Category: 101-84-8

An article Chan-Evans-Lam C-N Coupling Promoted by a Dinuclear Positively Charged Cu(II) Complex. Catalytic Performance and Some Evidence for the Mechanism of CEL Reaction Obviating Cu(III)/Cu(I) Catalytic Cycle WOS:000525806600001 published article about ARYLBORONIC ACIDS; COPPER(III) COMPLEXES; PHENYLBORONIC ACID; BORONIC ACIDS; BOND; ARYLATION; FRAMEWORK; PHENOLS; SPECTRA; METALS in [Akatyev, Nikolay; Il’in, Mikhail; Ilin, Mikhail, Jr.; Peregudova, Svetlana; Peregudov, Alexander; Buyanovskaya, Anastasiya; Dubovik, Alexander; Grinberg, Valerij; Pavlov, Alexander; Novikov, Valentin; Volkov, Ilya; Belokon, Yuri] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov St 28, Moscow 119991, Russia; [Kudryavtsev, Kirill] DI Mendeleyev Univ Chem Technol Russia, Miusskaya Sq 19, Moscow 125047, Russia; [Dubovik, Alexander] Russian Acad Sci, NM Emanuel Inst Biochem Phys, Kosygin St 4, Moscow 119334, Russia; [Orlov, Victor] Moscow MV Lomonosov State Univ, AN Belozersky Inst Phys Chem Biol, Leninskie Gory 1-40, Moscow 119991, Russia in 2020.0, Cited 56.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. SDS of cas: 101-84-8

In the present study, we report the synthesis of a series of copper(II) complexes with a wide range of ligands and their testing in the copper catalyzed Chan-Evans-Lam (CEL) coupling of aniline and phenylboronic acid. The efficiency of the coupling was directly connected with the ease of the reduction of Cu(II) to Cu(I) of the complexes. The most efficient catalyst was derived from 4-t-butyl-2,5-bis[(quinolinylimino)methyl]phenolate and two Cu(II) ions. Depending on the counter-anion nature and the concentration of the reaction mixture, the reaction can be directed to predominant C-N-bond formation. Forty-three derivatives of diphenylamine were prepared under the optimized conditions. The proposed mechanism of the catalysis was based on the reduction potential of a series of complexes, molecular weight measurements of the catalytic complex in MeOH and the kinetic studies of aniline and phenylboronic acid coupling. In addition, an H-1 NMR experiment in a sealed NMR tube, without external oxygen supply available, proved that no complete Cu(II) to Cu(I) conversion was observed under the condition, ruling out the usually accepted mechanism of the C-N coupling, which included the oxygenation of the intermediately formed Cu(I) complexes after the key step of C-N conversion had already been completed. Instead, a mechanism was proposed, involving an oxygen molecule coordinated to two copper ions in the key C-N bond formation without any detectable conversion of the Cu(II) complexes to Cu(I).

SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Akatyev, N; Il’in, M; Ilin, M; Peregudova, S; Peregudov, A; Buyanovskaya, A; Kudryavtsev, K; Dubovik, A; Grinberg, V; Orlov, V; Pavlov, A; Novikov, V; Volkov, I; Belokon, Y or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Diphenyl ether derivatives occupy the expanded binding site of cyclohexanedione compounds at the colchicine site in tubulin by movement of the alpha T5 loop WOS:000466254500013 published article about VASCULAR DISRUPTING AGENTS; INHIBITORS; COMPLEX; DESIGN in [Bueno, Oskia; Gargantilla, Marta; Jose Camarasa, Maria; Perez-Perez, Maria-Jesus; Priego, Eva-Maria] CSIC, IQM, Juan Cierva 3, Madrid 28006, Spain; [Estevez-Gallego, Juan; Fernando Diaz, J.] CSIC, CIB, Ramiro Maeztu 9, Madrid 28040, Spain; [Martins, Solange; Liekens, Sandra] Katholieke Univ Leuven, Rega Inst Med Res, Herestr 49, B-3000 Leuven, Belgium in 2019.0, Cited 39.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. SDS of cas: 101-84-8

