Category: 103-50-4

Name: Benzyl ether. Recently I am researching about RING-OPENING POLYMERIZATION; METAL-FREE; CRYSTAL-STRUCTURE; REDUCTIVE DEPOLYMERIZATION; CARBONYL-COMPOUNDS; ALDOL CONDENSATION; SYMMETRIC ETHERS; CARBOXYLIC-ACIDS; CYCLOTRIMERIZATION; ETHERIFICATION, Saw an article supported by the CEA, CNRS, the University Paris-Saclay; ANRFrench National Research Agency (ANR); H2020 (ERC). Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Monsigny, L; Thuery, P; Berthet, JC; Cantat, T. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

We report herein the possibility to perform the hydrosilylation of carbonyls using actinide complexes as catalysts. While complexes of the uranyl ion [UO2](2+) have been poorly considered in catalysis, we show the potentialities of the Lewis acid [UO2(OTf)(2)] (1) in the catalytic hydrosilylation of a series of aldehydes. [UO2(OTf)(2)] proved to be a very active catalyst affording distinct reduction products depending on the nature of the reductant. With Et3SiH, a number of aliphatic and aromatic aldehydes are reduced into symmetric ethers, while (Pr3SiH)-Pr-i yielded silylated alcohols. Studies of the reaction mechanism led to the isolation of aldehyde/uranyl complexes, [UO2(OTf)(2)(4-Me2N-PhCHO)(3)], [UO2(mu-kappa(2)-OTf)(2)(PhCHO)](n), and [UO2(mu-kappa(2)-OTf(kappa(1)-OTf)(PhCHO)(2)](2), which have been fully characterized by NMR, IR, and single-crystal X-ray diffraction.

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Name: Benzyl ether. Muro-Cruces, J; Roca, AG; Lopez-Ortega, A; Fantechi, E; del-Pozo-Bueno, D; Estrade, S; Peiro, F; Sepulveda, B; Pineider, F; Sangregorio, C; Nogues, J in [Muro-Cruces, Javier; Roca, Alejandro G.; Sepulveda, Borja; Nogues, Josep] CSIC, ICN2, Campus UAB, Barcelona 08193, Spain; [Muro-Cruces, Javier; Roca, Alejandro G.; Sepulveda, Borja; Nogues, Josep] BIST, Campus UAB, Barcelona 08193, Spain; [Muro-Cruces, Javier] Univ Autonoma Barcelona, Bellaterra 08193, Spain; [Lopez-Ortega, Alberto] Univ Castilla La Mancha, Inst Nanociencia Nanotecnol & Mat Mol, Campus Fabr Armas, Toledo 45071, Spain; [Lopez-Ortega, Alberto] Univ Castilla La Mancha, Dept Fis Aplicada, Campus Fabr Armas, Toledo 45071, Spain; [Fantechi, Elvira; Pineider, Francesco] Univ Pisa, Dipartimento Chim & Chim Ind, Via G Moruzzi 13, I-56124 Pisa, Italy; [Fantechi, Elvira; Pineider, Francesco] Univ Pisa, INSTM, Via G Moruzzi 13, I-56124 Pisa, Italy; [del-Pozo-Bueno, Daniel; Estrade, Sonia; Peiro, Francesca] Univ Barcelona, Dept Enginyeries Elect & Biomed, LENS MIND IN2UB, Marti & Franques 1, E-08028 Barcelona, Spain; [Sangregorio, Claudio] Univ Firenze, Dipartimento Chim, Via Lastruccia 3, I-50019 Sesto Fiorentino, FI, Italy; [Sangregorio, Claudio] Univ Firenze, INSTM, Via Lastruccia 3, I-50019 Sesto Fiorentino, FI, Italy; [Sangregorio, Claudio] ICCOM CNR, Via Madonna Piano 10, I-50019 Sesto Fiorentino, FI, Italy; [Nogues, Josep] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain published Precise Size Control of the Growth of Fe3O4 Nanocubes over a Wide Size Range Using a Rationally Designed One-Pot Synthesis in 2019, Cited 56. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

The physicochemical properties of spinel oxide magnetic nanoparticles depend critically on both their size and shape. In particular, spinel oxide nanocrystals with cubic morphology have shown superior properties in comparison to their spherical counterparts in a variety of fields, like, for example, biomedicine. Therefore, having an accurate control over the nanoparticle shape and size, while preserving the crystallinity, becomes crucial for many applications. However, despite the increasing interest in spinel oxide nanocubes there are relatively few studies on this morphology due to the difficulty to synthesize perfectly defined cubic nanostructures, especially below 20 nm. Here we present a rationally designed synthesis pathway based on the thermal decomposition of iron(III) acetylacetonate to obtain high quality nanocubes over a wide range of sizes. This pathway enables the synthesis of monodisperse Fe3O4 nanocubes with edge length in the 9-80 nm range, with excellent cubic morphology and high crystallinity by only minor adjustments in the synthesis parameters. The accurate size control provides evidence that even 1-2 nm size variations can be critical in determining the functional properties, for example, for improved nuclear magnetic resonance T-2 contrast or enhanced magnetic hyperthermia. The rationale behind the changes introduced in the synthesis procedure (e.g., the use of three solvents or adding Na-oleate) is carefully discussed. The versatility of this synthesis route is demonstrated by expanding its capability to grow other spinel oxides such as Co-ferrites, Mn-ferrites, and Mn3O4 of different sizes. The simplicity and adaptability of this synthesis scheme may ease the development of complex oxide nanocubes for a wide variety of applications.

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I found the field of Chemistry very interesting. Saw the article Highly Efficient and Selective N-Alkylation of Amines with Alcohols Catalyzed by in Situ Rehydrated Titanium Hydroxide published in 2020. Safety of Benzyl ether, Reprint Addresses Khodakov, AY (corresponding author), Univ Artois, Univ Lille, CNRS, Cent Lille,ENSCL,UCCS,UMR 8181, F-59000 Lille, France.; Ordomsky, VV (corresponding author), CNRS Solvay, UMI 3464, E2P2L, Shanghai 201108, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Catalytic N-alkylation of amines by alcohols to produce desired amines is an important catalytic reaction in industry. Various noble-metal-based homogeneous and heterogeneous catalysts have been reported for this process. The development of cheap non-noble-metal heterogeneous catalysts for the N-alkylation reaction would be highly desirable. Hereby, we propose the N-alkylation of amines by alcohols over a cheap and efficient heterogeneous catalyst-titanium hydroxide. This catalyst provides a selectivity higher than 90% to secondary amines for functionalized aromatic and aliphatic alcohols and amines with high catalytic activity and stability. Mild Bronsted acidity formed by the continuous rehydration of Lewis acidity excludes the side reactions and deactivation by adsorbed species. The mechanism of the reaction involves dehydration of alcohols to ethers with subsequent C-O bond cleavage by amine with the formation of secondary amine and recovery of alcohol.

Safety of Benzyl ether. Welcome to talk about 103-50-4, If you have any questions, you can contact Niu, F; Wang, QY; Yan, Z; Kusema, BT; Khodakov, AY; Ordomsky, VV or send Email.

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Ether – Wikipedia,
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SDS of cas: 103-50-4. Xu, LJ; Yuan, YY; Han, Q; Dong, L; Chen, L; Zhang, XM; Xu, L in [Xu, Lanjian; Yuan, Yangyang; Han, Qiao; Dong, Lei; Chen, Lei; Zhang, Xiaomin; Xu, Lei] Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, Dalian 116023, Peoples R China; [Xu, Lanjian; Han, Qiao; Dong, Lei; Chen, Lei] Univ Chinese Acad Sci, Beijing 100049, Peoples R China published High yield synthesis of nanoscale high-silica ZSM-5 zeolites via interzeolite transformation with a new strategy in 2020, Cited 51. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A novel interzeolite transformation strategy using internally confined organic structure directing agents (OSDAs), called the OSDA-confined strategy, is proposed for highly crystalline nanosized high-silica ZSM-5 zeolite synthesis, by which high yield and fast synthesis of ZSM-5 is achieved using BEA zeolite as a raw material. The transformation process was investigated by XRD, SEM, ICP, FTIR and UV Raman spectroscopy, which revealed that the decomposition of a parent zeolite and the crystallization process of products were well modulated by the confined OSDA. The transformation process could be divided into three stages consisting of raw material deconstruction, small size product formation and product growth. The strong etching power of NaOH contributes to the fast decomposition of BEA zeolites. In addition, tetrapropylammonium hydroxide (TPAOH) as an OSDA was confined in the parent zeolite instead of being added into the mother liquid, achieving a high local concentration of TPAOH, which could reduce the decomposition rate of the parent BEA zeolite and promote the efficient organization of the building units generated by the decomposition of the BEA zeolite. Thereof, a high yield was achieved by the synergistic effect of NaOH and occluded TPAOH. During the interzeolite transformation process, the six-membered rings (6Rs), five-membered rings (5Rs) and four-membered rings (4Rs) in the BEA zeolite framework were disassembled and combined with the help of 5Rs to produce the ZSM-5 zeolite structure. Moreover, due to the nanoscale and large surface area, the obtained ZSM-5 zeolite catalyst showed extremely high catalytic activity in the self-etherification reaction of benzyl alcohol (BA) to dibenzyl ether (DE). This study provides insights into the interzeolite transformation process, which would be helpful for achieving size control and high-efficiency synthesis.

SDS of cas: 103-50-4. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article High hydrogen production rate on RuS2@ MoS2 hybrid nanocatalyst by PEM electrolysis WOS:000459236100003 published article about EVOLUTION REACTION; MOLYBDENUM-DISULFIDE; OXYGEN REDUCTION; FUEL-CELL; NANOPARTICLES; CATALYSTS; ACID; ELECTROCATALYSTS; THIOPHENE; XPS in [Sarno, Maria] Univ Salerno, Dept Ind Engn, Via Giovanni Paolo II 132, I-84084 Fisciano SA, Italy; Univ Salerno, NANO MATES Res Ctr, Via Giovanni Paolo II 132, I-84084 Fisciano SA, Italy in 2019, Cited 58. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Product Details of 103-50-4

A new nanocatalyst, which combines the electrocatalytic activity of MoS2 nanosheets and RuS2 nanoparticles (NPs), was prepared through a safe and scalable, one-step bottom-up approach. It delivers high current density, with a Tafel slope of 36 mV/dec and a very small overpotential. The high exposure of MoS2 edges on the RuS2 NPs, the stronger d character of RuS2 and the electrical coupling of these two nanomaterials, grown together, were responsible for the high hydrogen production rates of 10.21/h (PEM cell 5cm x 5 cm, current density about 1.1 A/cm(2), power consumption 41.8 W, corresponding to 3.8 KWh/Nm(3) of energy consumption, efficiency 93%). (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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Ether – Wikipedia,
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In 2019 RUSS J ORG CHEM+ published article about CONJUGATED MAGNETIC NANOPARTICLES; EFFICIENT; CATALYST in [Sedighinia, E.; Badri, R.] Islamic Azad Univ, Dept Chem, Khouzestan Sci & Res Branch, Ahwaz, Iran; [Sedighinia, E.; Badri, R.] Islamic Azad Univ, Dept Chem, Ahvaz Branch, Ahwaz, Iran; [Kiasat, A. R.] Shahid Chamran Univ, Coll Sci, Dept Chem, Ahwaz 6135743169, Iran in 2019, Cited 30. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. HPLC of Formula: C14H14O

The application of yttrium iron garnet (YIG) superparamagnetic nanoparticles as a new recyclable and highly efficient heterogeneous magnetic catalyst for one-pot synthesis of pyrano[2,3-c]pyrazole derivatives under solvent-free conditions, as well as etherification and esterification reactions are described. The advantages of the proposed method include the lack of organic solvents, clean reaction, rapid removal of the catalyst, short reaction times, excellent yields, and recyclability of the catalyst.

