Category: 101-84-8

SDS of cas: 101-84-8. Park, MS; Kim, FS in [Park, Min Soo; Kim, Felix Sunjoo] Chung Ang Univ, Sch Chem Engn & Mat Sci, Seoul 06974, South Korea published Synergistic Effects of Processing Additives and Thermal Annealing on Nanomorphology and Hole Mobility of Poly(3-hexylthiophene) Thin Films in 2019.0, Cited 41.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Control of the nanoscale molecular ordering and charge-carrier mobility of poly(3-hexylthiophene-2,5-diyl) (P3HT) was achieved by the combined use of processing additives and thermal annealing. Evaluation of four processing additives (1,8-octanedithiol (ODT), diphenyl ether (DPE), 1-chloronaphthalene (CN), and 1,8-diiodooctane (DIO), which are commonly used for the fabrication of organic solar cells, revealed that the nanoscale molecular ordering and, therefore, the charge-carrier mobility, are largely affected by the additives, as demonstrated by spectral absorption, X-ray diffraction, and atomic force microscopy. Thermal annealing selectively influenced the morphological changes, depending on the solubility of P3HT in the additive at high temperature. In the case of CN, in which P3HT can be dissolved at moderate temperature, significant molecular ordering was observed even without thermal annealing. For DIO, in which P3HT is only soluble at elevated temperature, the mobility reached 1.14 x 10(-1) cm(2) V-1 s(-1) only after annealing. ODT and DPE were not effective as processing additives in a single-component P3HT. This study provides insight for designing the processing conditions to control the morphology and charge-transport properties of polymers.

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Zhang, JH; Sudduth, B; Sun, JM; Wang, Y in [Zhang, Jianghao; Sudduth, Berlin; Sun, Junming; Wang, Yong] Washington State Univ, Gene & Linda Voiland Sch Chem Engn & Bioengn, Pullman, WA 99164 USA; [Wang, Yong] Pacific Northwest Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA published Hydrodeoxygenation of Lignin-Derived Aromatic Oxygenates Over Pd-Fe Bimetallic Catalyst: A Mechanistic Study of Direct C-O Bond Cleavage and Direct Ring Hydrogenation in 2021.0, Cited 34.0. Computed Properties of C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Hydrodeoxygenation of lignin-derived phenols could be achieved generally with three reaction pathways: tautomerization, direct ring hydrogenation and direct C-O bond cleavage. The former pathway has been extensively studied over Pd/Fe catalyst in liquid-phase reaction, however, the contribution of the latter two is yet subject to further investigations. In this report, a comparative study of direct C-O bond cleavage and direct ring hydrogenation reaction pathways is presented on Pd/Fe, Fe and Pd/C catalysts using diphenyl ether as modelling compound. Despite its much higher activation energy than direct ring hydrogenation, direct C-O bond cleavage is dominant over Pd/Fe with much higher rates than the monometallic analogues due to the synergic catalysis of Pd-Fe. Based on this study and our previous results, the detailed reaction network for HDO of diphenyl ether is proposed. [GRAPHICS] .

Computed Properties of C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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I found the field of Chemistry very interesting. Saw the article Dual ligand-promoted palladium-catalyzed nondirected C-H alkenylation of aryl ethers published in 2020.0. Quality Control of Diphenyl oxide, Reprint Addresses Zhu, Q (corresponding author), Zhejiang Univ Technol, Coll Biotechnol & Bioengn, Hangzhou 310014, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Direct C-H functionalization of aryl ethers remains challenging owing to their low reactivity and selectivity. Herein, a novel strategy for nondirected C-H alkenylation of aryl ethers promoted by a dual ligand catalyst was demonstrated. This catalytic system readily achieved the highly efficient alkenylation of alkyl aryl ethers (anisole, phenetole, n-propyl phenyl ether, n-butyl phenyl ether and benzyl phenyl ether), cyclic aryl ethers (1,4-benzodioxan, 2,3-dihydrobenzofuran, dibenzofuran), and diphenyl oxides. Moreover, the proposed methodology was successfully employed for the late-stage modification of complex drugs containing the aryl ether motif. Interestingly, the compounds developed herein displayed fluorescent properties, which would facilitate their biological applications.

Welcome to talk about 101-84-8, If you have any questions, you can contact Yin, B; Fu, ML; Wang, L; Liu, J; Zhu, Q or send Email.. Quality Control of Diphenyl oxide

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Authors Cuthbert, ENT; Vittoria, A; Cipullo, R; Busico, V; Budzelaar, PHM in WILEY-V C H VERLAG GMBH published article about ALPHA-AGOSTIC INTERACTIONS; OLEFIN-POLYMERIZATION; MOLECULAR CALCULATIONS; CHAIN; METAL; PROPYLENE; GROUP-4; ZIRCONIUM; MECHANISM; INSERTION in [Cuthbert, Eric N. T.; Budzelaar, Peter H. M.] Univ Manitoba, Dept Chem, 144 Dysart Rd, Winnipeg, MB R3T 2N2, Canada; [Cuthbert, Eric N. T.; Vittoria, Antonio; Cipullo, Roberta; Busico, Vincenzo; Budzelaar, Peter H. M.] Dutch Polymer Inst, POB 902, NL-5600 AX Eindhoven, Netherlands; [Vittoria, Antonio; Cipullo, Roberta; Busico, Vincenzo; Budzelaar, Peter H. M.] Univ Napoli Federico II, Dipartimento Sci Chim, Via Cintia, I-80126 Naples, Italy in 2020.0, Cited 74.0. Formula: C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

A series of 20 bis(phenolate-ether) ligands, in combination with Zr and Hf, was tested for performance in propene polymerization, focusing on molecular weight, stereoregularity and regioregularity of the resulting polymer. Ligand variation covers length of the aliphatic linker between the ligand halves, as well as steric bulk of the groups ortho to the phenolate oxygen. The linker length has a dramatic effect on MW: two-carbon linkers produce oligomers (M-n < 2.5 kDa) while three- and four-carbon linkers generate much higher MW (M-n typically 50-500 kDa). Stereoselectivity can be tuned using large, flat substituents in the o-phenolate position; tuning of regioselectivity is much harder. Hf catalysts are slower than their Zr analogs and do not work well with MAO/BHT (BHT = 2,6-di-tert-butyl-4-methylphenol); they are generally more selective (MW, stereo and regio). Density functional calculations agree fairly well with observed selectivities, supporting the involvement of a fac/fac coordinated active species. These O4 catalysts are considerably more flexible than e.g. metallocenes, making accurate prediction of PP microstructure a significant challenge. Formula: C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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Recently I am researching about POLYCYCLIC AROMATIC-HYDROCARBONS; MASS-SPECTROMETRY; IONIC LIQUIDS; SEPARATION; COLUMNS; SAMPLES, Saw an article supported by the . Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Xu, L; Bai, JC; Du, AQ; Yang, ZX; Wu, B. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Application In Synthesis of Diphenyl oxide

In this work, 1,4-diphenyltriphenylene-grafted (14.2%) polysiloxane (DPTP) was successfully synthesized and statically coated on capillary columns as a stationary phase for gas chromatography. The DPTP columns exhibited excellent efficiencies of 3646 plates m(-1) for a 30 m column and 3125 plates m(-1) for a 10 m column, as evidenced by naphthalene measurements at 120 degrees C, which demonstrated the good film-forming ability of DPTP. Thermogravimetric analysis showed that the weight of DPTP is reduced by 2% at 380 degrees C. Separation of the polyethylene pyrolysis product indicated that the maximum allowable operating temperature of the DPTP column is 360 degrees C. The moderate polarity of the DPTP column was investigated in terms of McReynolds constants. The DPTP column was utilized to separate analytes, including aromatic isomers, fatty acid esters, ethers, polycyclic aromatic hydrocarbons and their derivatives, and nitrogenous heterocyclic compounds, on the basis of the column’s strong pi-pi stacking, dipole-induced dipole, and dispersion interactions with solutes. In general, the DPTP column offers great potential as a novel stationary phase for separating various analytes due to its special structure and remarkable separation performance.

Welcome to talk about 101-84-8, If you have any questions, you can contact Xu, L; Bai, JC; Du, AQ; Yang, ZX; Wu, B or send Email.. Application In Synthesis of Diphenyl oxide

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Authors Chen, XZ; Chen, X; Qi, J; Liang, CH in ELSEVIER published article about CATALYTIC PERFORMANCE; SELECTIVE CONVERSION; ELECTRONIC-STRUCTURE; ACTIVATED CARBON; M-CRESOL; GUAIACOL; HYBRID; MO2C; HYDROGENATION; CARBURIZATION in [Liang, Changhai] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China; Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116012, Peoples R China in 2020.0, Cited 48.0. Safety of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

The controllable synthesis of molybdenum carbides with different phases by a facile and environmentally friendly method and understanding their structure-performance relationship are still challenges. In this work, lamellar beta-Mo2C and alpha-MoC1-x have been synthesized by a self-assembly synthetic route using Mo-dopamine as single source without any template and additive at a relatively low carburization temperature. The introduction of H-2 fortifies the reducibility of the system and accelerates the carburization process and phase transformation. The structure-performance relationship was also investigated in the hydrodeoxygenation (HDO) of diphenyl ether. Thereinto, beta-Mo2C exhibits 99.9% conversion and 95.2% selectivity to benzene, while alpha-MoC1-x shows only 74.6% conversion with 84.8% selectivity to benzene and 12.7% to O-containing product phenol at the same conditions. The superior HDO performance of beta-Mo2C can be attributed to the more active sites in beta-Mo2C than alpha-MoC1-x. beta-Mo2C with stronger thermostability exhibits long-term stability during the HDO process. The results show that beta-Mo2C is a promising catalyst for lignin valorization.

Safety of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Chen, XZ; Chen, X; Qi, J; Liang, CH or concate me.

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Recently I am researching about HYPERTHERMIA THERAPY; NANOPARTICLES; GRAPHENE; NANOFLUIDS; NANOSHEETS; CURCUMIN; SHEETS; AGENT; MOS2, Saw an article supported by the Ministry of Science and Technology of TaiwanMinistry of Science and Technology, Taiwan [106-2314-13-002-124-MY3, 107-2221-E-002-194-MY3]; Excellent Translational Medicine Research Projects of National Taiwan University College of Medicine [NSCCMOH-131-72]; National Taiwan University HospitalNational Taiwan University [NSCCMOH-131-72]. Published in MDPI in BASEL ,Authors: Hatamie, S; Shih, PJ; Chen, BW; Wang, IJ; Young, TH; Yao, DJ. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. HPLC of Formula: C12H10O

The design of novel materials to use simultaneously in an ocular system for driven therapeutics and wound healing is still challenging. Here, we produced nanocomposites of tungsten disulfide carriers with spherical cobalt ferrite nanoparticles (NPs) as core inside a cubic iron oxide NPs shell (WS2/s-CoFe2O4@c-Fe3O4). Transmission electron microscopy (TEM) confirmed that 10 nm s-CoFe2O4@c-Fe3O4 NPs were attached on the WS2 sheet surfaces. The cytotoxicity of the WS2 sheets and nanocomposites were evaluated on bovine cornea endothelial cells (BCECs) using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay for a duration of three days. The MTT assay results showed low toxicity of the WS2 sheets on BCECs by 67% cell viability at 100 mu g/mL in 24 h, while the nanocomposites show 50% cell viability in the same conditions. The magnetic resonance imaging (MRI) of nanocomposites revealed the excellent T-2-weighted imaging with an r(2) contrast of 108 mM(-1) S-1. The in vitro photothermal therapy based on WS2 sheets and WS2/s-CoFe2O4 @c-Fe3O4 nanocomposites using 808 nm laser showed that the maximum thermal energy dispatched in medium at different applied power densities (1200 mw, 1800, 2200, 2600 mW) was for 0.1 mg/mL of the sample solution. The migration assay of BCECs showed that the wound healing was approximately 20% slower for the cell exposed by nanocomposites compared with the control (no exposed BCECs). We believe that WS2/s-CoFe2O4@c-Fe3O4 nanocomposites have a synergic effect as photothermal therapy agents for eye diseases and could be a target in an ocular system using MRI.

HPLC of Formula: C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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Beteck, RM; Seldon, R; Jordaan, A; Warner, DF; Hoppe, HC; Laming, D; Khanye, SD in [Beteck, Richard M.; Khanye, Setshaba D.] Rhodes Univ, Div Pharmaceut Chem, Fac Pharm, ZA-6140 Grahamstown, South Africa; [Seldon, Ronnett] Univ Cape Town, Dept Chem, Drug Discovery & Dev Ctr H3 D, ZA-7701 Rondebosch, South Africa; [Jordaan, Audrey; Warner, Digby F.] Univ Cape Town, SAMRC NHLS UCT Mol Mycobacteriol Res Unit, Dept Pathol, ZA-7925 Observatory, South Africa; [Warner, Digby F.] Univ Cape Town, Inst Infect Dis & Mol Med, ZA-7925 Observatory, South Africa; [Warner, Digby F.] Univ Cape Town, Wellcome Ctr Infect Dis Res Africa, ZA-7925 Observatory, South Africa; [Hoppe, Heinrich C.] Rhodes Univ, Dept Biochem & Microbiol, Fac Sci, ZA-6140 Grahamstown, South Africa; [Hoppe, Heinrich C.; Laming, Dustin; Khanye, Setshaba D.] Rhodes Univ, Ctr Chemico & Biomed Res, ZA-6140 Grahamstown, South Africa published New Quinolone-Based Thiosemicarbazones Showing Activity Against Plasmodium falciparum and Mycobacterium tuberculosis in 2019.0, Cited 39.0. Name: Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Co-infection of malaria and tuberculosis, although not thoroughly investigated, has been noted. With the increasing prevalence of tuberculosis in the African region, wherein malaria is endemic, it is intuitive to suggest that the probability of co-infection with these diseases is likely to increase. To avoid the issue of drug-drug interactions when managing co-infections, it is imperative to investigate new molecules with dual activities against the causal agents of these diseases. To this effect, a small library of quinolone-thiosemicarbazones was synthesised and evaluated in vitro against Plasmodium falciparum and Mycobacterium tuberculosis, the causal agents of malaria and tuberculosis, respectively. The compounds were also evaluated against HeLa cells for overt cytotoxicity. Most compounds in this series exhibited activities against both organisms, with compound 10, emerging as the hit; with an MIC90 of 2 mu M against H37Rv strain of M. tuberculosis and an IC50 of 1 mu M against the 3D7 strain of P. falciparum. This study highlights quinolone-thiosemicarabazones as a class of compounds that can be exploited further in search of novel, safe agents with potent activities against both the causal agents of malaria and tuberculosis.

Welcome to talk about 101-84-8, If you have any questions, you can contact Beteck, RM; Seldon, R; Jordaan, A; Warner, DF; Hoppe, HC; Laming, D; Khanye, SD or send Email.. Name: Diphenyl oxide

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I found the field of Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences very interesting. Saw the article Formation of brown carbon on Fe-bearing clay from volatile phenol under simulated atmospheric conditions published in 2020.0. Name: Diphenyl oxide, Reprint Addresses Jin, X; Gu, C (corresponding author), Nanjing Univ, Sch Environm, State Key Lab Pollut Control & Resource Reuse, Nanjing 210023, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

Atmospheric brown carbon (BrC) has recently attracted great concerns due to its potential contribution to climate change. It was reported that dissolved Fe(III) species can act as an efficient oxidant to catalyze the polymerization of volatile phenol substances, subsequently forming atmospheric BrC in aerosols. Since Fe in the atmosphere is commonly associated with clay mineral dusts, the transformation of phenol substances on Fe-bearing clay mineral surface is potentially important for BrC formation. In this study, taking guaiacol as the model phenol substance, its brown carbon formation process was investigated on Fe(III) modified montmorillonite under different relative humidities (RHs). The spectroscopic features and compositions of the produced BrC were systematically characterized. The results demonstrated that the interface FeOH2+ is the key species to promote the polymerization of guaiacol, and RH plays a significant role to influence the surface acidity of clay and the gas-to-particle adsorption of guaiacol. The BrC was produced with the most abundance and variety under moderate RH (similar to 33%), while higher RH (similar to 100%) accelerated the polymerization rate. Since aerosol moisture content might not largely influence the hydroxylation states of the surface bearing Fe(III) species, it signifies the importance of clay associated Fe(III) to catalyze the BrC formation in varied conditions Our study highlights the importance of clay mineral dust on the formation of BrC, and reveals the brown carbon formation pathways under environmentally relevant conditions.

Name: Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Ling, JY; Sheng, F; Wang, Y; Peng, AP; Jin, X; Gu, C or send Email.

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Category: ethers-buliding-blocks. Erasmus, E in [Erasmus, E.] Univ Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa published Morphology-Dependent Ullmann C-O Arylation Using Cu2O Nanocrystals in 2020.0, Cited 29.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Five different copper-oxide nanocrystals were prepared by colloidal synthesis to form either cubic, octahedral, rhombic dodecahedral, truncated cubic, or fluffy sphere structures. These Cu-oxide nanocrystals were characterised using scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-vis. The SEM images show that the Cu2O nanocrystals are relatively uniform and all the crystals have a particle mean diameter below 1000 nm. The smallest particle mean diameter is 411 nm for the rhombic dodecahedral crystals, while the octahedral crystal displays the largest particle mean diameter of 864 nm. The XPS results indicate that the copper is primarily Cu(I)in Cu2O, but some as Cu(II)are also present. The apparent optical band gap energies could be determined from the optical properties of the five Cu-oxide nanocrystals, using the classical Tauc equation. The apparent optical band gap energies ranged between 2.04 and 2.14 eV. The Ullmann C-O coupling reaction was used to investigate the catalytic performance of the Cu-oxide nanocrystals. The fluffy sphere gave the highest % conversion, while the rhombic dodecahedral showed the lowest conversion.

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