Category: 103-50-4

An article Surface engineering in improving activity of Pt nanocubes for ammonia electrooxidation reaction WOS:000532683200058 published article about PREFERENTIAL 100 ORIENTATION; ELECTROCHEMICAL OXIDATION; PT-IR; FUEL-CELL; ANODIC-OXIDATION; PT(100) SITES; BINARY-ALLOYS; THIN-FILMS; PLATINUM; ELECTROCATALYSTS in [Siddharth, Kumar; Qin, Xueping; Chan, Yat Tung; Zhu, Shangqian; Shao, Minhua] Hong Kong Univ Sci & Technol, Dept Chem & Biol Engn, Kowloon, Clear Water Bay, Hong Kong, Peoples R China; [Hong, Youngmin; Lee, Hye Jin; Choi, Sang-Il] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea; [Hong, Youngmin; Lee, Hye Jin; Choi, Sang-Il] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Daegu 41566, South Korea; [Chen, Guohua] Hong Kong Polytech Univ, Dept Mech Engn, Kowloon, Hong Kong, South Korea in 2020, Cited 57. Name: Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Ammonia (NH3) electro-oxidation reaction (AOR) is an important reaction in direct NH3 fuel cells, NH3 electrolyzer, and NH3-based electrochemical sensors. However, its slow kinetics and structure-sensitive properties require specific electrocatalyst designs. In this study, Ir-decorated N nanocubes are developed as unique surface engineered model catalysts. For the first time, we find that a trace amount of Ir (less than 2%) could increase the AOR activity of N nanocubes by more than twice. Theoretical simulation results also illustrate that the surfacedecorated Ir could lower the energy barrier in the rate determining *NH formation step on N surfaces, thus increasing activity in accordance with experimental findings. Additionally, Ir and Ni(OH)(2)-decorated N nanocubes can significantly improve the durability. Our findings demonstrate the importance of surface engineering in catalyst synthesis and pave the way of advanced electrocatalyst designs for ammonia oxidation and other catalytic reactions.

Name: Benzyl ether. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Name: Benzyl ether. I found the field of Chemistry very interesting. Saw the article Linker-assisted structuration of tunable uranium-based hybrid lamellar nanomaterials published in 2020, Reprint Addresses Maynadie, J (corresponding author), Univ Montpellier, CEA, ENSCM, CNRS,ICSM, Marcoule, France.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

Obtaining bulk materials ordered at the nanoscale using nanoparticles as building blocks is a new challenge for scientists and is of primary interest in some research areas. In this study, we developed a simple one-pot route towards nanostructured hybrid materials based on uranium oxide through a non-hydrolytic condensation process under mild solvothermal conditions (T = 160 degrees C) using ditopic organic linkers as structuring agents. The obtained materials present a sand rose morphology composed of agglomerated nanometric sheets with a lamellar substructure. Nanometric sheets are composed of inorganic fringes consisting of a studtite phase [(UO2)O-2(H2O)(2)]center dot 2H(2)O that alternates with organic fringes formed by the structuring organic linker. A multiparametric study based on SAXS experiments and TEM analyses has highlighted the control of structural parameters by varying some synthesis conditions. The interlamellar distances are tunable from 1.60 nm to 1.94 nm through the length of the structuring linker and the inter-sheet distance from 1.85 nm to 2.10 nm through synthesis temperature. This efficient one-pot route appears to be very promising for the production of tunable multiscale nanostructured hybrid materials and can be implemented in many research areas, paving the way for various applications.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

COA of Formula: C14H14O. In 2020 CATALYSTS published article about EFFECTIVE CATALYST; CARBONYL-COMPOUNDS; BENZYLIC ALCOHOLS; BROMOSUCCINIMIDE; ALKYLATION; STRATEGY; NBS in [Ajvazi, Njomza; Stavber, Stojan] Jozef Stefan Int Postgrad Sch, Jamova 39, Ljubljana 1000, Slovenia; [Stavber, Stojan] Jozef Stefan Inst, Jamova 39, Ljubljana 1000, Slovenia in 2020, Cited 42. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

N-halosuccinimides (chloro, bromo, and iodo, respectively) were introduced, tested, and applied as efficient and non-metal precatalysts for C-, N-, O-, and X-nucleophilic substitution reactions of alcohols under solvent-free reaction conditions (SFRC) or under high substrate concentration reaction conditions (HCRC) efficiently and selectively, into the corresponding products.