HPLC of Formula: C14H14O. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Safety of Benzyl ether. I found the field of Gastroenterology & Hepatology very interesting. Saw the article The Influence of Disease Activity on Pregnancy Outcomes in Women With Inflammatory Bowel Disease: A Systematic Review and Meta-Analysis published in 2021, Reprint Addresses Park, JJ (corresponding author), Yonsei Univ, Severance Hosp, Dept Internal Med, Div Gastroenterol,Coll Med, 50-1 Yonsei Ro, Seoul 03722, South Korea.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

Background and Aims: Robust evidence regarding the impact of disease activity on pregnancy outcomes in women with inflammatory bowel disease [IBD] is crucial for both clinicians and patients in preparing a birth plan. We sought to perform a systematic review and meta-analysis to assess the pooled influences of disease activity on pregnancy outcomes in women with IBD. Methods: We searched MEDLINE, EMBASE and the COCHRANE library to identify articles comparing pregnancy outcomes between active and inactive IBD at the time of conception or during pregnancy. A meta-analysis was performed using a random-effects model to pool estimates and report odds ratios [ORs]. Results: A total of 28 studies were identified as eligible for the meta-analysis. In women with active IBD, the pooled ORs for low birth weight [LBW], preterm birth, small for gestational age [SGA], spontaneous abortion and stillbirths were respectively 3.81 (95% confidence interval [CI] 1.81-8.02), 2.42 [95% CI 1.74-3.35], 1.48 [95% CI 1.19-1.85], 1.87 [95% CI 1.17-3.0] and 2.27 [95% CI 1.03-5.04] compared to women with inactive IBD. In the subgroup analysis based on disease type, women with active ulcerative colitis had an increased risk of LBW, preterm birth and spontaneous abortion. Women with active Crohn’s disease had a higher risk of preterm birth, SGA and spontaneous abortion. Conclusions: Active IBD during the periconception period and pregnancy is associated with an increased risk of adverse pregnancy outcomes. Our data suggest that pregnancy should be planned when the disease is quiescent, and continuous disease control is important even during pregnancy.

Safety of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Kim, MA; Kim, YH; Chun, J; Lee, HS; Park, SJ; Cheon, JH; Il Kim, T; Kim, WH; Park, JJ or concate me.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Gambe, J; Jouin, J; Remondiere, F; Thomas, P; Masson, O in SPRINGER published article about SOLVOTHERMAL SYNTHESIS; SIZE DEPENDENCE; ZIRCONIA; TEMPERATURE; STABILIZATION; NANOCRYSTALS in [Gambe, Jess; Jouin, Jenny; Remondiere, Fabien; Thomas, Philippe; Masson, Olivier] Ctr Europeen Ceram, IRCER UMR 7315, 12 Rue Atlantis, F-87068 Limoges, France in 2020, Cited 37. HPLC of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

This work deals with the synthesis of zirconium dioxide (ZrO2) nanoparticles (NPs) in different solvents and their structural characterization for better understanding the oxygen donor solvent/zirconium precursor/NPs structure relationships. By selecting solvents over their capacity to produce different crystalline states from alkalinized zirconium alkoxide, spherical nanoparticles with a size of about 1.3-3 nm and a narrow size distribution were elaborated using a nonaqueous solvothermal sol-gel route. Conventional X-ray diffraction (XRD) was used to determine the average structure and crystallite size of the nanoparticles. Well-crystallized and single-phased nanoparticles with average monoclinic and tetragonal structure were obtained with benzaldehyde and benzyl alcohol, respectively, and a much distorted structure was observed for the synthesis in anisole. The atomic pair distribution functions (PDF) of the samples were also analyzed to access the local structure of the nanoparticles. The PDF of the benzaldehyde-prepared sample is consistent with the monoclinic structure. However, the local structure of nanoparticles synthesized with benzyl alcohol does not fully conform to the tetragonal structure observed by XRD, but exhibits monoclinic-like distortions. Lastly, the anisole-prepared nanoparticles present large structural distortions at the medium range and monoclinic local structural features. The restructuring of this last sample was studied by post-treatments in different solvents and leads to the expression of the tetragonal polymorph. Moreover, it seems that the main structural features are obtained in the early stages of the nanoparticles’ formation.

HPLC of Formula: C14H14O. Welcome to talk about 103-50-4, If you have any questions, you can contact Gambe, J; Jouin, J; Remondiere, F; Thomas, P; Masson, O or send Email.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Application In Synthesis of Benzyl ether. I found the field of Chemistry very interesting. Saw the article Linker-assisted structuration of tunable uranium-based hybrid lamellar nanomaterials published in 2020, Reprint Addresses Maynadie, J (corresponding author), Univ Montpellier, CEA, ENSCM, CNRS,ICSM, Marcoule, France.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

Obtaining bulk materials ordered at the nanoscale using nanoparticles as building blocks is a new challenge for scientists and is of primary interest in some research areas. In this study, we developed a simple one-pot route towards nanostructured hybrid materials based on uranium oxide through a non-hydrolytic condensation process under mild solvothermal conditions (T = 160 degrees C) using ditopic organic linkers as structuring agents. The obtained materials present a sand rose morphology composed of agglomerated nanometric sheets with a lamellar substructure. Nanometric sheets are composed of inorganic fringes consisting of a studtite phase [(UO2)O-2(H2O)(2)]center dot 2H(2)O that alternates with organic fringes formed by the structuring organic linker. A multiparametric study based on SAXS experiments and TEM analyses has highlighted the control of structural parameters by varying some synthesis conditions. The interlamellar distances are tunable from 1.60 nm to 1.94 nm through the length of the structuring linker and the inter-sheet distance from 1.85 nm to 2.10 nm through synthesis temperature. This efficient one-pot route appears to be very promising for the production of tunable multiscale nanostructured hybrid materials and can be implemented in many research areas, paving the way for various applications.

Welcome to talk about 103-50-4, If you have any questions, you can contact Re, E; Le Goff, X; Toquer, G; Maynadie, J; Meyer, D or send Email.. Application In Synthesis of Benzyl ether

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Discovery of Novel Resorcinol Dibenzyl Ethers Targeting the Programmed Cell Death-1/Programmed Cell Death-Ligand 1 Interaction as Potential Anticancer Agents WOS:000562941200026 published article about IMMUNE CHECKPOINT BLOCKADE; CANCER; IMMUNOTHERAPY; PD-L1; ACTIVATION; INHIBITORS in [Cheng, Binbin; Ren, Yichang; Niu, Xiaoge; Wang, Wei; Wang, Shuanghu; Tu, Yingfeng; Liu, Shuwen; Chen, Jianjun] Southern Med Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab New Drug Screening, Guangzhou 510515, Peoples R China; [Wang, Jin] AbbVie Inc, N Chicago, IL 60064 USA; [Yang, Deying; Liao, Guochao] Guangzhou Univ Chinese Med, Joint Lab Translat Canc Res Chinese Med, Minist Educ Peoples Republ China, Int Inst Translat Chinese Med, Guangzhou 510006, Peoples R China in 2020, Cited 48. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Formula: C14H14O

Novel small molecule compounds based on various scaffolds including chalcone, flavonoid, and resorcinol dibenzyl ether were designed and tested for their inhibitory activity against the Programmed Cell Death-1/Programmed Cell Death-Ligand 1 (PD-1/PD-L1) pathway. Among them, compound NP19 inhibited the human PD-1/PD-L1 interaction with IC50 values of 12.5 nM in homogeneous time-resolved fluorescence (HTRF) binding assays. In addition, NP19 dose-dependently elevated IFN-gamma production in a coculture model of Hep3B/OS-8/hPD-L1 and CD3 T cells. Furthermore, NP19 displayed significant in vivo antitumor efficacy in two different mouse models of cancer (a melanoma B16-F10 tumor model and an H22 hepatoma tumor model). Moreover, H&E staining and flow cytometry data suggested that NP19 activated the immune microenvironment in the tumor, which may contribute to its antitumor effects. This work shows NP19 is a promising lead compound for further development as a new generation of small molecule inhibitors targeting the PD-1/PD-L1 pathway.

Welcome to talk about 103-50-4, If you have any questions, you can contact Cheng, BB; Ren, YC; Niu, XG; Wang, W; Wang, SH; Tu, YF; Liu, SW; Wang, J; Yang, DY; Liao, GC; Chen, JJ or send Email.. Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem