Category: 103-50-4

Recommanded Product: 103-50-4. Recently I am researching about ACETIC-ACID; NANOCLUSTER NUCLEATION; OXIDE NANOPARTICLES; ETHYLENE-GLYCOL; GROWTH; SURFACE; ADSORPTION; CRYSTALLIZATION; HYDROGENATION; DECOMPOSITION, Saw an article supported by the ETH ZurichETH Zurich; Swiss National Science FoundationSwiss National Science Foundation (SNSF)European Commission [200021_165888]. Published in SPRINGER in NEW YORK ,Authors: Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Benzyl alcohol is a versatile reaction medium for the synthesis of different types of nanoparticles. Its ability to act as an oxygen source gave access to metal oxide nanoparticles, while its reducing properties can be harnessed for the preparation of metals. Here we report the synthesis of Pd and PdCu nanoparticles in benzyl alcohol supplemented by a detailed mechanistic study for both systems. To elucidate the chemical formation mechanism of the Pd nanoparticles, we performed in situ attenuated total reflection ultraviolet-visible (ATR-UV-vis) and Fourier transform infrared spectroscopy (ATR-FTIR), providing information on the organic as well as on the inorganic side of the reaction. Potential gaseous products were analyzed by in situ gas chromatography (GC) and mass spectrometry (MS). We observed the formation of benzaldehyde, toluene, and dibenzyl ether as the three main organic products. The formation of the PdCu alloy nanoparticles was studied by ex situ powder X-ray diffraction (PXRD). A time-resolved study of the synthesis at 100 degrees C indicated that initially three types of particles formed, composed of an alloy with high Pd content, an alloy with high content of copper, and palladium particles, and only later in the reaction course they transformed into an alloy with a Pd-to-Cu ratio close to 1. [GRAPHICS] .

Recommanded Product: 103-50-4. About Benzyl ether, If you have any questions, you can contact Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands WOS:000496465000013 published article about ASYMMETRIC TRANSFER HYDROGENATION; METAL-COMPLEXES; ENANTIOSELECTIVE HYDROSILYLATION; SELECTIVE REDUCTION; MANGANESE COMPLEXES; IRON COMPLEXES; KETONES; ALDEHYDES; EFFICIENT; HYDROSILATION in [Martinez-Ferrate, Oriol; Chatterjee, Basujit; Werle, Christophe; Leitner, Walter] Max Planck Inst Chem Energy Convers, Stiftstr 34-36, D-45470 Mulheim, Germany; [Leitner, Walter] Rhein Westfal TH Aachen, ITMC, Worringer Weg 2, D-52074 Aachen, Germany in 2019, Cited 111. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Recommanded Product: 103-50-4

Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 degrees C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

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An article Synthesis and catalytic evaluation of acidic carbons in the etherification of glycerol obtained from biodiesel production WOS:000662269700004 published article about BENZYL ALCOHOL; CRUDE GLYCEROL; CONVERSION; DEACTIVATION; ETHERS; FUEL in [Chiosso, Maria E.; Casella, Monica L.] Univ Nacl Noroeste Prov Buenos Aires, Dept Ciencias Basicas & Expt, Roque Saenz Pena 456, RA-6000 Junin, Argentina; [Chiosso, Maria E.; Casella, Monica L.] UNNOBA, UNSAdA, CONICET, Ctr Invest & Transferencia Noroeste Prov Buenos A, Monteagudo 2772, RA-2700 Pergamino, Argentina; [Chiosso, Maria E.; Merlo, Andrea B.] Univ Nacl La Plata, CONICET La Plata, CCT, Ctr Invest & Desarrollo Ciencias Aplicadas Dr Jor, Calle 47 257, RA-1900 La Plata, Argentina in 2021, Cited 37. Recommanded Product: 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

In this paper, the catalytic behaviour of carbonaceous system (Ccs) functionalized with -SO3H groups were studied in the etherification of refined (Gly) and crude glycerol (GlyC), with benzyl alcohol (BA). This Ccs was obtained by a synthetic method with low energetic cost in only 24 h. Its catalytic activity and selectivity were studied varying the catalyst percentage (2.5, 5 and 10 wt.%), the initial reactant molar ratio and temperature (between 80 and 120 degrees C). A very good catalytic performance was achieved (97 % conversion after 360 min of reaction), at 120 degrees C, Gly:BA = 3:1 and 10 wt.% of Ccs. The high activity can be attributed to high acid site density (6.4 mmol H+/g), that also allowed us to working at lower reaction temperature (100 degrees C) and with less catalyst concentration (2.5 wt.%), without observing significant loss in BA conversion. Monoether (ME1) was the major product of the reaction with 72 % selectivity. The material can be reused and still gives a notable conversion of BA (about 43 %) after three successive reuses. Finally, the Ccs was active and selective to the desired products in the etherification of crude glycerol (GlyC) derived of biodiesel industry. An important BA conversion (45 %) was obtained only reducing the water content of GlyC and without carrying out any other purification and/or neutralization treatment.

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Recommanded Product: Benzyl ether. I found the field of Chemistry; Science & Technology – Other Topics; Materials Science; Physics very interesting. Saw the article Hafnium-Doped Mesoporous Silica as Efficient Lewis Acidic Catalyst for Friedel-Crafts Alkylation Reactions published in 2019, Reprint Addresses Huang, YB; Wang, F (corresponding author), Nanjing Forestry Univ, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Nanjing 210037, Jiangsu, Peoples R China.; Huang, YB (corresponding author), Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China.; Huang, YB (corresponding author), Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94706 USA.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

The development of an efficient solid catalyst for Friedel-Crafts (FC) reactions is of great importance to organic synthetic chemistry. Herein, we reported the hafnium-doped mesoporous silica catalyst Hf/SBA-15 and its first use for Friedel-Crafts alkylation reactions. Catalysts with different Si/Hf ratios were prepared and characterized, among which Hf/SBA-15(20) (Si/Hf = 20:1) was the most active catalyst, offering up to 99.1% benzylated product under mild reaction conditions. The influences of reaction conditions on the product were systematically investigated and compared. Pyridine-IR characterization of the catalyst showed that Lewis acid formed the primary active sites for the Friedel-Crafts alkylation reaction. X-ray photoelectron spectroscopy (XPS) characterization revealed that the electron shift from the Hf center to the silica framework resulted in a more active Lewis metal center for FC reactions. Moreover, the catalyst was successfully applied to the alkylation reaction with different alcohols and aromatic compounds. Finally, the Hf/SBA-15(20) catalyst also showed good recyclability in the recycling runs, demonstrating its high potential of being used for large scale FC reactions in the industry.

Recommanded Product: Benzyl ether. Welcome to talk about 103-50-4, If you have any questions, you can contact Huang, YB; Luo, YJ; Wang, F or send Email.

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Authors Guidea, A; Sarbu, C in TAYLOR & FRANCIS INC published article about ORGANIC-SOLVENTS; CHROMATOGRAPHY; PARAMETERS in [Guidea, Alexandrina; Sarbu, Costel] Babes Bolyai Univ, Fac Chem & Chem Engn, Dept Chem, Arany Janos Str 11, RO-400028 Cluj Napoca, Romania in 2020, Cited 34. Product Details of 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Advanced chemometric methods, such as fuzzy c-means, a semi-supervised clustering method, and fuzzy discriminant analysis, a robust supervised method, have been successfully applied for characterization and classification of 72 solvents according to the chemical parameters (P’ and x(i)) developed by Snyder. The obtained results (fuzzy partitions) and parameters of the prototypes (robust fuzzy means) clearly demonstrated the efficiency and information power of the advanced fuzzy methods in solvent characterization and classification, and allow a rationale choice of a good solvent or an efficient mixture of solvents in chromatography and other fields. Also, this methodology generates the premises for future investigations using other different properties of solvents.

Product Details of 103-50-4. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

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Ether – Wikipedia,
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Computed Properties of C14H14O. In 2021 NANOTECHNOLOGY published article about COERCIVITY; MODEL in [Fabris, Fernando; Lohr, Javier; Lima, Enio, Jr.; de Almeida, Adriele Aparecida; Rodriguez, Luis M.; Vasquez Mansilla, Marcelo; Zysler, Roberto D.; De Biasi, Emilio; Winkler, Elin L.] Consejo Nacl Invest Cient & Tecn, Ctr Atom Bariloche, Inst Nanociencia & Nanotecnol CNEA, RA-8400 San Carlos De Bariloche, Argentina; [Lohr, Javier] Lab Argentino Haces Neutrones CNEA Argentina, San Carlos De Bariloche, Rio Negro, Argentina; [Troiani, Horacio E.] Ctr Atom Bariloche, Lab Caracterizac Mat & Oxidos Noestequiomet, Gerencia Invest Aplicada, RA-8400 San Carlos De Bariloche, Argentina; [Aguirre, Myriam H.] Univ Zaragoza, Inst Ciencias Mat Aragon, Mariano Esquillor S-N, E-50018 Zaragoza, Spain; [Aguirre, Myriam H.] Univ Zaragoza, Lab Microscopias Avanzadas, Mariano Esquillor S-N, E-50018 Zaragoza, Spain; [Aguirre, Myriam H.; Goya, Gerardo F.] Univ Zaragoza, Inst Nanociencias & Mat Aragon, Mariano Esquillor S-N, E-50018 Zaragoza, Spain; [Aguirre, Myriam H.; Goya, Gerardo F.] Univ Zaragoza, Dept Fis Mat Condensada, Mariano Esquillor S-N, E-50018 Zaragoza, Spain; [Rinaldi, Daniele] Univ Politecn Marche, Dept Mat Environm Sci & Urban Planning SIMAU, I-60131 Ancona, Italy; [Ghirri, Alberto] CNR, Ist Nanosci, Via Campi 213-A, I-41125 Modena, Italy; [Peddis, Davide; Fiorani, Dino] CNR, Ist Struttura Mat, Area Ric Roma 1,CP 10, I-00015 Rome, Italy; [Zysler, Roberto D.; De Biasi, Emilio; Winkler, Elin L.] Univ Nacl Cuyo, Inst Balseiro, Mendoza, Argentina in 2021, Cited 61. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

In this work it is shown a precise way to optimize the heat generation in high viscosity magnetic colloids, by adjusting the Neel relaxation time in core/shell bimagnetic nanoparticles, for magnetic fluid hyperthermia (MFH) applications. To pursue this goal, Fe3O4/ZnxCo1-xFe2O4 core/shell nanoparticles were synthesized with 8.5 nm mean core diameter, encapsulated in a shell of similar to 1.1 nm of thickness, where the Zn atomic ratio (Zn/(Zn + Co) at%) changes from 33 to 68 at%. The magnetic measurements are consistent with a rigid interface coupling between the core and shell phases, where the effective magnetic anisotropy systematically decreases when the Zn concentration increases, without a significant change of the saturation magnetization. Experiments of MFH of 0.1 wt% of these particles dispersed in water, in Dulbecco modified Eagles minimal essential medium, and a high viscosity butter oil, result in a large specific loss power (SLP), up to 150 W g(-1), when the experiments are performed at 571 kHz and 200 Oe. The SLP was optimized adjusting the shell composition, showing a maximum for intermediate Zn concentration. This study shows a way to maximize the heat generation in viscous media like cytosol, for those biomedical applications that require smaller particle sizes.

Computed Properties of C14H14O. Welcome to talk about 103-50-4, If you have any questions, you can contact Fabris, F; Lohr, J; Lima, E; de Almeida, AA; Troiani, HE; Rodriguez, LM; Mansilla, MV; Aguirre, MH; Goya, GF; Rinaldi, D; Ghirri, A; Peddis, D; Fiorani, D; Zysler, RD; De Biasi, E; Winkler, EL or send Email.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Application In Synthesis of Benzyl ether. Tanigawa, T; Tsunoji, N; Sadakane, M; Sano, T in [Tanigawa, Takuya; Tsunoji, Nao; Sadakane, Masahiro; Sano, Tsuneji] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan published Zeolite hydrothermal conversion in the presence of various cyclic alkylammonium cations and synthesis of nanosized BEA and MFI zeolites in 2019, Cited 56. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Zeolite synthesis using faujasite-type (FAU) zeolites as the starting silica/alumina source in the presence of various organic structure-directing agents (OSDAs) with cyclic alkylammonium structures was investigated. The obtained zeolite phases strongly depended on the structure of the OSDA and the Si/Al ratio of the starting FAU. Zeolites with different framework structures, such as BEA, MFI, CHA, and LEV, were obtained. Among the used OSDAs, methylpropylpyrrolidinium, butylmethylpyrrolidinium, and methylpropylpiperidinium effectively produced nanosized BEA and MFI zeolites, whereas dimethylpiperidinium and cyclohexyltrimethylammonium produced CHA and LEV zeolites, respectively. The nanosized MFI and BEA zeolites obtained through zeolite hydrothermal conversion exhibited remarkably smaller particle sizes and higher external surface area as compared to those of the conventional MFI and BEA zeolite samples synthesized using tetrapropylammonium and tetraethylammonium, respectively. We also found that the highly crystalline nanosized BEA and MFI zeolites exhibited better catalytic performance in the dehydration of benzyl alcohol to benzyl ether as compared to the conventional zeolites with large particle sizes. In addition, nanosized MFI zeolites, synthesized using FAU as a starting material and cyclic ammonium compounds, showed catalytic activities superior to those of the nano sized MFI zeolites synthesized from amorphous starting materials and cyclic ammonium compounds.

Welcome to talk about 103-50-4, If you have any questions, you can contact Tanigawa, T; Tsunoji, N; Sadakane, M; Sano, T or send Email.. Application In Synthesis of Benzyl ether

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2020 IND CROP PROD published article about LIGNOCELLULOSIC BIOMASS; LIGNIN; WOOD; CELLULOSE; PRETREATMENT; STRAW; VALORIZATION; DISSOLUTION; STATE; DES in [Wang, Wangxia; Gu, Feng; Sun, Kaiyong; Cai, Zhaosheng] Yancheng Inst Technol, Sch Chem & Chem Engn, Yancheng 224000, Peoples R China; [Wang, Wangxia; Wu, Wenjuan; Jin, Yongcan] Nanjing Forestry Univ, Jiangsu Prov Key Lab Pulp & Paper Sci & Technol, Nanjing 210037, Peoples R China; [Zhu, J. Y.] USDA Forest Serv, Forest Prod Lab, Madison, WI 53726 USA; [Yao, Shufeng] Jiangsu Prov Key Lab Biomass Energy & Mat, Nanjing 210042, Peoples R China in 2020, Cited 36. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Safety of Benzyl ether

Lignin valorization is significantly influenced by the degrees of lignin condensation measured by the amount of cleaved beta-O-4 ether linkages and interunit C-C linkages formed during biomass fractionation. To minimize the cleavage of aryl ether and formation of C-C linkages, a p-toluenesulfonic acid (p-TsOH)/choline chloride (ChCl) solvent system with hydrotropic properties was evaluated. The ChC1 was chosen to control the H+ concentration of the p-TsOH/ChCl solvent system. Compared with p-TsOH/H2O, the degradation of beta-O-4 was kept in a similar rate during p-TsOH/ChCl fractionation; however, the formation of C-C linkage was slower. Under 75/25 p-TsOH/ChCl mass ratio at 80 degrees C for 20 min, 76.6 % of miscanthus lignin, with beta-O-4 content of 30.9 %, and 88.9 % of wheat straw lignin, with beta-O-4 content of 33.6 %, can be dissolved. In addition, the low polar and layered structure of hydrotropic p-TsOH/ChCl system has a strong ability to dissolve lignin, which resulted in lignin with larger particle size and lower surface charge. The results also indicated that lignin from p-TsOH/ChCl solvent system has great potential for lignin depolymerization to aromatics for valorization.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

I found the field of Chemistry; Environmental Sciences & Ecology very interesting. Saw the article Novel mesoporous TiO2(B) whisker-supported sulfated solid superacid with unique acid characteristics and catalytic performances published in 2019. Name: Benzyl ether, Reprint Addresses Li, LC (corresponding author), Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Mesoporous TiO2(B) whisker was firstly applied as a support for synthesizing the novel sulfated solid superacid (SO42-/TiO2(B)). According to NH3-TPD, TG and Py-IR characterization results, it was found that the similar amount of sulfate group on TiO2(B) and anatase showed significantly different acid characteristics and catalytic performances. The total acid amount of SO42-/TiO2(B) was about 1.8 times as anatase-supported sulfated solid superacid (SO42-/Anatase). Simultaneously, the SO42-/TiO2(B) possessed higher percentage of Bronsted acid and more weak-medium acid strength than SO42-/Anatase. These acidic properties endowed SO42-/TiO2(B) with the increased esterification reaction rate and decreased alkylation byproduct selectivity compared with that of SO42-/Anatase. Structure-performance analysis exhibited that there were more bridged bidentate sulfate groups coordinated to the TiO2(B) in SO42-/TiO2(B), which could induce more Ti cations than that of the chelating one. This was the key factor to be responsible for the unique acid characteristics of SO42-/TiO2(B). The present work provides a novel solid superacid and might open a strategy to mediate the acid characteristic for sulfated solid superacid.

Welcome to talk about 103-50-4, If you have any questions, you can contact Li, LC; Yue, HQ; Ji, T; Li, W; Zhao, XJ; Wang, L; She, J; Gu, XL; Li, XB or send Email.. Name: Benzyl ether

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Recently I am researching about SURFACE ACID PROPERTIES; ESTERIFICATION; CATALYSTS; CREATION; PERFORMANCE; CRYSTALS; ETHANOL, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21606048, 21878050]. Published in ELSEVIER in AMSTERDAM ,Authors: Yue, YY; Guo, XX; Liu, T; Liu, HY; Wang, TH; Yuan, P; Zhu, HB; Bai, ZS; Bao, XJ. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Application In Synthesis of Benzyl ether

A template free synthesis route was developed for the synthesis of hierarchical zeolite Beta from a natural layered aluminosilicate mineral kaolin. Detailed study on the crystallization of zeolite Beta established the optimized synthesis condition, and the synthesized hierarchical Beta zeolite was fully studied by XRD, IR, SEM, TEM, BET, NH3-TPD, Py-IR and NMR techniques. The characterization results reveal that the hierarchical Beta zeolite possesses good crystallinity, bimodal pore architecture, large surface area, big pore volume, high acid site concentration and excellent hydrothermal stability. An improved catalytic performance was achieved in hierarchical Beta zeolite for the esterification of acetic acid with benzyl alcohol, and the high activity and selectivity in this zeolite are mainly attributed to the presence of mesopores for accelerating the intraparticle diffusion rate of both reactant and product. This novel synthesis methodology provides a low-cost and environmentally-benign way for the preparation of hierarchical Beta zeolite, which could serve a sustainable platform of large-scale production of hierarchical zeolite for practical application.

Application In Synthesis of Benzyl ether. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem