effects, and carcinogenic effects among different populations.

Welcome to talk about 101-84-8, If you have any questions, you can contact Wu, ZN; He, C; Han, W; Song, J; Li, HJ; Zhang, YD; Jing, XH; Wu, WD or send Email.. Category: ethers-buliding-blocks

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Recommanded Product: Diphenyl oxide. In 2020.0 APPL CATAL B-ENVIRON published article about POLYBROMINATED DIPHENYL ETHERS; GRAPHITIC CARBON NITRIDE; REDUCTIVE DEBROMINATION; HYDROGEN-PRODUCTION; TETRABROMODIPHENYL ETHERS; DECABROMODIPHENYL ETHER; AQUEOUS-SOLUTIONS; DEGRADATION; TIO2; KINETICS in [Lei, Ming; Wang, Zhiying; Nie, Wenshan; Tang, Heqing] South Cent Univ Nationalities, Coll Resources & Environm Sci, Wuhan 430074, Hubei, Peoples R China; [Zhu, Lihua] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China in 2020.0, Cited 57.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Deep debromination of polybrominated diphenyl ethers (PBDEs) by visible light photocatalysis is still a challenge in the field of halogenated pollutants control. Here, an efficient photocatalyst (Pd/g-C3N4) was prepared by a simple impregnation-chemical reduction method with bulk g-C3N4 and PdCl2 as precursors. Under preferred reaction conditions (visible light irradiation for 120 min), the use of the 0.5% Pd/g-C3N4 composites (0.4 g L-1) yielded an almost complete debromination of BDE47 (10 mu mol L-1) in methanol-water mixture, while the debromination of BDE47 did not occur on pure g-C3N4. A Pd-promoted active H atom species attack and C-Br bond cleavage route was proposed according to the identified degradation intermediates. A catalytic mechanism was further clarified: Pd nanoparticles exerted affinity interaction with bromine atoms, and the storing of electrons on Pd would increase the binding interaction. In the debromination process, methanol acts as both a hole scavenger and a hydrogen donor to provide active H atom species through the reaction of H+ and photogenerated electrons on Pd nanoparticles. The initiation of BDE47 debromination on Pd nanoparticles required an induction period to enrich a critical amount of electrons for stretching the C-Br bond and its subsequent being attacked by active H atoms. The generated 2,2′-dibromodiphenyl ether (BDE4) would be further reduced to bromine-free products by hydro-debromination process or coupling reaction.

Welcome to talk about 101-84-8, If you have any questions, you can contact Lei, M; Wang, ZY; Zhu, LH; Nie, WS; Tang, HQ or send Email.. Recommanded Product: Diphenyl oxide

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Authors Farzana, S; Ruan, YF; Wang, Q; Wu, RB; Kai, Z; Meng, Y; Leung, KMY; Lam, PKS in PERGAMON-ELSEVIER SCIENCE LTD published article about PEARL RIVER DELTA; POLYBROMINATED DIPHENYL ETHERS; CHAIN CHLORINATED PARAFFINS; PERSONAL CARE PRODUCTS; ALTERNATIVE FLAME RETARDANTS; ORGANIC UV-FILTERS; SPATIAL-DISTRIBUTION; PHTHALATE-ESTERS; FRESH-WATER; PERFLUOROALKYL SUBSTANCES in [Farzana, Shazia; Ruan, Yuefei; Wang, Qi; Wu, Rongben; Kai, Zhang; Meng, Yan; Leung, Kenneth M. Y.; Lam, Paul K. S.] City Univ Hong Kong, State Key Lab Marine Pollut SKLMP, Hong Kong, Peoples R China; [Wang, Qi; Wu, Rongben; Lam, Paul K. S.] City Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China; [Leung, Kenneth M. Y.] Univ Hong Kong, Swire Inst Marine Sci, Pokfulam Rd, Hong Kong, Peoples R China; [Leung, Kenneth M. Y.] Univ Hong Kong, Sch Biol Sci, Pokfulam Rd, Hong Kong, Peoples R China; [Ruan, Yuefei; Kai, Zhang; Meng, Yan; Leung, Kenneth M. Y.; Lam, Paul K. S.] Southern Marine Sci & Engn Guangdong Lab Zhuhai, Zhuhai, Peoples R China in 2020.0, Cited 129.0. SDS of cas: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

This study aimed to establish marine water quality criteria (MWQC) for emerging chemicals of concern (ECCs) for protecting aquatic life in the Greater Bay Area (GBA) of South China. Despite the frequent occurrence and elevated concentrations of these ECCs in the GBA, there is a lack of regional MWQC for these contaminants. We screened 21 common ECCs that were classified into the following six groups: (1) new persistent organic contaminants; (2) brominated flame retardants; (3) perfluoroalkyl and polyfluoroalkyl substances; (4) pharmaceutically active compounds (PhACs); (5) plasticizers; and (6) personal care products. Globally, MWQC for PhACs remain largely unavailable despite their increasing occurrence in marine environments. Using an integrative scientific approach, we derived interim MWQC for the GBA with specific protection goals. The approach described herein can be applied for the derivation of MWQC for ECCs and the establishment of guidelines for ecological risk assessment in the GBA and other regions.

SDS of cas: 101-84-8. Welcome to talk about 101-84-8, If you have any questions, you can contact Farzana, S; Ruan, YF; Wang, Q; Wu, RB; Kai, Z; Meng, Y; Leung, KMY; Lam, PKS or send Email.

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Category: ethers-buliding-blocks. Authors Sun, J; Hang, TJ; Cao, L; Fan, XL; Feng, YL; Tan, L; Li, KY; Wang, QY; Liu, YX; Yang, GJ in ELSEVIER SCI LTD published article about in [Sun, Jing; Hang, Taijun; Li, Keyu; Wang, Qinyi; Liu, Yingxiang; Yang, Gongjun] China Pharmaceut Univ, Key Lab Drug Qual Control & Pharmacovigilance, Sch Pharm, Minist Educ, Nanjing 211198, Peoples R China; [Sun, Jing; Cao, Ling; Fan, Xialei; Feng, Youlong; Tan, Li] Jiangsu Inst Food & Drug Control, Nanjing 210019, Peoples R China in 2021.0, Cited 69.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

China produces and consumes large quantities of brominated flame retardants (BFRs) as well as several other unregulated electronic waste recycling activities, causing high BFR concentrations in the natural environment. Thus, Traditional Chinese Medicines (TCMs) may be contaminated by legacy BFRs (e.g. polybrominated diphenyl ethers (PBDEs)) and emerging BFRs (eBERs, such as decabromodiphenyl ethane (DBDPE)) during growth, processing, packaging, and transportation. Pheretima, which is a typical animal drug recorded in Chinese Pharmacopoeia, was used as an example to evaluate human exposure to BFRs through TCM intake. This study is the first to determine 25 PBDEs and 5 eBERs in Pheretima and estimate the daily BFR intake via Pheretima-containing TCMs. Twenty-seven Shanghai Pheretima and fifty-one Guang Pheretima samples were collected between March and June 2019 in southeast China. High BFR detection frequencies were found in Pheretima, of which BDE-209 and DBDPE were the most predominant analytes. The total PBDE contents ranged from 73 pg/g to 8,725 pg/g, while that of the eBERs varied between 115 pg/g and 2,824 pg/g. The profiles and abundances were found to be species- and origin-dependent. However, the traditional processing of Pheretima may reduce BFR residues. Based on the usual clinical doses of Pheretima and the available chronic oral reference doses of BDE-47, 99, 153, and 209, the mean (95th percentile) of the total hazard quotient was estimated to be 9.1 x 10(-5) (2.7 x 10(-4)). Therefore, there is little risk related to BFR exposure for patients taking formulated Pheretima-containing TCMs. However, it is necessary to establish routine monitoring programs for the co-existence of pollutants in TCMs to perform a systematic and comprehensive risk assessment. (C) 2021 Elsevier Ltd. All rights reserved.

Welcome to talk about 101-84-8, If you have any questions, you can contact Sun, J; Hang, TJ; Cao, L; Fan, XL; Feng, YL; Tan, L; Li, KY; Wang, QY; Liu, YX; Yang, GJ or send Email.. Category: ethers-buliding-blocks

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In 2019.0 J AM CHEM SOC published article about BOND-DISSOCIATION ENERGIES; HYDROGEN-ATOM ABSTRACTION; DIRECT ARYLATION; ACTIVATION; OXIDATION; PHOTOCATALYSIS; REACTIVITY; 1,2-DIOLS; RADICALS; SUGARS in [Dimakos, Victoria; Su, Hsin Y.; Garrett, Graham E.; Taylor, Mark S.] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada in 2019.0, Cited 53.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. SDS of cas: 101-84-8

Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by C-C bond formation with net retention of configuration, are obtained. Computational modeling supports a mechanism involving formation of a tetracoordinate borinic ester, which accelerates hydrogen atom transfer with the quinuclidine-derived radical cation through polarity-matching and/or ion-pairing effects.

SDS of cas: 101-84-8. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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SDS of cas: 101-84-8. Authors Gorginpour, F; Zali-Boeini, H in ELSEVIER published article about in [Gorginpour, Forough; Zali-Boeini, Hassan] Univ Isfahan, Dept Chem, Esfahan 8174673441, Iran in 2021, Cited 72. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

A quinoxaline-based porous organic polymer (Q-POP) as a mesoporous organic copolymer was developed as a new platform for the immobilization of CuNPs and copper nanocrystals. The prepared materials were characterized by FT-IR, XRD, N-2 adsorption-desorption isotherms, ICP, TGA, SEM, HR-TEM, EDX, and single-crystal X-ray crystallography. The obtained catalyst presented extraordinary catalytic activity towards Ullmann C-O coupling reactions with high surface area, hierarchical porosity, and excellent thermal and chemical stability. Due to its high porosity, and synergistic effect of copper nanocrystals incorporated in the polymer composite, the as-synthesized catalyst was successfully utilized for the Ullmann C-O coupling reaction of phenols and different aryl halides to prepare various diaryl ether derivatives. All types of aryl halides (except aryl fluorides) were screened in the Ullmann C-O coupling reaction with phenols to produce diaryl ethers in good to excellent yields (70-97 %), and it was found that aryl iodides have the best results. Besides, due to the strong interactions between CuNPs, N, and O-atoms of quinoxaline moiety existing in the polymeric framework, the copper leaching from the support was not observed. Furthermore, the catalyst was recycled and reused for five consecutive runs without significant activity loss.

SDS of cas: 101-84-8. Welcome to talk about 101-84-8, If you have any questions, you can contact Gorginpour, F; Zali-Boeini, H or send Email.

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Application In Synthesis of Diphenyl oxide. Recently I am researching about TRANSITION-METAL DICHALCOGENIDES; HEAT-TRANSFER ENHANCEMENT; THERMOPHYSICAL PROPERTIES; OPTICAL-CONSTANTS; ETHYLENE-GLYCOL; TRANSFER FLUIDS; CONDUCTIVITY; EFFICIENT; PERFORMANCE; INTERFACE, Saw an article supported by the Ministerio de Ciencia, Innovacion y Universidades of the Spanish Government [RTI2018-096393-B-I00, UNCA15-CE-2945]; EU COSTEuropean Cooperation in Science and Technology (COST) [COST-CA15119-STSM-42437, COST-CA15119-STSM-42461]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Martinez-Merino, P; Sani, E; Mercatelli, L; Alcantara, R; Navas, J. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Nanofluids are colloidal systems based on the suspension of nanoparticles in a fluid. Their thermal properties mean that they are promising heat transfer fluids with possible applications in different fields, concentrating solar energy being one of particular interest. Thus, this study presents the preparation of nanofluids based on WSe2 nanoparticles suspended in the eutectic mixture of biphenyl and diphenyl oxide, which is a heat transfer fluid widely used in concentrating solar power plants. To this end, solvothermal synthesis was used to prepare WSe2 nanosheets, which were characterized by means of scanning transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy. The physical and chemical stability of the nanofluids was analyzed, observing that they became more stable when Triton X-100 was used as the surfactant. The presence of WSe2 nanosheets did not result in a significant increase in density or viscosity) but, by contrast, improvements were obtained in their isobaric specific heat and thermal conductivity, up to 4.7 and 64%, respectively. Spectral optical properties were investigated as well, showing a significant effect of the WSe2 nanosheet addition to the extinction coefficient of the base fluid in the wavelength range of the solar spectrum, promising for direct absorption solar collectors. Finally, the efficiency of the nanofluids was analyzed in a solar collector considering the Ur parameter, obtaining a remarkable increase in the efficiency of up to 34% with respect to the pure heat transfer fluid. This proves the possibility to obtain a sustainable production of energy from the sun using these WSe2-based nanofluids.

Welcome to talk about 101-84-8, If you have any questions, you can contact Martinez-Merino, P; Sani, E; Mercatelli, L; Alcantara, R; Navas, J or send Email.. Application In Synthesis of Diphenyl oxide

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An article 3-(Ethoxycarbonyl)-1-(5-methyl-5-(nitrosooxy)hexyl)pyridin-1-ium cation: A green alternative to tert-butyl nitrite for synthesis of nitro-group-containing arenes and drugs at room temperature WOS:000517855700004 published article about IONIC LIQUIDS OILS; ORTHO-NITRATION; STEREOSELECTIVE NITRATION; REGIOSPECIFIC SYNTHESIS; AROMATIC SULFONAMIDES; EFFICIENT SYNTHESIS; IPSO-NITRATION; METAL; NITROOLEFINS; NITROARENES in [Natarajan, Palani] Panjab Univ, Dept Chem, Chandigarh 160014, India; Panjab Univ, Ctr Adv Studies Chem, Chandigarh 160014, India in 2020.0, Cited 67.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Category: ethers-buliding-blocks

Due to their remarkable properties, task-specific ionic liquids have turned out to be progressively popular over the last few years in the field of green organic synthesis. Herein, for the first time, we report that a new task-specific nitrite-based ionic liquid such as 3-(ethoxycarbonyl)-1-(5-methyl-5-(nitrosooxy)hexyl) pyridin-1-ium bis(trifluoromethanesulfonyl)imides (TS-N-IL) derived from biodegradable ethyl nicotinate indeed acted as an efficient and eco-friendly reagent for the synthesis of highly valuable nitroaromatic compounds and drugs including nitroxynil, tolcapone, niclofolan, flutamide, niclosamide and nitrazepam. The bridging of an ionic liquid with nitrite group not only increases the yield and rate of direct C-N bond formation reaction but also allows easy product separation and recyclability of a byproduct. Nonvolatile nature, easy synthesis, merely stoichiometric need and mildness are a portion of the extra focal points of TS-N-IL while contrasted with tert-butyl nitrite an outstanding and highly-flammable reagent utilized largely in organic synthesis. (C) 2019 Elsevier Ltd. All rights reserved.

Category: ethers-buliding-blocks. Welcome to talk about 101-84-8, If you have any questions, you can contact Natarajan, P; Chaudhary, R; Rani, N; Sakshi; Venugopalan, P or send Email.

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HPLC of Formula: C12H10O. I found the field of Environmental Sciences & Ecology very interesting. Saw the article Associations of prenatal exposures to low levels of Polybrominated Diphenyl Ether (PBDE) with thyroid hormones in cord plasma and neurobehavioral development in children at 2 and 4 years published in 2019.0, Reprint Addresses Yuan, W (corresponding author), Fudan Univ, NHC Key Lab Reprod Regulat, Shanghai Inst Planned Parenthood Res, 779 Lao Hu Min Rd, Shanghai 200237, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

Background: Neurotoxic effects of Polybrominated Diphenyl Ethers (PBDEs) at low levels have not been well studied in human population, and whether the associations can be explained by thyroid hormones (THs) remains unclear. Objectives: We examined the associations of prenatal PBDE exposures with THs in cord plasma and neurobehavior of children at 2 and 4 years among general population in China. Methods: Participants were mother-child pairs in the Shanghai-Minhang Birth Cohort Study. Nine PBDE congeners and THs (thyroid stimulating hormone, total thyroxine, free thyroxine, total triiodothyronine, and free triiodothyronine) were determined in cord plasma. Child Behavior Checklist (CBCL/1.5-5) were completed by caregivers to assess children’s neurobehavioral development at 2 and 4 years. In the final analyses, 199 and 307 mother-child pairs at 2 and 4 years were included to examine associations of PBDEs with CBCL scores using Pearson-scale-adjusted Poisson regressions, and 339 subjects were included in linear regression models to investigate the associations between PBDEs and THs. Results: BDE-47 had the highest detection rate of 83.82% with the median concentration of 0.19 ng/g lipid, followed by BDE-28, -99, -100 and -153 with detection rates nearly 50%. We found positive associations between prenatal PBDE concentrations and children’s neurobehavior, including Somatic Complaints, Withdrawn, Sleep Problems and Internalizing Problems in girls, and Somatic Complaints and Attention Problems in boys. We also observed inverse associations of the sum of BDE-47, – 28, – 99, -100 and -153 with THs. However, by adding THs to the models examining associations between PBDEs and CBCL, the main results didn’t measurably change. Conclusions: This study adds new knowledge that prenatal PBDEs at low levels may be related to long-lasting behavioral abnormalities in children and reduced THs in cord plasma. However, the hypothesis that the neurotoxic impact of PBDEs may be explained by alterations in cord THs was not supported.

HPLC of Formula: C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Ji, HL; Liang, H; Wang, ZL; Miao, MH; Wang, X; Zhang, XT; Wen, S; Chen, AM; Sun, XW; Yuan, W or send Email.

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An article High pollutant exposure level of the largest European community of bottlenose dolphins in the English Channel WOS:000485216500001 published article about PORPOISES PHOCOENA-PHOCOENA; TOXIC EQUIVALENCY FACTORS; POLYBROMINATED DIPHENYL ETHERS; PERSISTENT ORGANIC POLLUTANTS; TURSIOPS-TRUNCATUS; POLYCHLORINATED-BIPHENYLS; NORTH-SEA; LIFETIME EXPOSURE; SOCIAL-STRUCTURE; RISK-ASSESSMENT in [Zanuttini, Cyrielle; Gally, Francois] GECC, Pl Justes, F-50130 Octeville, France; [Scholl, Georges; Eppe, Gauthier] Univ Liege, UR MolSys B6c, CART, B-4000 Liege, Belgium; [Thome, Jean-Pierre] Univ Liege, CART LEAE, Freshwater & Ocean Sci Unit reS FOCUS CART LEAE, B6C, Liege, Belgium; [Das, Krishna] Univ Liege, B6C, Freshwater & Ocean Sci Unit reS FOCUS Oceanol, Liege, Belgium in 2019.0, Cited 48.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Computed Properties of C12H10O

The objective of this study was to assess the levels of persistent organic pollutants (POPs) and mercury (T-Hg) in the blubber and skin, respectively, of the free-ranging bottlenose dolphins, Tursiops truncatus, from the Normanno-Breton Gulf, one of the largest identified coastal population in Europe. Among all the POPs analysed in this study, the Sigma NDL-PCBs were the most abundant compounds found in the blubber (mean: 1.33 x 10(5) -0.65 x 10(5) ng.g(-1) lipid weight (lw) for males and females respectively), followed by Sigma DDX (1.11 x 10(4) -4.67 x 10(3) ng.g(-1 )lw) > Sigma DL-PCBs (8.06 x 10(3)-2.62 x 10(3) ng.g(-1 )lw) >Sigma PBDEs (1.95 x 10(3) -0.64 x 10(3) ng.g(-1) lw) > dieldrin (1.86 x 10(3)-0.18 x 10(3) ng.g(-1 )lw) >Sigma endosulfan (405-62 ng.g(-1 )lw) > HCB (86-52 ng.g(-1 )lw) > Sigma HCHs (47-60 ng. g(-1) lw) >Sigma chlordane (24-0.97 ng.g(-1 )lw) >Sigma PCDFs (0.3-0.1 ng.g(-1 )lw) >Sigma PCDDs (0.06-0.05 ng.g(-1) lw). The T-Hg concentrations were highly variable between individuals (2.45 x 10(3) ng.g(-1) to 21.3 x 10(3) ng.g(-1) dry weight, dw). The reported concentrations are among the highest reported for cetaceans. We strongly recommend that the Normanno-Breton Gulf be a special area of conservation (cSAC) candidate because it contains the last large European population of bottlenose dolphins (rare or threatened within a European context) designated under the EC Habitats Directive.

Computed Properties of C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Zanuttini, C; Gally, F; Scholl, G; Thome, JP; Eppe, G; Das, K or send Email.

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Ether – Wikipedia,
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