Microtubule targeting agents represent a very active arena in the development of anticancer agents. In particular, compounds binding at the colchicine site in tubulin are being deeply studied, and the structural information recently available on this binding site allows structure-directed design of new ligands. Structural comparison of our recently reported high resolution X-Ray structure of the cyclohexanedione derivative TUB075 bound to tubulin and the tubulin-DAMA-colchicine complex has revealed a conformational change in the alpha T5 loop. By a grid-based computational analysis of the tubulin-DAMA-colchicine binding site, we have identified a new favourable binding area in the colchicine-site that was unexplored by our lead TUB075. Thus, based on a structure-guided design, new cyclohexanedione derivatives have been synthesized and tested for tubulin binding and in cellular assays. As a result, we have identified diphenyl ether derivatives with IC50 values around 10-40 nM against three different tumor cell lines and affinity constants for tubulin similar to that of colchicine around 10(7) M-1. As expected, they halted the cell cycle progression at G2/M phase at concentrations as low as 0.08 mu M. (C) 2019 Elsevier Masson SAS. All rights reserved.

About Diphenyl oxide, If you have any questions, you can contact Bueno, O; Gargantilla, M; Estevez-Gallego, J; Martins, S; Diaz, JF; Camarasa, MJ; Liekens, S; Perez-Perez, MJ; Priego, EM or concate me.. SDS of cas: 101-84-8

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

HPLC of Formula: C12H10O. In 2019.0 ENVIRON POLLUT published article about DIPHENYL ETHERS PBDES; MYTILUS-EDULIS; BLUE MUSSEL; PLASTIC CONTAMINATION; SPATIAL-DISTRIBUTION; MARINE-ENVIRONMENT; FRESH-WATER; FISH; SEDIMENTS; QUANTIFICATION in [Hermabessiere, Ludovic; Himber, Charlotte; Dehaut, Alexandre; Duflos, Guillaume] ANSES, Lab Secur Aliments, Blvd Bassin Napoleon, F-62200 Boulogne Sur Mer, France; [Paul-Pont, Ika; Cassone, Anne-Laure; Lambert, Christophe; Soudant, Philippe] IFREMER, Lab Sci Environm Marin LEMAR, Inst Univ Europeen Mer, UMR6539,UBO,CNRS,IRD, Technopole Brest Iroise,Rue Dumont dUrville, F-29280 Plouzane, France; [Receveur, Justine; Jezequel, Ronan] CEDRE, 715 Rue Alain Colas, F-29218 Brest 2, France; [El Rakwe, Maria] IFREMER, LDCM, Ctr Bretagne, ZI Pointe Diable, CS 10070, F-29280 Plouzane, France; [Rinnert, Emmanuel] IFREMER, Lab Cycle Geochim & Ressources LCG, Ctr Bretagne, ZI Pointe Diable, CS 10070, F-29280 Plouzane, France; [Riviere, Gilles] ANSES, Direct Evaluat Risques, 14 Rue Pierre & Marie Curie, F-94701 Maisons Alfort, France; [Huvet, Arnaud] IFREMER, Lab Sci Environm Marin LEMAR, UMR 6539, UBO,CNRS,IRD, F-29280 Plouzane, France in 2019.0, Cited 118.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Nowadays, environmental pollution by microplastics (<5 mm; MP) is a major issue. MP are contaminating marine organisms consumed by humans. This work studied MP contamination in two bivalve species of commercial interest: blue mussel (Mytilus edulis) and common cockle (Cerastoderma edule) sampled on the Channel coastlines (France). In parallel, 13 plastic additives and 27 hydrophobic organic compounds (HOC) were quantified in bivalves flesh using SBSE-TD-GS-MS/MS to explore a possible relationship between their concentrations and MP contamination levels. MP were extracted using a 10% potassium hydroxide digestion method then identified by mu-Raman spectroscopy. The proportion of contaminated bivalves by MP ranged from 34 to 58%. Blue mussels and common cockles exhibited 0.76 +/- 0.40 and 2.46 +/- 1.16 MP/individual and between 0.15 +/- 0.06 and 0.74 +/- 035 MP/g of tissue wet weight. Some HOC and plastic additives were detected in bivalves. However, no significant Pearson or Spearman correlation was found between MP loads and plastic additives or HOC concentrations in bivalve tissues for the two species. (C) 2019 Elsevier Ltd. All rights reserved. HPLC of Formula: C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2020 J CHEM THEORY COMPUT published article about HARMONIC VIBRATIONAL FREQUENCIES; SCALE FACTORS; ORGANIC LIQUIDS; SPECTROSCOPY; DENSITY; ENERGY; IR; FUNCTIONALS; COEFFICIENT; MOLECULES in [Henschel, Henning; Andersson, Alfred T.; Jespers, Willem; Ghahremanpour, Mohammad Mehdi; van der Spoel, David] Uppsala Univ, Uppsala Ctr Computat Chem, Dept Cell & Mol Biol, Sci Life Lab, SE-75124 Uppsala, Sweden; [Ghahremanpour, Mohammad Mehdi] Yale Univ, Dept Chem, 225 Prospect St, New Haven, CT 06520 USA in 2020, Cited 53. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Formula: C12H10O

Infrared spectroscopy can provide significant insight into the structures and dynamics of molecules of all sizes. The information that is contained in the spectrum is, however, often not easily extracted without the aid of theoretical calculations or simulations. We present here the calculation of the infrared spectra of a database of 703 gas phase compounds with four different force fields (CGenFF, GAFF-BCC, GAFF-ESP, and OPLS) using normal-mode analysis. Modern force fields increasingly use virtual sites to describe, e.g., lone-pair electrons or the o -holes on halogen atoms. This requires some adaptation of code to perform normal-mode analysis of such compounds, the implementation of which into the GROMACS software is briefly described as well. For the quantitative comparison of the obtained spectra with experimental reference data, we discuss the application of two different statistical correlation coefficients, Pearson and Spearman. The advantages and drawbacks of the different methods of comparison are discussed, and we find that both methods of comparison give the same overall picture, showing that present force field methods cannot match the performance of quantum chemical methods for the calculation of infrared spectra.

Formula: C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. In 2019.0 FIBER POLYM published article about RING-OPENING POLYMERIZATION; THERMAL-DEGRADATION; BIODEGRADABLE POLYMERS; MELT POLYCONDENSATION; MECHANICAL-PROPERTIES; CLINICAL-APPLICATIONS; POLYGLYCOLIC ACID; IN-VITRO; POLYLACTIDE; COMPOSITES in [Ayyoob, Muhammad; Yang, Xin; Kim, Ji Heung; Nam, Sung Woo; Kim, Young Jun] Sungkyunkwan Univ, Dept Chem Engn, Suwon 16419, South Korea; [Park, Ho-Joon; Park, Soo-young] Kyungpook Natl Univ, Dept Polymer Sci, Daegu 41566, South Korea in 2019.0, Cited 42.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

High molecular weight bioresorbable polyglactin was successfully synthesized by direct esterification of glycolic acid and lactic acid in diphenylether under vacuum. The reaction mixture was initially dehydrated at 120 degrees C, diphenylether and catalysts were added when the temperature was raised to 180 degrees C, meanwhile the reaction mixture was kept dehydrated azeotropically for several hours. Diphenylether was removed from reaction mixture using vacuum and white solid polyglactin was obtained after purification. The intrinsic viscosity of polyglactin was in a range of 0.6 to 1.10 dl/g. This synthesis process can be an economical alternative to the conventional synthesis of polyglactin.

Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Recommanded Product: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Spatial Distribution and Congener Profiles of Polybrominated Diphenyl Ethers in Surface Sediment from Sanmen Bay and Xiamen Bay, Southeast China WOS:000487648400015 published article about HALOGENATED FLAME RETARDANTS; WASTE RECYCLING AREA; MARINE-SEDIMENTS; POLYHALOGENATED CARBAZOLES; POLYCHLORINATED-BIPHENYLS; SOURCE IDENTIFICATION; ECOLOGICAL RISKS; RIVER ESTUARY; YELLOW-RIVER; PBDES in [Liu, Kunyan; Qiu, Yong; Wang, Xiaodong; Wang, Yan] Jinan Univ, Res Ctr Harmful Algae & Marine Biol, Guangzhou 510632, Guangdong, Peoples R China; [Qiu, Yong] Zhejiang Univ Technol, Coll Environm, Hangzhou 310032, Zhejiang, Peoples R China; [Lin, Kunde] Xiamen Univ, Coll Environm & Ecol, Fujian Prov Key Lab Coastal Ecol & Environm Studi, Xiamen 361102, Fujian, Peoples R China; [Chen, Da; Qu, Han; Hu, Yongxia] Jinan Univ, Sch Environm, Guangzhou 510632, Guangdong, Peoples R China; [Chen, Da; Qu, Han; Hu, Yongxia] Jinan Univ, Guangdong Key Lab Environm Pollut & Hlth, Guangzhou 510632, Guangdong, Peoples R China in 2019.0, Cited 54.0. Category: ethers-buliding-blocks. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Coastal areas are influenced by anthropogenic input of a variety of organic pollutants, among which polybrominated diphenyl ethers (PBDEs) represent an important group. In the present study, we investigated the contamination status of PBDEs in surface sediment from two economically important Bays in Southeast China, Sanmen Bay (SMB; n = 29) and Xiamen Bay (XMB; n = 10). Concentrations of n-ary sumation PBDEs ranged from 2.2 to 78.5 ng/g dw (median 5.7 ng/g dw) in SMB and 7.9-276.0 ng/g dw (median 43.5 ng/g dw) in XMB, respectively. A nearshore-offshore decreasing trend was observed for both n-ary sumation PBDEs and BDE-209 concentrations, indicating strong urban influences. Although the current levels would not produce any significant impact on benthos and aquatic ecosystems of the studied regions, continuous monitoring is needed to understand the temporal trends of contamination in the important coastal waters and whether sediment-associated PBDEs constitute a potential source to aquatic ecosystems.

Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.. Category: ethers-buliding-blocks

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Safety of Diphenyl oxide. I found the field of Chemistry very interesting. Saw the article Synthesis and investigation of sulfonated poly(p-phenylene)-based ionomers with precisely controlled ion exchange capacity for use as polymer electrolyte membranes published in 2020, Reprint Addresses Rikukawa, M (corresponding author), Sophia Univ, Dept Mat & Life Sci, Chiyoda Ku, 7-1 Kioi Cho, Tokyo 1028554, Japan.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

To achieve precise control of sulfonated polymer structures, a series of poly(p-phenylene)-based ionomers with well-controlled ion exchange capacities (IECs) were synthesised via a three-step technique: (1) preceding sulfonation of the monomer with a protecting group, (2) nickel(0) catalysed coupling polymerisation, and (3) cleavage of the protecting group of the polymers. 2,2-Dimethylpropyl-4-[4-(2,5-dichlorobenzoyl)phenoxy]benzenesulfonate (NS-DPBP) was synthesised as the preceding sulfonated monomer by treatment with chlorosulfuric acid and neopentyl alcohol. NS-DPBP was readily soluble in various organic solvents and stable during the nickel(0) catalysed coupling reaction. Sulfonated poly(4-phenoxybenzoyl-1,4-phenylene) (S-PPBP) homopolymer and seven types of random copolymers (S-PPBP-co-PPBP) with different IECs were obtained by varying the stoichiometry of NS-DPBP. The IECs and weight average molecular weights (M(w)s) of ionomers were in the range of 0.41-2.84 meq. g(-1) and 143 000-465 000 g mol(-1), respectively. The water uptake, proton conductivities, and water diffusion properties of ionomers exhibited a strong IEC dependence. Upon increasing the IEC of S-PPBP-co-PPBPs from 0.86 to 2.40 meq. g(-1), the conductivities increased from 6.9 x 10(-6) S cm(-1) to 1.8 x 10(-1) S cm(-1) at 90% RH. S-PPBP and S-PPBP-co-PPBP (4 : 1) with IEC values >2.40 meq. g(-1) exhibited fast water diffusion (1.6 x 10(-11) to 8.0 x 10(-10) m(2) s(-1)), and were comparable to commercial perfluorosulfuric acid polymers. When fully hydrated, the maximum power density and the limiting current density of membrane electrode assemblies (MEAs) prepared with S-PPBP-co-PPBP (4 : 1) were 712 mW cm(-2) and 1840 mA cm(-2), respectively.

Safety of Diphenyl oxide. About Diphenyl oxide, If you have any questions, you can contact Yoshida-Hirahara, M; Takahashi, S; Yoshizawa-Fujita, M; Takeoka, Y; Rikukawa, M or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Evaluation of three temperature- and mobile phase-dependent retention models for reversed-phase liquid chromatographic retention and apparent retention enthalpy WOS:000462106800009 published article about ORGANIC MODIFIER CONCENTRATION; GRADIENT ELUTION; ADSORPTION; SIMULATION; MECHANISM in [Horner, Anthony R.; Wilson, Rachael E.; Groskreutz, Stephen R.; Murray, Bridget E.; Weber, Stephen G.] Univ Pittsburgh, Chevron Sci Ctr, 219 Parkman Ave, Pittsburgh, PA 15260 USA in 2019, Cited 45. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Formula: C12H10O

Predicting retention and enthalpy allows for the simulation and optimization of advanced chromatographic techniques including gradient separations, temperature-assisted solute focusing, multidimensional liquid chromatography, and solvent focusing. In this paper we explore the fits of three expressions for retention as a function of mobile phase composition and temperature to retention data of 101 small molecules in reversed phase liquid chromatography. The three retention equations investigated are those by Neue and Kuss (NK) and two different equations by Pappa-Louisi et al., one based on a partition model (PL-P) and one based on an adsorption model (PL-A). More than 25 000 retention factors were determined for 101 small molecules under various mobile phase and temperature conditions. The pure experimental uncertainty is very small, approximately 0.22% uncertainty in retention factors measured on the same day (2.1% when performed on different days). Each of the three equations for ln(k) was fit to the experimental data based on a least-squares approach and the results were analyzed using lack-of-fit residuals. The PL-A model, while complex, gives the best overall fits. In addition to examining the equations’ adequacy for retention, we also examined their use for apparent retention enthalpy. This enthalpy can be predicted by taking the derivative of these expressions with respect to the inverse of absolute temperature. The numerical values of the fitted parameters based on retention data can then be used to predict retention enthalpy. These enthalpy predictions were compared to those obtained from a modified van ‘t Hoff equation that included a quadratic term in inverse temperature. Based on analysis of 1 211 van’t Hoff plots (solute-mobile phase-day combinations), ninety-eight percent showed a significantly better fit when using the modified van ‘t Hoff expression, justifying its use to provide apparent enthalpies as a function of mobile phase composition and temperature. The foregoing apparent enthalpies were compared to the apparent enthalpies predicted by the three models. The PL-A model, which contains a temperature dependent enthalpy, provided the best enthalpy prediction. However, there is virtually no correlation between the overall lack of fit to experimental ln(k) for each model and the corresponding lack of fit of the linear (in 1/T) van ‘t Hoff expression. Thus, the temperature-dependent enthalpy is apparently not the cause of a model’s ability to fit ln(k) as a function of mobile phase composition and temperature. The value in these expressions is their ability to predict chromatograms, allowing for optimization of an advanced chromatographic technique. The two simpler models NK and PL-P, which do not contain a temperature dependent enthalpy, have their merits in modelling retention (NK being the better of the two) and enthalpy (PL-P being the better of the two) if a simpler expression is required for a given application. (C) 2019 Elsevier B.V. All rights reserved.

Formula: C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Horner, AR; Wilson, RE; Groskreutz, SR; Murray, BE; Weber, SG or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recommanded Product: Diphenyl oxide. Stasse, M; Ribaut, T; Heroguez, V; Schmitt, V in [Stasse, Margot; Schmitt, Veronique] Univ Bordeaux, CNRS, UMR 5031, Ctr Rech Paul Pascal, Bordeaux, France; [Stasse, Margot; Heroguez, Valerie] Univ Bordeaux, CNRS, Lab Chim Polymeres Organ, UMR 5629, Bordeaux, France; [Ribaut, Tiphaine] Takasago Europe Perfumery Lab, 12 Rue Torricelli, F-75017 Paris, France published Elaboration of double emulsion-based polymeric capsules for fragrance in 2021.0, Cited 23.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

We aim at encapsulating fragrances made of a variety of lipophilic species to slow down their diffusion. Our strategy is to develop capsules by polymerizing the water intermediate phase of an oil-in-water-in-oil double emulsion. In other terms, our system consists in a direct emulsion of fragrance (O1) in a water phase (W) containing monomer, initiator, and cross-linker. To obtain the double emulsion, this direct emulsion, stabilized by a hydrophilic surfactant, is itself dispersed in an external lipophilic solvent used in perfumery (O2) and stabilized by a lipophilic surfactant. Polymerization of the intermediate water phase aims at obtaining a 3D network. Differently from nowadays-proposed capsules, this strategy allows polymerization only taking place in the water phase rather in the phase containing the fragrance. Moreover, the obtained 3D network is supposed to play the role of an effective barrier limiting the diffusion of the inner lipophilic species towards either the external solvent or air. Such an approach implies the combination of a formulation step to elaborate the double emulsion using two antagonistic surfactants, a hydrophilic one and a lipophilic one, and of the polymerization of the intermediate phase. Insertion of the polymerizable species in the double emulsion shall not destabilize it. Some monomers exhibiting interfacial affinity and interfering with the formulation of the double emulsion have to be avoided. By varying the nature of the monomers and the cross-linker to monomer ratio, capsules with high encapsulation efficiencies and with various mechanical properties have been obtained.

Recommanded Product: Diphenyl oxide. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Name: Diphenyl oxide. In 2020.0 MACROMOLECULES published article about ORGANIC SOLAR-CELLS; NON-FULLERENE ACCEPTORS; MORPHOLOGY; PERFORMANCE; POLYMER; DONOR in [Zhang, Xue; Wang, Hui; Li, Donghui; Chen, Mengxue; Mao, Yuchao; Du, Baocai; Zhuang, Yuan; Liu, Dan; Wang, Tao] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China; [Zhang, Xue; Wang, Hui; Li, Donghui; Chen, Mengxue; Mao, Yuchao; Du, Baocai; Zhuang, Yuan; Liu, Dan; Wang, Tao] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Peoples R China; [Tan, Wenliang; Huang, Wenchao] Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia; [Zhao, Yan] Wuhan Univ Technol, Int Sch Mat Sci & Engn, Wuhan 430070, Peoples R China in 2020.0, Cited 53.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

The molecular aggregation of nonfullerene acceptors (NFA) can significantly affect the light absorption, charge generation, and power conversion efficiency (PCE) of organic solar cells (OSCs). In this work, we demonstrate the regulation of J-aggregation of COi8DFIC NFA toward near- infrared absorption via solvent additives 1,8-diiodooctane (DIO), diphenyl ether (DPE), and 1-chloronaphthalene (CN). Molecular dynamics simulations reveal preferential interaction of DIO with the alkyl side chains of COi8DFIC, endowing side-chains with the flexibility to adjust conformations to promote the formation of A-to-D type J-aggregation among the COi8DFIC backbone, resulting in a significant red-shift of absorbance toward the near-infrared region. The enhanced J-aggregation via pi-pi stacking, evidenced by grazing-incidence wide-angle X-ray scattering, constructs three-dimensional charge transport channels at the molecular level to facilitate charge transport. The presence of 0.5 vol % DIO molecules, which is most effective among all three additives, boosts the maximum achievable PCE of CF cast PTB7-Th:COi8DFIC OSCs from 8.5% to 12.9%. Our results provide a new concept to enhance the efficiency of OSCs via dedicated control of molecular aggregations of nonfullerene acceptors.

Welcome to talk about 101-84-8, If you have any questions, you can contact Zhang, X; Wang, H; Li, DH; Chen, MX; Mao, YC; Du, BC; Zhuang, Y; Tan, WL; Huang, WC; Zhao, Y; Liu, D; Wang, T or send Email.. Name: Diphenyl oxide

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem