Category: 103-50-4

An article Windowless thin layer electrochemical Raman spectroscopy of Ni-Fe oxide electrocatalysts during oxygen evolution reaction WOS:000554922000020 published article about CATALYSTS; IDENTIFICATION; OXIDATION in [Tang, Fei; Liu, Tian; Jiang, Wulv; Gan, Lin] Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China in 2020, Cited 29. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Safety of Benzyl ether

In-situ Raman spectroelectrochemistry is a powerful tool to understand the structures and reaction mechanisms of electrochemical interfaces yet usually suffers from a low sensitivity and detection efficiency. Herein, we develop a windowless thin layer electrochemical cell design to improve the detection efficiency of in-situ Raman spectroscopy for practical nanoscale electrocatalysts. This was achieved by perforating a hole in the optical window of the cell, which not only eliminates the refraction of light by the window but also induces a meniscus thin electrolyte layer on the working electrode, thus significantly improving the detection efficiency of Raman spectra. We successfully applied thismethod to conduct in-situ Raman spectroscopy of structural evolutions of two representative Ni-Fe oxide catalysts (layered double hydroxides and spinel oxides) during oxygen evolution reaction (OER) electrocatalysis. It was shown that both catalysts underwent surface transformation to oxyhydroxides and formed active oxygen species at OER relevant potentials. However, the extent of the surface transformation was much lower on the Ni-Fe spinel catalyst, accounting for its lower OER activity. We further show that adding a carbon support can promote the surface transformation of Ni-Fe spinel to oxyhydroxides, thus significantly increasing the electrocatalytic activities. The established windowless thin layer method provides a new way to conduct in-situ electrochemical Raman spectroscopy of a wide range of materials and may be also combined with surface-enhanced Raman spectroscopic methods.

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Authors Fan, BB; Zhang, DF; Li, MJ; Zhong, WK; Zeng, ZMY; Ying, L; Huang, F; Cao, Y in SCIENCE PRESS published article about POWER CONVERSION EFFICIENCY; FULLERENE-POLYMER; ACCEPTOR; RECOMBINATION; SOLVENT; DESIGN in [Fan, Baobing; Zhang, Difei; Li, Meijing; Zhong, Wenkai; Zeng, Zhaomiyi; Ying, Lei; Huang, Fei; Cao, Yong] South China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China in 2019, Cited 44. Quality Control of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

To achieve high photovoltaic performance of bulk hetero-junction organic solar cells (OSCs), a range of critical factors including absorption profiles, energy level alignment, charge carrier mobility and miscibility of donor and acceptor materials should be carefully considered. For electron-donating materials, the deep highest occupied molecular orbital (HOMO) energy level that is beneficial for high open-circuit voltage is much appreciated. However, a new issue in charge transfer emerges when matching such a donor with an acceptor that has a shallower HOMO energy level. More to this point, the chemical strategies used to enhance the absorption coefficient of acceptors may lead to increased molecular crystallinity, and thus result in less controllable phase-separation of photoactive layer. Therefore, to realize balanced photovoltaic parameters, the donor-acceptor combinations should simultaneously address the absorption spectra, energy levels, and film morphologies. Here, we selected two non-fullerene acceptors, namely BTPT-4F and BTPTT-4F, to match with a wide-bandgap polymer donor P2F-EHp consisting of an imide-functionalized benzotriazole moiety, as these materials presented complementary absorption and well-matched energy levels. By delicately optimizing the blend film morphology, we demonstrated an unprecedented power conversion efficiency of over 16% for the device based on P2F-EHp:BTPTT-4F, suggesting the great promise of materials matching toward high-performance OSCs.

Quality Control of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Fan, BB; Zhang, DF; Li, MJ; Zhong, WK; Zeng, ZMY; Ying, L; Huang, F; Cao, Y or concate me.

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Zhao, WJ; Li, X; Li, HW; Zheng, XL; Ma, HW; Long, JX; Li, XH in [Zhao, Weijie; Li, Xuan; Li, Haowei; Zheng, Xinlai; Ma, Hongwei; Long, Jinxing; Li, Xuehui] South China Univ Technol, Sch Chem & Chem Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China published Selective Hydrogenolysis of Lignin Catalyzed by the Cost-Effective Ni Metal Supported on Alkaline MgO in 2019, Cited 57. Recommanded Product: Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Bulk chemicals produced from renewable resources are receiving considerable attention due to the increase in sustainable practices. In this study, a novel, efficient, and sustainable strategy has been proposed to produce versatile petroleum based monophenols from the natural aromatic polymer, lignin, via the selective cleavage of its specific chemical linkages by a cost-effective catalyst, Ni/MgO. The results demonstrate that 93.4% of lignin is converted, yielding 15.0% monophenols in the presence of 20% Ni/MgO. Importantly, 42.3% of these volatile chemicals are found to be 4-ethyl phenol (the yield is 6.31%), a widely used fine chemical currently obtained from the petrochemical industry. Further comparative investigations on the raw and recovered lignin using heteronuclear single quantum correlation-nuclear magnetic resonance (HSQC-NMR), Fourier transform infrared (FT-IR), quantitative C-13 NMR, and the alkaline nitrobenzene oxidation method reveal that the selective breakage of the ester bond between the p-hydroxyphenyl structural unit and the other fragments followed by decarboxylation is responsible for the good performance of the 4-ethyl phenol formation process. Therefore, the results of this work would provide new insights for producing value-added petrochemicals from renewable lignin.

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An article Simultaneous acquisition of Fe3O4 monocrystals: Tunable magnetic properties with various morphologies WOS:000522647100006 published article about IRON-OXIDE NANOPARTICLES; FACILE SYNTHESIS; STABILIZER in [Zheng, Zemin; Li, Huiyong; Hu, Dafeng; Jiang, Hao; Geng, Xuemin; Lu, Jiangwei; Zhang, Xudong; Yang, Peng; Wan, Yanfen] Yunnan Univ, Sch Mat Sci & Engn, Yunnan Key Lab Micro Nano Mat & Technol, Kunming 650091, Yunnan, Peoples R China; [Cao, Yiming; Li, Zhe] Qujing Normal Univ, Ctr Magnet Mat & Devices, Qujing 655011, Yunnan, Peoples R China; [Cao, Yiming; Li, Zhe] Qujing Normal Univ, Key Lab Adv Funct & Low Dimens Mat, Yunnan Higher Educ Inst, Qujing 655011, Yunnan, Peoples R China in 2020, Cited 26. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Recommanded Product: Benzyl ether

Fe3O4 nanoparticles (NPs) with a face-centered cubic (fcc) structure and two different morphologies (nanospheres and nanoprisms) were synthesized by a facile one-step method. The synthesized Fe3O4 nanospheres and nanoprisms were monocrystalline and separable in a magnetic field. In different volume ratios of oleylamine (OAm) to dibenzyl ether, the sizes of the prepared Fe3O4 NPs ranged from 5 to 21 nm. The OAm amount in the synthesis can significantly control the morphology of Fe3O4 NPs. As the OAm content increased from 10 ml to 30 ml, the faceted nanoprisms shrank while the nanospheres enlarged. At an OAm content of 25 ml, the nanoprisms diminished while more hexagonal and sphere-like particles appeared, implying a critical point of morphology transition from triangle to hexagon. The magnetic properties also depended on the NP morphology and size. The prepared Fe3O4 NPs are promising candidates in medical applications such as magnetic resonance imaging, targeted drug delivery, blood purification, and tumor hyperthermia.

Welcome to talk about 103-50-4, If you have any questions, you can contact Zheng, ZM; Cao, YM; Li, Z; Li, HY; Hu, DF; Jiang, H; Geng, XM; Lu, JW; Zhang, XD; Yang, P; Wan, YF or send Email.. Recommanded Product: Benzyl ether

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Ether – Wikipedia,
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Category: ethers-buliding-blocks. Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; METAL-COMPLEXES; ENANTIOSELECTIVE HYDROSILYLATION; SELECTIVE REDUCTION; MANGANESE COMPLEXES; IRON COMPLEXES; KETONES; ALDEHYDES; EFFICIENT; HYDROSILATION, Saw an article supported by the Max Planck SocietyMax Planck SocietyFoundation CELLEX; RWTH Aachen University; Bundesministerium fur Bildung und Forschung as part of the project MANGANFederal Ministry of Education & Research (BMBF) [03SF0508]; Cluster of Excellence The Fuel Science Center. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Martinez-Ferrate, O; Chatterjee, B; Werle, C; Leitner, W. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 degrees C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

Category: ethers-buliding-blocks. Welcome to talk about 103-50-4, If you have any questions, you can contact Martinez-Ferrate, O; Chatterjee, B; Werle, C; Leitner, W or send Email.

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Ether – Wikipedia,
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Authors Nagendra, B; Rizzo, P; Daniel, C; Guerra, G in AMER CHEMICAL SOC published article about STRESS-INDUCED CRYSTALLIZATION; STRAIN-INDUCED CRYSTALLIZATION; SYNDIOTACTIC POLYSTYRENE; ISOTACTIC POLYPROPYLENE; UNIPLANAR ORIENTATIONS; INDUCED NUCLEATION; OPTICAL-PROPERTIES; RANDOM COPOLYMERS; PHASE; CLATHRATE in [Nagendra, Baku; Rizzo, Paola; Daniel, Christophe; Guerra, Gaetano] Univ Salerno, Dipartimento Chim & Biol, INSTM Res Unit, I-84084 Fisciano, SA, Italy in 2021, Cited 51. Computed Properties of C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The dependence of polymer film transparency on different kinds of planar orientations of nanoporous-crystalline (NC) phases of syndiotactic polystyrene (sPS) and poly(2,6-dimethyl-1,4-phenylene)oxide (PPO) is described. The two polymers exhibit opposite behavior: film transparency is improved for sPS and PPO by orientations of the chain axes of the NC phases being parallel (c(parallel to)) and perpendicular (c(perpendicular to)) to the film plane, respectively. This behavior can be rationalized by the negative and positive birefringence of sPS and PPO chains, respectively. In fact, to maximize transparency, the refractive index of the NC phase along the perpendicular to the film plane has to be increased to come closer to that of the corresponding amorphous phase. This can be pursued by controlling the orientation of the NC phases and hence of the associated refractive index ellipsoids.

Computed Properties of C14H14O. Welcome to talk about 103-50-4, If you have any questions, you can contact Nagendra, B; Rizzo, P; Daniel, C; Guerra, G or send Email.

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Ether – Wikipedia,
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Wu, XY; Qiao, K; Qin, H; Zhang, D; Gao, D; Yang, Z; Fang, Z; Guo, K in [Wu, Xiaoyu; Qiao, Kai; Qin, Hong; Zhang, Dong; Gao, Di; Fang, Zheng; Guo, Kai] Nanjing Tech Univ, Coll Biotechnol & Pharmaceut Engn, Nanjing 211816, Jiangsu, Peoples R China; [Yang, Zhao] China Pharmaceut Univ, Sch Engn, 639 Longmian Ave, Nanjing 211198, Jiangsu, Peoples R China; [Fang, Zheng; Guo, Kai] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China published Silver(i)-mediated oxidative C(sp(3))-H amination of ethers with azole derivatives under mild conditions in 2019, Cited 68. COA of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A silver(i)-mediated oxidative N-H/C(sp(3))-H coupling of NH-azoles with ethers has been developed. Various substrates were well N-alkylated in this methodology and the corresponding desired products were given in moderate to good yields. Moreover, the late-stage alkylation of bioactive molecules was achieved. This protocol involved C(sp(3))-N bond formation via a radical pathway generated in the presence of low cost and readily available heptafluoroisopropyl iodide (i-C3F7I). Generally, this reaction features excellent functional group compatibility, broad substrate scope, good regioselectivity, and fast access to pharmaceuticals such as SQ 22536.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Product Details of 103-50-4. Zhang, S; Han, F; Yan, SR; He, MY; Miao, CX; He, LN in [Zhang, Shuai; He, Liang-Nian] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China; [Zhang, Shuai; He, Liang-Nian] Nankai Univ, Coll Chem, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China; [Zhang, Shuai; Han, Feng; Yan, Shaorui; He, Mingyue; Miao, Chengxia] Inst Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271018, Shandong, Peoples R China published Efficient Catalysts In situ Generated from Zinc, Amide and Benzyl Bromide for Epoxide/CO2 Coupling Reaction at Atmospheric Pressure in 2019, Cited 58. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Herein, in situ generated efficient catalysts were designed for fixation of CO2 to cyclic carbonates under mild conditions. Zinc bromide and N,N-dibenzyl-N,N-dimethylammonium bromide, being proved as active catalyst species, were in situ generated from cheap Zn powder, dimethyl formamide and benzyl bromide, and catalyzed the cycloaddition reaction of CO2 and various terminal epoxides in moderate to excellent yields at 80 degrees C and atmospheric pressure of CO2. The protocol circumvents the preparation of active catalysts, simultaneously possesses good catalytic activity under mild conditions.

Welcome to talk about 103-50-4, If you have any questions, you can contact Zhang, S; Han, F; Yan, SR; He, MY; Miao, CX; He, LN or send Email.. Product Details of 103-50-4

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

HPLC of Formula: C14H14O. Authors Tekale, DP; Yadav, GD; Dalai, AK in MDPI published article about in [Tekale, Devendra P.; Yadav, Ganapati D.] Inst Chem Technol, Dept Chem Engn, Nathalal Parekh Marg, Mumbai 400019, Maharashtra, India; [Dalai, Ajay K.] Univ Saskatchewan, Catalysis & Chem React Engn Lab, Dept Chem & Biol Engn, Saskatoon, SK S7N 5A9, Canada in 2021, Cited 41. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Value addition to glycerol, the sole co-product in biodiesel production, will lead to reform of the overall biodiesel economy. Different valuable chemicals can be produced from glycerol using heterogeneous catalysis and these valuable chemicals are useful in industries such as cosmetics, pharmaceuticals, fuels, soap, paints, and fine chemicals. Therefore, the conversion of glycerol to valuable chemicals using heterogeneous catalysis is a noteworthy area of research. Etherification of glycerol with alkenes or alcohols is an important reaction in converting glycerol to various value-added chemicals. This article describes reaction of glycerol with benzyl alcohol in solvent-free medium by using a clay supported modified heteropolyacid (HPA), Cs2.5H0.5PW12O40/K-10 (Cs-DTP/K-10) as solid catalyst and its comparison with other catalysts in a batch reactor. Mono-Benzyl glycerol ether (MBGE) was the major product formed in the reaction along with formation of di-benzyl glycerol ether (DBGE). The effects of different parameters were studied to optimize the reaction parameters. This work provides an insight into characterization of Cs2.5H0.5PW12O40/K-10 catalyst by advanced techniques such as surface area measurement, X-ray analysis, ICP-MS, FT-IR, and SEM. Reaction products were characterized and confirmed by using the GCMS method. The kinetic model was developed from an insight into the reaction mechanism. The apparent energy of activation was found to be 18.84 kcal/mol.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Selective catalytic oxidation over Au-Pd/titanate nanotubes and the influence of the catalyst preparation method on the activity WOS:000472188100015 published article about LIQUID-PHASE OXIDATION; TITANATE NANOTUBES; BIMETALLIC CATALYSTS; GOLD; NANOPARTICLES; STABILITY; CHEMISTRY; PALLADIUM; TIO2; SIO2 in [Khawaji, Motaz; Chadwick, David] Imperial Coll London, Dept Chem Engn, London SW7 2AZ, England in 2019, Cited 41. Computed Properties of C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The dependence of the selective oxidation catalytic activity of Au-Pd supported on titanate nanotubes on the catalyst preparation method has been investigated. The most active Au-Pd/Ti-NT catalyst for the selective oxidation of benzyl alcohol is shown to be that prepared using colloidal synthesis and immobilization with PVA as a stabilizer, which has markedly superior catalytic activity compared to catalysts prepared by deposition-precipitation, adsorption, and dry impregnation methods. Au-Pd NPs stabilized by graphene oxide sheets and immobilized on Ti-NT has also been studied and while not optimum shows promising catalytic activity. The superior catalytic activity of the catalysts prepared by colloidal synthesis is attributed to the high metal dispersion on the external surfaces of Ti-NT, the narrow particle size distribution, and the high degree of Au-Pd alloying. This work also demonstrates that in the adsorption method of preparation using HAuCl4.3H(2)O and PdCl2 precursors, the uptake of Pd ions in solution by Ti-NT is proportional to the sodium content in Ti-NT, which implies that Na is involved in an ion-exchange reaction with Pd ions.

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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem