Category: 101-84-8

Product Details of 101-84-8. Authors Marin, IM; De Masi, D; Lacroix, LM; Fazzini, PF; van Leeuwen, PWNM; Asensio, JM; Chaudret, B in ROYAL SOC CHEMISTRY published article about in [Mustieles Marin, Irene; De Masi, Deborah; Lacroix, Lise-Marie; Fazzini, Pier-Francesco; van Leeuwen, Piet W. N. M.; Asensio, Juan M.; Chaudret, Bruno] Univ Toulouse, CNRS, LPCNO, INSA,UPS, 135 Ave Rangueil, F-31077 Toulouse, France; [Asensio, Juan M.] IFP Energies Nouvelles, Rond Point Echangeur Solaize, BP 3, F-69360 Solaize, France in 2021.0, Cited 54.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Bimetallic FeNi3 nanoparticles (NPs) enriched with Ni (FeNi3@Ni) have been used to perform the hydrodeoxygenation reaction (HDO) and cleavage of lignocellulose-derived products in solution using magnetic induction. The application of a high frequency magnetic field induces high temperatures at the surface of the NPs that drive the catalytic reaction. The activation of the C-O bond of several functional groups was studied. FeNi3@Ni NPs, which act both as catalysts and magnetic heating agents, catalyzed the total conversion of furfural and 5-hydroxymethyl furfural into respectively 2-methylfuran and 2,5-dimethylfuran under mild conditions (12 mol% catalyst, 3 bar H-2, 49 mT). The oligomerization of cyclopentanone, derived from furfural, was also achieved to yield C-10 and C-15 oligocyclopentyl products. Under the same conditions, diphenyl and benzyl phenyl ether, used as model molecules of polymeric lignin, were cleaved at 86% and 100% conversion respectively, to yield a mixture of hydrogenolysis and hydrogenated products. This is explained by the presence of Ni at the surface of the NP that favors the hydrogenation of the aromatic rings. The short reaction times and simplicity of the experimental set-up highlight the advantages of the application of magnetic heating for difficult transformations in solution, here the catalytic treatment of biomass-derived molecules.

Product Details of 101-84-8. Welcome to talk about 101-84-8, If you have any questions, you can contact Marin, IM; De Masi, D; Lacroix, LM; Fazzini, PF; van Leeuwen, PWNM; Asensio, JM; Chaudret, B or send Email.

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Application In Synthesis of Diphenyl oxide. I found the field of Chemistry very interesting. Saw the article Direct Immersion-Solid-Phase Microextraction Coupled to Gas Chromatography-Mass Spectrometry and Response Surface Methodology for Nontarget Screening of (Semi-) Volatile Migrants from Food Contact Materials published in 2020.0, Reprint Addresses Nerin, C (corresponding author), Univ Zaragoza, Dept Analyt Chem, EINA, GUIA Grp,I3A, Zaragoza 50018, Spain.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.

Toward a more rigorous inspection of food contact materials, the importance of sample preparation for nontarget screening should be addressed. Direct immersion-solid-phase microextraction coupled to gas chromatography mass spectrometry (DI-SPME-GC-MS) was optimized for nontarget screening of migrants in 3% acetic acid, 10% ethanol, and 95% ethanol food simulants by response surface methodology (RSM) in the present study. Optimum conditions were DVB/CAR/PDMS fiber, no pH adjustment for 10% and 95% ethanol simulant but pH adjustment to 7 for 3% acetic acid simulant, no salt addition, 5 min preincubation, 55 min extraction at 70 degrees C, and 8 min desorption at 250 degrees C. In addition, 9.5 times dilution of 95% ethanol samples prior to extraction was required. pH modification of 3% acetic acid samples was found to be critical for the extraction of amines. The proposed methodology was then evaluated by determining the limit of detection (LOD) as well as repeatability of 35 food contact materials-related substances. Except for those amines and diols which have a relatively high LOD, the LODs of the rest of the substances were 0.1-14.1 mu g/kg with a precision of 1.9-23.0% in 10% ethanol and were 0.1-20.2 mu g/kg with a precision of 2.5-19.6% in 3% acetic acid simulant. The LOD and precision in 95% ethanol simulant were 0.7-163.7 mu g/kg and 1.4-26.8%, respectively. The proposed method can be applied for an overall screening of migrants from these three simulants at even trace levels, though attention should be paid to some specific analytes, e.g., diols and amines, which could have a high LOD and toxicity.

About Diphenyl oxide, If you have any questions, you can contact Su, QZ; Vera, P; Nerin, C or concate me.. Application In Synthesis of Diphenyl oxide

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An article Exposure pathways, levels and toxicity of polybrominated diphenyl ethers in humans: A review WOS:000541251900007 published article about BROMINATED FLAME RETARDANTS; POLYCHLORINATED-BIPHENYLS PCBS; THYROID-HORMONE LEVELS; POTENTIAL HEALTH-RISK; WASTE RECYCLING AREA; METABOLITES OH-PBDES; IN-HOUSE DUST; UK HUMAN-MILK; BREAST-MILK; CORD-BLOOD in [Wu, Zhineng; Song, Jie; Li, Huijun; Wu, Weidong] Xinxiang Med Univ, Sch Publ Hlth, Xinxiang 453003, Henan, Peoples R China; [He, Chang] Univ Queensland, QAEHS, Brisbane, Qld 4102, Australia; [Han, Wei] Northeast Agr Univ, Coll Resources & Environm, Harbin 150030, Peoples R China; [Zhang, Yadi] Nankai Univ, Tianjin Key Lab Environm Remediat & Pollut Contro, Key Lab Pollut Proc & Environm Criteria, Coll Environm Sci & Engn,Minist Educ, Tianjin 300350, Peoples R China; [Jing, Xiaohua] Anyang Normal Univ, Sch Chem & Chem Engn, Anyang 455002, Peoples R China in 2020.0, Cited 241.0. Category: ethers-buliding-blocks. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

Polybrominated diphenyl ethers (PBDEs) are extensively used as brominated flame retardants (BFRs) in different types of materials, which have been listed as Persistent Organic Pollutants (POPs) by the Stockholm Convention in 2009 and 2017. Due to their ubiquities in the environment and toxicities, PBDEs have posed great threat to both human health and ecosystems. The aim of this review is to offer a comprehensive understanding of the exposure pathways, levels and trends and associated health risks of PBDEs in human body in a global scale. We systematically reviewed and described the scientific data of PBDE researches worldwide from 2010 to March 2020, focusing on the following three areas: (1) sources and human external exposure pathways of PBDEs; (2) PBDE levels and trends in humans; (3) human data of PBDEs toxicity. Dietary intake and dust ingestion are dominant human exposure pathways. PBDEs were widely detected in human samples, especially in human serum and human milk. Data showed that PBDEs are generally declining in human samples worldwide as a result of their phasing out. Due to the common use of PBDEs, their levels in humans from the USA were generally higher than that in other countries. High concentrations of PBDEs have been detected in humans from PBDE production regions and e-waste recycling sites. BDE-47, -153 and -99 were proved to be the primary congeners in humans. Human toxicity data demonstrated that PBDEs have extensively endocrine disruption effects, developmental effects, and carcinogenic effects among different populations.

Welcome to talk about 101-84-8, If you have any questions, you can contact Wu, ZN; He, C; Han, W; Song, J; Li, HJ; Zhang, YD; Jing, XH; Wu, WD or send Email.. Category: ethers-buliding-blocks

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SDS of cas: 101-84-8. In 2019.0 ANGEW CHEM INT EDIT published article about C-H FUNCTIONALIZATION; F BOND ACTIVATION; METAL-FREE; QUINONES; CHEMISTRY; BIOSYNTHESIS; BENZOQUINONE; ACIDS in [Yu, Congjun; Patureau, Frederic W.] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany in 2019.0, Cited 86.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

A metal free and highly regioselective oxidative arylation reaction of fluorophenols is described. The relative position of the fluoride leaving group (i.e., ortho or para) controls the 1,2 or 1,4 nature of the arylated quinone product, lending versatility and generality to this oxidative, defluorinative, arylation concept.

SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Yu, CJ; Patureau, FW or concate me.

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I found the field of Chemistry very interesting. Saw the article Acid-Mediated Sulfonylthiolation of Arenes via Selective Activation of SS-Morpholino Dithiosulfonate published in 2021. Name: Diphenyl oxide, Reprint Addresses Kanemoto, K; Fukuzawa, SI (corresponding author), Chuo Univ, Fac Sci & Engn, Tokyo 1128551, Japan.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

A trifluoroacetic-acid-mediated desulfurilative sulfonylthiolation of arenes using SS-morpholino dithiosulfonate is described. This system is based on selective activation of the morpholino group over the tosyl group of the doubly transformable sulfur surrogate. Mechanistic studies suggested that the reaction proceeds through electrophilic aromatic substitution followed by sulfur extrusion. The wide substrate scope of this reaction and the transformability of the resulting thiosulfonates enable expeditious access to divergent multifunctionalized sulfides.

Welcome to talk about 101-84-8, If you have any questions, you can contact Kanemoto, K; Furuhashi, K; Morita, Y; Komatsu, T; Fukuzawa, SI or send Email.. Name: Diphenyl oxide

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I found the field of Chemistry; Engineering very interesting. Saw the article Hydrogenolysis of lignin-derived aryl ethers to monomers over a MOF-derived Ni/N-C catalyst published in 2020. Recommanded Product: Diphenyl oxide, Reprint Addresses Zhao, YP; Cao, JP (corresponding author), China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221114, Jiangsu, Peoples R China.; Zhao, YP (corresponding author), Taiyuan Univ Technol, State Key Lab Breeding Base Coal Sci & Technol Co, Taiyuan 030024, Peoples R China.; Zhao, YP (corresponding author), Taiyuan Univ Technol, Minist Sci & Technol, Taiyuan 030024, Peoples R China.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide

A highly efficient Ni/N-C catalyst was synthesized by facile pyrolysis of a Ni-containing metal-organic framework (Ni-MOF), and its catalytic hydrogenolysis performance towards C-O bonds in lignin was evaluated in detail using diphenyl ether (DPE) as a model compound. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses show that the flower-like nanosheets of the Ni-MOF shrink, forming a loose and ordered spherical structure during pyrolysis. Under the optimal conditions, DPE was completely converted and the selectivity to monomers (benzene, cyclohexanol and cyclohexane) reached 99.1%. During the catalytic hydrogenolysis conversion (CHC) of DPE, the direct cleavage of the C-aromatic-O bond affording benzene and phenol is the major reaction pathway, and a low H2 pressure is crucial to increase the monomer selectivity. Furthermore, Ni/N-C-450 shows high hydrogenolysis activity for other lignin-derived aryl ethers, such as benzyl phenyl ether, dibenzyl ether, dinaphthalene ether, benzyl 2-naphthyl ether and 3-methoxyphenol.

Recommanded Product: Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Si, XG; Zhao, YP; Song, QL; Cao, JP; Wang, RY; Wei, XY or send Email.

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Recently I am researching about AGGREGATION-INDUCED EMISSION; CATALYZED CARBOARYLATION; REARRANGEMENT; ALKYNES; C-14; TETRAPHENYLETHENE; EFFICIENT; VESICLES; OLEFINS; CATIONS, Saw an article supported by the Ecole Polytechnique Federale de Lausanne (EPFL); Swiss National Science FoundationSwiss National Science Foundation (SNSF)European Commission. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Suleymanov, AA; Doll, M; Ruggi, A; Scopelliti, R; Fadaei-Tirani, F; Severin, K. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Product Details of 101-84-8

Tetraarylethenes are obtained by acid-induced coupling of vinyl triazenes with aromatic compounds. This new C-H activation route for the synthesis of aggregation-induced emission luminogens is simple, fast, and versatile. It allows the direct grafting of triarylethenyl groups onto a variety of aromatic compounds, including heterocycles, supramolecular hosts, biologically relevant molecules, and commercial polymers.

Welcome to talk about 101-84-8, If you have any questions, you can contact Suleymanov, AA; Doll, M; Ruggi, A; Scopelliti, R; Fadaei-Tirani, F; Severin, K or send Email.. Product Details of 101-84-8

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Ether – Wikipedia,
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Padervand, M; Lichtfouse, E; Robert, D; Wang, CY in [Padervand, Mohsen; Wang, Chuanyi] Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Peoples R China; [Padervand, Mohsen] Univ Maragheh, Fac Sci, Dept Chem, Maragheh, Iran; [Lichtfouse, Eric] Aix Marseille Univ, CNRS, IRD, INRAE,Coll France,CEREGE, F-13100 Aix En Provence, France; [Robert, Didier] Univ Lorraine, ICPEES, 12 Rue Victor Demange, F-57500 St Avold, France published Removal of microplastics from the environment. A review in 2020.0, Cited 123.0. Application In Synthesis of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

The production of fossil fuel-derived, synthetic plastics is continually increasing, while poor plastic waste management has recently induced severe pollution issues. Microplastics are plastic particles smaller than 5 mm. Microplastics are ubiquitous and slowly-degrading contaminants in waters and soils. Microplastics have long residence time, high stability, high potential of being fragmented and can adsorb other contaminants. Many aquatic species contain microplastics, which are in particular easily accumulated by planktonic and invertebrate organisms. Then, microplastics are transferred along food chains, leading to physical damages, decrease in nutritional diet value and exposure of the living organism to pathogens. Raw plastics contain chemical additives such as phthalates, bisphenol A and polybrominated diphenyl ethers that may induce toxic effects after ingestion by living organisms. Furthermore, the adsorption capability of microplastics makes them prone to carry several contaminants. Methods to remove microplastics from water and other media are actually needed. Here, we review microplastics occurrence, transport, raw polymers and additives, toxicity and methods of removal. Removal methods include physical sorption and filtration, biological removal and ingestion, and chemical treatments. Mechanisms, efficiency, advantages, and drawbacks of various removal methods are discussed.

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COA of Formula: C12H10O. In 2020 NATURE published article about ELECTRON-TRANSFER; CATALYSIS; FLUORESCENCE; RULE; DEPROTECTION; SULFONAMIDES; REDUCTION; EMISSION; BREAKING; AMINES in [MacKenzie, Ian A.; Wang, Leifeng; Onuska, Nicholas P. R.; Williams, Olivia F.; Moran, Andrew M.; Nicewicz, David A.] Univ N Carolina, Dept Chem, Chapel Hill, NC 27515 USA; [Begam, Khadiza] Kent State Univ, Dept Phys, Kent, OH 44242 USA; [Dunietz, Barry D.] Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA in 2020, Cited 38. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.

Photoinduced electron transfer (PET) is a phenomenon whereby the absorption of light by a chemical species provides an energetic driving force for an electron-transfer reaction(1-4). This mechanism is relevant in many areas of chemistry, including the study of natural and artificial photosynthesis, photovoltaics and photosensitive materials. In recent years, research in the area of photoredox catalysis has enabled the use of PET for the catalytic generation of both neutral and charged organic free-radical species. These technologies have enabled previously inaccessible chemical transformations and have been widely used in both academic and industrial settings. Such reactions are often catalysed by visible-light-absorbing organic molecules or transition-metal complexes of ruthenium, iridium, chromium or copper(5,6). Although various closed-shell organic molecules have been shown to behave as competent electron-transfer catalysts in photoredox reactions, there are only limited reports of PET reactions involving neutral organic radicals as excited-state donors or acceptors. This is unsurprising because the lifetimes of doublet excited states of neutral organic radicals are typically several orders of magnitude shorter than the singlet lifetimes of known transition-metal photoredox catalysts(7-11). Here we document the discovery, characterization and reactivity of a neutral acridine radical with a maximum excited-state oxidation potential of -3.36 volts versus a saturated calomel electrode, which is similarly reducing to elemental lithium, making this radical one of the most potent chemical reductants reported(12). Spectroscopic, computational and chemical studies indicate that the formation of a twisted intramolecular charge-transfer species enables the population of higher-energy doublet excited states, leading to the observed potent photoreducing behaviour. We demonstrate that this catalytically generated PET catalyst facilitates several chemical reactions that typically require alkali metal reductants and can be used in other organic transformations that require dissolving metal reductants.

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Formula: C12H10O. Authors Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S in AMER CHEMICAL SOC published article about in [Zakhtser, Alter; Naitabdi, Ahmed; Benbalagh, Rabah; Rochet, Francois; Salzemann, Caroline; Petit, Christophe] Sorbonne Univ, F-75005 Paris, France; [Giorgio, Suzanne] Aix Marseille Univ, F-13288 Marseille, France in 2021, Cited 65. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8

We report on the shape, composition (from Pt95Zn5 to Pt77Zn23), and surface chemistry of Pt-Zn nanoparticles obtained by reduction of precursors M2+(acac) (-)(2) (M2+: Pt2+ and Zn2+) in oleylamine, which serves as both solvent and ligand. We show first that the addition of phenyl ether or benzyl ether determines the composition and shape of the nanoparticles, which point to an adsorbate-controlled synthesis. The organic (ligand)/inorganic (nanoparticles) interface is characterized on the structural and chemical level. We observe that the particles, after washing with ethanol, are coated with oleylamine and the oxidation products of the latter, namely, an aldimine and a nitrile. After exposure to air, the particles oxidize, covering themselves with a few monolayer thick ZnO film, which is certainly discontinuous when the particles are low in zinc. Pt-Zn particles are unstable and prone to losing Zn. We have strong indications that the driving force is the preferential oxidation of the less noble metal. Finally, we show that adsorption of CO on the surface of nanoparticles modifies the oxidation state of amine ligands and attribute it to the displacement of hydrogen adsorbed on Pt. All the structural and chemical information provided by the combination of electron microscopy and X-ray photoelectron spectroscopy allows us to give a fairly accurate picture of the surface of nanoparticles and to better understand why Pt-Zn alloys are efficient in certain electrocatalytic reactions such as the oxidation of methanol.

Formula: C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.

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