COA of Formula: C14H14O. Welcome to talk about 103-50-4, If you have any questions, you can contact Ajvazi, N; Stavber, S or send Email.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Gemini Surfactant-Directed Facile Pillaring of Two-Dimensional Zeolites with Enhanced Catalytic Activity in Friedel-Crafts Alkylation WOS:000573372100020 published article about UNIT-CELL THICK; LAYER STRUCTURE PRESERVATION; BRONSTED ACID SITES; EXTERNAL SURFACE; MOLECULAR-SIEVE; MWW ZEOLITES; MFI; NANOSHEETS; MCM-36; SELECTIVITY in [Yuan, Mei-Ting; Zhao, Dong-Yang; Hao, Qing-Qing; Luo, Qun-Xing; Zhang, Jianbo; Chen, Huiyong; Sun, Ming; Xu, Long; Ma, Xiaoxun] Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China; [Hao, Qing-Qing; Luo, Qun-Xing; Zhang, Jianbo; Chen, Huiyong; Sun, Ming; Xu, Long; Ma, Xiaoxun] Minist Educ Adv Use Technol Shanbei Energy, Chem Engn Res Ctr, Xian 710069, Shaanxi, Peoples R China; [Hao, Qing-Qing; Luo, Qun-Xing; Zhang, Jianbo; Chen, Huiyong; Sun, Ming; Xu, Long; Ma, Xiaoxun] Int Sci & Technol Cooperat Base Most Clean Utiliz, Collaborat Innovat Ctr Dev Energy & Chem Ind Nort, Xian 710069, Shaanxi, Peoples R China in 2020, Cited 42. Name: Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

We report an efficient procedure for the synthesis of pillared MWW zeolites (MCM-36) via integrating intercalation and hydrolysis of tetraethyl orthosilicate (TEOS) into one step. Specifically, two specially selected surfactants with more hydrophilicity instead of the conventional swelling agent cetyltrimethylammonium bromide (CTAB) were employed to increase the interlayer wetting ability and water content. The resultant intercalation and hydrolysis of TEOS occur concurrently in a confined interlayer microenvironment with enriched interlayer water and basic hexamethyleneimine (HMI). It is found that the wetting ability of swelling surfactants has a profound effect on pillarization efficiency, resulting in the different degrees of order of the layered structure, pore-size distribution, and accessibility of the acid sites of MCM-36. MCM-36 prepared using a gemini-type surfactant as a swelling agent shows a highly long-range ordered structure and enhanced catalytic activity for alkylation of benzene with benzyl alcohol compared to the one produced using conventional CTAB as a swelling agent.

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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Papadopoulos, GN; Kokotou, MG; Spiliopoulou, N; Nikitas, NF; Voutyritsa, E; Tzaras, DI; Kaplaneris, N; Kokotos, CG in [Papadopoulos, Giorgos N.; Kokotou, Maroula G.; Spiliopoulou, Nikoleta; Nikitas, Nikolaos F.; Voutyritsa, Errika; Tzaras, Dimitrios I.; Kaplaneris, Nikolaos; Kokotos, Christoforos G.] Natl & Kapodistrian Univ Athens, Dept Chem, Lab Organ Chem, Athens 15771, Greece published Phenylglyoxylic Acid: An Efficient Initiator for the Photochemical Hydrogen Atom Transfer C-H Functionalization of Heterocycles in 2020, Cited 107. Category: ethers-buliding-blocks. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

C-H functionalization at the alpha-position of heterocycles has become a rapidly growing area of research. Herein, a cheap and efficient photochemical method was developed for the C-H functionalization of heterocycles. Phenylglyoxylic acid (PhCOCOOH) could behave as an alternative to metal-based catalysts and organic dyes and provided a very general and wide array of photochemical C-H alkylation, alkenylation, and alkynylation, as well as C-N bond forming reaction methodologies. This novel, mild, and metal-free protocol was successfully employed in the functionalization of a wide range of C-H bonds, utilizing not only O- or N-heterocycles, but also the less studied S-heterocycles.

Welcome to talk about 103-50-4, If you have any questions, you can contact Papadopoulos, GN; Kokotou, MG; Spiliopoulou, N; Nikitas, NF; Voutyritsa, E; Tzaras, DI; Kaplaneris, N; Kokotos, CG or send Email.. Category: ethers-buliding-blocks

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2021 J ENERGY INST published article about PHENOLIC-COMPOUNDS; METAL-CATALYSTS; ENZYMATIC-HYDROLYSIS; CARBON; GUAIACOL; BIOMASS; CONVERSION; FUELS; HYDROCONVERSION; HYDROGENOLYSIS in [Hu, Lin; Wei, Xian-Yong; Kang, Yu-Hong; Guo, Xian-Hou; Xu, Mei-Ling; Zong, Zhi-Ming] China Univ Min & Technol, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China; [Wei, Xian-Yong] Ningxia Univ, State Key Lab High Efficiency Coal Utilizat & Gre, Yinchuan 750021, Ningxia, Peoples R China in 2021, Cited 59. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Application In Synthesis of Benzyl ether

Recently high yield of cycloalkanes originates from selective hydrodeoxygenation (HDO) of lignin-derived bio-oil under mild conditions, which still encounters the great challenges. Herein, mordenite-supported ruthenium bifunctional catalyst (Ru3%/M) was prepared by using the deposition-precipitation (DP) method for the HDO reaction of the petroleum ether-extractable portions (PEEP) from alkali catalytic ethanolysis of lignin (CEOL). Ru3%/M catalyst was characterized systematically by XRD, XPS, FTIRS, NH3-TPD, N-2-adsorption, SEM, and TEM, indicating that it had the moderate acid sites and uniform Ru nanoparticles dispersion. The synthesized catalyst was further tested for the HDO per-formance of diphenyl ether, oxybis(methylene)dibenzene, and anisole, respectively. Results showed that three lignin model compounds can be converted to high yield of cycloalkanes under 160 degrees C and 3 MPa H-2 in n-hexane. This catalyst showed the high catalytic activity for diphenyl ether HDO reaction, the con -version decreased slightly to 87.6% after five recycle times. Furthermore, catalyst feed mass was the key factor for HDO reaction of raw PEEP from CEOL, promoting the HDO reaction process to produce high yield of cycloalkanes. Interestingly, the mass ratio between catalyst feed and raw PEEP was 1, thus 74.36% relative content (RC) of cycloalkanes can be obtained. The upgraded PEEP from CEOL has potential to be used as clean liquid fuels. (C) 2021 Energy Institute. Published by Elsevier Ltd. All rights reserved.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Gong, F; Cheng, L; Yang, NL; Betzer, O; Feng, LZ; Zhou, Q; Li, YG; Chen, RH; Popovtzer, R; Liu, Z in [Gong, Fei; Cheng, Liang; Yang, Nailin; Feng, Liangzhu; Liu, Zhuang] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China; [Betzer, Oshra; Popovtzer, Rachela] Bar Ilan Univ, Fac Engn, IL-52900 Ramat Gan, Israel; [Betzer, Oshra; Popovtzer, Rachela] Bar Ilan Univ, Inst Nanotechnol & Adv Mat, IL-52900 Ramat Gan, Israel; [Zhou, Qiang; Li, Yonggang; Chen, Ruihua] Soochow Univ, Affiliated Hosp 1, Dept Radiol, Suzhou 215006, Jiangsu, Peoples R China published Ultrasmall Oxygen-Deficient Bimetallic Oxide MnWOX Nanoparticles for Depletion of Endogenous GSH and Enhanced Sonodynamic Cancer Therapy in 2019, Cited 40. Category: ethers-buliding-blocks. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Sonodynamic therapy (SDT) triggered by ultrasound (US) has attracted increasing attention owing to its abilities to overcome critical limitations including low tissue-penetration depth and phototoxicity in photodynamic therapy. Herein, the design of a new type of sonosensitizer is revealed, namely, ultrasmall oxygen-deficient bimetallic oxide MnWOX nanoparticles, for multimodal imaging-guided enhanced SDT against cancer. As-made MnWOX nanoparticles with poly(ethylene glycol) (PEG) modification show high physiological stability and biocompatibility. Interestingly, such MnWOX-PEG nanoparticles exhibit highly efficient US-triggered production of O-1(2) and center dot OH, higher than that of previously reported sonosensitizers (e.g., protoporphyrin IX and titanium dioxide), because the oxygen-deficient structure of MnWOX serves as an electron trap site to prevent electron-hole recombination. The glutathione depletion capability of MnWOX-PEG can also further favor SDT-triggered cancer cell killing. With efficient tumor homing as illustrated by computer tomography and magnetic resonance imaging, MnWOX-PEG enables effective destruction of mouse tumors under US stimulation. After accomplishing its therapeutic functions, MnWOX-PEG can be metabolized by the mouse body without any long-term toxicity. Herein, a new type of sono-sensitizing agent with high SDT efficacy, multimodal imaging functions, and rapid clearance is presented, an agent which is promising for noninvasive SDT cancer treatment.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2019 MICROPOR MESOPOR MAT published article about STRUCTURE-DIRECTING AGENTS; HIGH-SILICA CHABAZITE; INTERZEOLITE CONVERSION; FAU ZEOLITE; CHA ZEOLITE; CATALYTIC PERFORMANCE; STABILITY; TRANSFORMATIONS; ALUMINOSILICATE; NOX in [Tanigawa, Takuya; Tsunoji, Nao; Sadakane, Masahiro; Sano, Tsuneji] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan in 2019, Cited 56. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Safety of Benzyl ether

Zeolite synthesis using faujasite-type (FAU) zeolites as the starting silica/alumina source in the presence of various organic structure-directing agents (OSDAs) with cyclic alkylammonium structures was investigated. The obtained zeolite phases strongly depended on the structure of the OSDA and the Si/Al ratio of the starting FAU. Zeolites with different framework structures, such as BEA, MFI, CHA, and LEV, were obtained. Among the used OSDAs, methylpropylpyrrolidinium, butylmethylpyrrolidinium, and methylpropylpiperidinium effectively produced nanosized BEA and MFI zeolites, whereas dimethylpiperidinium and cyclohexyltrimethylammonium produced CHA and LEV zeolites, respectively. The nanosized MFI and BEA zeolites obtained through zeolite hydrothermal conversion exhibited remarkably smaller particle sizes and higher external surface area as compared to those of the conventional MFI and BEA zeolite samples synthesized using tetrapropylammonium and tetraethylammonium, respectively. We also found that the highly crystalline nanosized BEA and MFI zeolites exhibited better catalytic performance in the dehydration of benzyl alcohol to benzyl ether as compared to the conventional zeolites with large particle sizes. In addition, nanosized MFI zeolites, synthesized using FAU as a starting material and cyclic ammonium compounds, showed catalytic activities superior to those of the nano sized MFI zeolites synthesized from amorphous starting materials and cyclic ammonium compounds.

Safety of Benzyl ether. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Hu, L; Wei, XY; Kang, YH; Guo, XH; Xu, ML; Zong, ZM in ELSEVIER SCI LTD published article about PHENOLIC-COMPOUNDS; METAL-CATALYSTS; ENZYMATIC-HYDROLYSIS; CARBON; GUAIACOL; BIOMASS; CONVERSION; FUELS; HYDROCONVERSION; HYDROGENOLYSIS in [Hu, Lin; Wei, Xian-Yong; Kang, Yu-Hong; Guo, Xian-Hou; Xu, Mei-Ling; Zong, Zhi-Ming] China Univ Min & Technol, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China; [Wei, Xian-Yong] Ningxia Univ, State Key Lab High Efficiency Coal Utilizat & Gre, Yinchuan 750021, Ningxia, Peoples R China in 2021, Cited 59. Safety of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Recently high yield of cycloalkanes originates from selective hydrodeoxygenation (HDO) of lignin-derived bio-oil under mild conditions, which still encounters the great challenges. Herein, mordenite-supported ruthenium bifunctional catalyst (Ru3%/M) was prepared by using the deposition-precipitation (DP) method for the HDO reaction of the petroleum ether-extractable portions (PEEP) from alkali catalytic ethanolysis of lignin (CEOL). Ru3%/M catalyst was characterized systematically by XRD, XPS, FTIRS, NH3-TPD, N-2-adsorption, SEM, and TEM, indicating that it had the moderate acid sites and uniform Ru nanoparticles dispersion. The synthesized catalyst was further tested for the HDO per-formance of diphenyl ether, oxybis(methylene)dibenzene, and anisole, respectively. Results showed that three lignin model compounds can be converted to high yield of cycloalkanes under 160 degrees C and 3 MPa H-2 in n-hexane. This catalyst showed the high catalytic activity for diphenyl ether HDO reaction, the con -version decreased slightly to 87.6% after five recycle times. Furthermore, catalyst feed mass was the key factor for HDO reaction of raw PEEP from CEOL, promoting the HDO reaction process to produce high yield of cycloalkanes. Interestingly, the mass ratio between catalyst feed and raw PEEP was 1, thus 74.36% relative content (RC) of cycloalkanes can be obtained. The upgraded PEEP from CEOL has potential to be used as clean liquid fuels. (C) 2021 Energy Institute. Published by Elsevier Ltd. All rights reserved.

Welcome to talk about 103-50-4, If you have any questions, you can contact Hu, L; Wei, XY; Kang, YH; Guo, XH; Xu, ML; Zong, ZM or send Email.. Safety of Benzyl ether

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recently I am researching about BENZYL ALCOHOL; CRUDE GLYCEROL; CONVERSION; DEACTIVATION; ETHERS; FUEL, Saw an article supported by the Universidad Nacional de La PlataNational University of La Plata [X757, X802]; ANPCyTANPCyT [PICT 2016-0148]; UNNOBA (project SIB 2019) [0596/2019]; CICPBA (project (PIT-AP-BA)) from Argentina [No428/2016]. Published in ELSEVIER in AMSTERDAM ,Authors: Chiosso, ME; Casella, ML; Merlo, AB. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. SDS of cas: 103-50-4

In this paper, the catalytic behaviour of carbonaceous system (Ccs) functionalized with -SO3H groups were studied in the etherification of refined (Gly) and crude glycerol (GlyC), with benzyl alcohol (BA). This Ccs was obtained by a synthetic method with low energetic cost in only 24 h. Its catalytic activity and selectivity were studied varying the catalyst percentage (2.5, 5 and 10 wt.%), the initial reactant molar ratio and temperature (between 80 and 120 degrees C). A very good catalytic performance was achieved (97 % conversion after 360 min of reaction), at 120 degrees C, Gly:BA = 3:1 and 10 wt.% of Ccs. The high activity can be attributed to high acid site density (6.4 mmol H+/g), that also allowed us to working at lower reaction temperature (100 degrees C) and with less catalyst concentration (2.5 wt.%), without observing significant loss in BA conversion. Monoether (ME1) was the major product of the reaction with 72 % selectivity. The material can be reused and still gives a notable conversion of BA (about 43 %) after three successive reuses. Finally, the Ccs was active and selective to the desired products in the etherification of crude glycerol (GlyC) derived of biodiesel industry. An important BA conversion (45 %) was obtained only reducing the water content of GlyC and without carrying out any other purification and/or neutralization treatment.

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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem