Category: 103-50-4

An article Bimetallic Oxide FeWO(X)Nanosheets as Multifunctional Cascade Bioreactors for Tumor Microenvironment-Modulation and Enhanced Multimodal Cancer Therapy WOS:000567835100001 published article about PHOTODYNAMIC THERAPY; NANOPARTICLES; EFFICIENT; GROWTH in [Gong, Fei; Chen, Muchao; Yang, Nailin; Dong, Ziliang; Tian, Longlong; Hao, Yu; Zhuo, Mingpeng; Liu, Zhuang; Chen, Qian; Cheng, Liang] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab CarbonBased Funct Mat & Devices, Suzhou 215123, Peoples R China in 2020, Cited 36. Computed Properties of C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Modulating the hostile tumor microenvironment (TME) rather than directly killing cancer cells may be an effective strategy to improve the therapeutic benefits in cancer treatment. Herein, FeWO(X)nanosheets are constructed as cascade bioreactors to modulate the TME and enhance radiotherapy and immunotherapy of tumors. Synthesized by the thermal-decomposition method and modified by poly(ethylene glycol) (PEG), the obtained FeWOX-PEG with multivalent metal elements (Fe2+/3+, W5+/6+) exhibit efficient catalytic decomposition of hydrogen peroxide (H2O2) to generate hydroxyl radicals (center dot OH) for chemo-dynamic therapy (CDT). The generated high valence of metal ions (Fe3+/W6+) in FeWOX-PEG are reduced by endogenous glutathione (GSH), both leading to depletion of GSH and further amplified oxidative stress, and resulting in the reduced metal valence statuses (Fe2+/W5+) enabling cascade bioreactions. Such FeWOX-PEG bioreactors enhance the oxidative stress in the tumor and interact with X-rays, significantly improving cancer radiotherapy (RT). Furthermore, the reactive oxygen species (ROS)-induced inflammation caused by FeWOX-PEG in TME activates the immune system and promotes the tumor-infiltration of various types of immune cells, which working together with cytotoxic T-lymphocyte antigen-4 (CTLA-4) checkpoint blockade could elicits a robust immune response to defeat tumors.

Welcome to talk about 103-50-4, If you have any questions, you can contact Gong, F; Chen, MC; Yang, NL; Dong, ZL; Tian, LL; Hao, Y; Zhuo, MP; Liu, Z; Chen, Q; Cheng, L or send Email.. Computed Properties of C14H14O

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An article A method of detecting two tumor markers (p-hydroxybenzoic acid and p-cresol) in human urine using a porous magnetic < beta > -cyclodextrine polymer as solid phase extractant, an alternative for early gastric cancer diagnosis WOS:000447481600018 published article about NANOPARTICLES; FABRICATION; FACILE; WATER; OXIDE in [Shi, Yi; Zhang, Jingyi; He, Jia; Liu, Donghao; Meng, Xiaoyan; He, Hua] China Pharmaceut Univ, Dept Analyt Chem, 24 Tongjia Lane, Nanjing 211198, Jiangsu, Peoples R China; [Huang, Tao] China Pharmaceut Univ, State Key Lab Nat Med, Nanjing 211198, Jiangsu, Peoples R China; [He, Hua] China Pharmaceut Univ, Key Lab Drug Qual Control & Phannacovigilance, Minist Educ, Nanjing 211198, Jiangsu, Peoples R China in 2019, Cited 28. Name: Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Analyzing of tumor markers has become an important means for cancer diagnosis and prevention. In this study, a novel solid phase extraction based on porous magnetic cyclodextrin polymer (MA-CD) was developed and used for detection of trace small molecule gastric tumor markers in urine samples. The adsorption properties of the magnetic cyclodextrin polymer were tested. Through experiments of the solid phase extraction (SPE) at the different condition, the optimal condition was selected to test the two tumor markers by High-performance liquid chromatography -Diode array detector (HPLC-DAD). The analytical performance of the method showed good accuracy (88.82%-104.34%) and precision (< 3.55%), appropriated detection limits (1.016 and 5.714 mu g L-1) and linear ranges (0.6-24.0 mu g L-1) with convenient determination coefficients (> 0.9994). The results demonstrated that the developed approach is efficient, low-cost for gastric tumor markers detection.

Welcome to talk about 103-50-4, If you have any questions, you can contact Shi, Y; Zhang, JY; He, J; Liu, DH; Meng, XY; Huang, T; He, H or send Email.. Name: Benzyl ether

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Recommanded Product: Benzyl ether. Recently I am researching about BIODIESEL PRODUCTION; ZIRCONIA CATALYSTS; SURFACE-STRUCTURE; CRYSTAL PHASE; CO ADSORPTION; TIO2-B 100; TITANIA; ESTERIFICATION; NANOCOMPOSITES; CONDENSATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21406118, 21774059]; Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX17_0852]; State Key Laboratory of Materials-Oriented Chemical Engineering [ZK201702, KL16-01]; Priority Academic Program Development of Jiangsu Higher Education Institutions. Published in ELSEVIER SCIENCE BV in AMSTERDAM ,Authors: Li, LC; Yue, HQ; Ji, T; Li, W; Zhao, XJ; Wang, L; She, J; Gu, XL; Li, XB. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Mesoporous TiO2(B) whisker was firstly applied as a support for synthesizing the novel sulfated solid superacid (SO42-/TiO2(B)). According to NH3-TPD, TG and Py-IR characterization results, it was found that the similar amount of sulfate group on TiO2(B) and anatase showed significantly different acid characteristics and catalytic performances. The total acid amount of SO42-/TiO2(B) was about 1.8 times as anatase-supported sulfated solid superacid (SO42-/Anatase). Simultaneously, the SO42-/TiO2(B) possessed higher percentage of Bronsted acid and more weak-medium acid strength than SO42-/Anatase. These acidic properties endowed SO42-/TiO2(B) with the increased esterification reaction rate and decreased alkylation byproduct selectivity compared with that of SO42-/Anatase. Structure-performance analysis exhibited that there were more bridged bidentate sulfate groups coordinated to the TiO2(B) in SO42-/TiO2(B), which could induce more Ti cations than that of the chelating one. This was the key factor to be responsible for the unique acid characteristics of SO42-/TiO2(B). The present work provides a novel solid superacid and might open a strategy to mediate the acid characteristic for sulfated solid superacid.

Welcome to talk about 103-50-4, If you have any questions, you can contact Li, LC; Yue, HQ; Ji, T; Li, W; Zhao, XJ; Wang, L; She, J; Gu, XL; Li, XB or send Email.. Recommanded Product: Benzyl ether

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Authors Nguyen, VHH; Doan, SH; Van, TT; Pham, PH; Nguyen, TTN; Nguyen, NN; Tu, TN; Phan, NTS in WILEY published article about ONE-POT SYNTHESIS; OXIME ACETATES; METAL; PYRIDINES; CYCLIZATION; ACTIVATION; FUNCTIONALIZATION; NANOPARTICLES; PERFORMANCE; ADSORPTION in [Nguyen, Vu H. H.; Doan, Son H.; Van, Tram T.; Pham, Phuc H.; Nguyen, Tran T. N.; Phan, Nam T. S.] HCMC Univ Technol, VNU HCM, Fac Chem Engn, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam; [Nguyen, Ngoc N.; Tu, Thach N.] VNU HCM, Ctr Innovat Mat & Architectures, Linh Trung Ward, Quarter 6, Ho Chi Minh City, Vietnam in 2019, Cited 44. Application In Synthesis of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Iron-based metal-organic framework VNU-20 was utilized as a heterogeneous catalyst for cascade reactions between ketoximes and dibenzyl ether to produce 2,4,6-triphenylpyridines. Additionally, benzyl alcohol and (dimethoxymethyl) benzene could be used as an alternative starting materials for the transformation. The oxidant exhibited a remarkable impact on the reactions, and di-tertbutylperoxide was the most appropriate candidate. The VNU-20 displayed higher efficiency than many homogeneous and heterogeneous catalysts. The catalyst was reusable for the cascade reactions without a noticeable deterioration in catalytic activity. This transformation is new, and would offer alternative routes to triphenylpyridines utilizing ketoximes as building blocks.

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HPLC of Formula: C14H14O. Authors Wang, Z; Wang, G; Kang, TT; Liu, SW; Wang, L; Zou, HY; Chong, Y; Liu, Y in BMC published article about in [Wang, Ze; Kang, Tingting; Liu, Shuwei; Liu, Yi] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China; [Zou, Haoyang] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130012, Peoples R China; [Chong, Yu] Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China; [Wang, Guan] Jilin Univ, China Japan Union Hosp, Dept Gastroenterol, Changchun 130033, Peoples R China; [Wang, Lu] Jilin Univ, Sch & Hosp Stomatol, Dept Oral Pathol, Changchun 130021, Peoples R China in 2021, Cited 39. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Background Despite tremendous progress has been achieved in tumor theranostic over the past decade, accurate identification and complete eradication of tumor cells remain a great challenge owing to the limitation of single imaging modality and therapeutic strategy. Results Herein, we successfully design and construct BiVO4/Fe3O4@polydopamine (PDA) superparticles (SPs) for computed tomography (CT)/photoacoustic (PA)/magnetic resonance (MR) multimodal imaging and radiotherapy (RT)/photothermal therapy (PTT) synergistic therapy toward oral epithelial carcinoma. On the one hand, BiVO4 NPs endow BiVO4/Fe3O4@PDA SPs with impressive X-ray absorption capability due to the high X-ray attenuation coefficient of Bi, which is beneficial for their utilization as radiosensitizers for CT imaging and RT. On the other hand, Fe3O4 NPs impart BiVO4/Fe3O4@PDA SPs with the superparamagnetic property as a T-2-weighted contrast agent for MR imaging. Importantly, the aggregation of Fe3O4 NPs in SPs and the presence of PDA shell greatly improve the photothermal conversion capability of SPs, making BiVO4/Fe3O4@PDA SPs as an ideal photothermal transducer for PA imaging and PTT. By integrating advantages of various imaging modalities (CT/PA/MR) and therapeutic strategies (RT/PTT), our BiVO4/Fe3O4@PDA SPs exhibit the sensitive multimodal imaging feature and superior synergistic therapeutic efficacy on tumors. Conclusions Since there are many kinds of building blocks with unique properties appropriating for self-assembly, our work may largely enrich the library of nanomateirals for tumor diagnosis and treatment.

Welcome to talk about 103-50-4, If you have any questions, you can contact Wang, Z; Wang, G; Kang, TT; Liu, SW; Wang, L; Zou, HY; Chong, Y; Liu, Y or send Email.. HPLC of Formula: C14H14O

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Zou, YL; Li, YR; Xu, JY; Huang, XY; Chen, DY in [Zou, Yunlong; Li, Yanran; Xu, Jiayin; Huang, Xiayun; Chen, Daoyong] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200438, Peoples R China published Heavily superparamagnetic magnetite-loaded polymeric worm-like micelles that have an ultrahighT(2)relaxivity in 2020, Cited 17. Application In Synthesis of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Composite worm-like micelles (CWMs) that encapsulate a large number of superparamagnetic magnetite nanoparticles (SMNPs) within the core while still having a small width should have a high magnetic resonance sensitivity and simultaneously a desirable circulation behaviour in biological systems. However, the preparation of such CWMs is still a challenge. Herein we report the fabrication of CWMsviatwo-stage self-assembly of SMNPs guided by a block copolymer and DNA, respectively. First, poly(ethylene glycol)-b-poly(4-vinylpyridine) co-assembled with SMNPs to form spherical composite micelles, guiding the clustering of multiple SMNPs within the core of the micelles. Then, at the second stage, DNA co-assembled with and guided the linear aggregation and fusion of the micelles, resulting in the CWM encapsulating a large number of SMNPs in the linear core. As a proof of concept, CWMs with aT(2)relaxivity as high as 704 mM(-1)s(-1)and a low MRI detection limit of 2.2 mu g mL(-1)(similar to 0.02 nM CWMs) were prepared; it is significant that theT(2)relaxivity of the SMNPs assembled in the CWMs is around 20 times that of the same SMNPs in the same amount but individually dispersed in the suspension. Additionally, although heavily loaded with SMNPs, the CWMs have a width as small as 20.5 nm and a core-shell structure with PEG as the shell. These features should make the CWMs very promising in their use as ultra-sensitive magnetic resonance imaging probes.

Welcome to talk about 103-50-4, If you have any questions, you can contact Zou, YL; Li, YR; Xu, JY; Huang, XY; Chen, DY or send Email.. Application In Synthesis of Benzyl ether

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Ether – Wikipedia,
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Application In Synthesis of Benzyl ether. In 2020 ENERG FUEL published article about ZSM-5 ZEOLITE; Y ZEOLITE; LIGNITE; HYDROGENATION; GUAIACOL; HYDRODEOXYGENATION; HYDROGENOLYSIS; ACCESSIBILITY; SITES; NI in [Kang, Yu-Hong; Wei, Xian-Yong; Liu, Guang-Hui; Ma, Xiang-Rong; Gao, Yong; Li, Xiao; Li, Yan Jun; Zong, Zhi-Min] China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China; [Kang, Yu-Hong; Wei, Xian-Yong; Ma, Xiang-Rong; Gao, Yong; Li, Xiao; Li, Yan Jun; Ma, Ya-Jun; Yan, Long] Yulin Univ, Shaanxi Key Lab Low Metamorph Coal Clean Utilizat, Sch Chem & Chem Engn, Yulin 71900, Shaanxi, Peoples R China in 2020, Cited 29. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A novel and highly active zeolite Y/ZSM-5 composite zeolite (CZ)-supported nickel catalyst (Ni/CZ with 10% of Ni loading) was prepared by modified deposition-precipitation to uniformly disperse Ni nanoparticles (NNPs) onto CZ. Hecaogou subbituminous coal was exhaustively extracted with isometric carbon disulfide/acetone mixed solvent to afford the extractable portion and inextractable portion (IEP). Ethanol-soluble portion (ESP) was obtained by ethanolyzing the IEP at 300 degrees C and subjected to catalytic hydroconversion (CHC) over Ni-10%/CZ at 160 degrees C to afford catalytically hydroconverted ESP (CHCESP). Both ESP and CHCESP were analyzed with a Fourier transform infrared spectrometer, gas chromatograph/mass spectrometer (GC/MS), and quadrupole exactive orbitrap mass spectrometer. The results show that the relative contents (RCs) of both chain alkanes and hydroarenes in CHCESP are significantly higher than those in ESP and cyclanes and alkenes were only detected in CHCESP, while the RCs of both arenes and oxygen-containing organic compounds in CHCESP are much lower than those in ESP and nitrogen- and/or sulfur-containing organic compounds were only detected in ESP with GC/MS. According to the CHC of oxybis(methylene)dibenzene (OBMDB), Ni-10%/CZ can effectively activate H-2 to biatomic active hydrogen (H center dot center dot center dot H) and the resulting H center dot center dot center dot H was heterolytically split into an immobile H- attached on Ni/CZ and a mobile H+. H+ transfers to an oxygen atom (OA) in OBMDB and cleaves the C-O bridged bond to produce phenylmethanol (PM) and benzylium, followed by H- abstraction from the Ni/CZ surface by benzylium to form toluene. H+ transfer to the OA in PM also leads to the cleavage of the C-O bond in PM to produce H2O and benzylium, which abstracts H- from the Ni/CZ surface to yield toluene. H center dot center dot center dot H transfer to the benzene ring in toluene generates methylcyclohexane. Therefore, Ni-10%/CZ catalyzes both H+ and H center dot center dot center dot H transfer. In addition, it proved to be stable for the CHC of OBMDB after 3 cycles.

Application In Synthesis of Benzyl ether. Welcome to talk about 103-50-4, If you have any questions, you can contact Kang, YH; Wei, XY; Liu, GH; Ma, XR; Gao, Y; Li, X; Li, YJ; Ma, YJ; Yan, L; Zong, ZM or send Email.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Heavily superparamagnetic magnetite-loaded polymeric worm-like micelles that have an ultrahighT(2)relaxivity WOS:000575294200003 published article about IRON-OXIDE NANOPARTICLES; MRI CONTRAST AGENTS in [Zou, Yunlong; Li, Yanran; Xu, Jiayin; Huang, Xiayun; Chen, Daoyong] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200438, Peoples R China in 2020, Cited 17. Product Details of 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Composite worm-like micelles (CWMs) that encapsulate a large number of superparamagnetic magnetite nanoparticles (SMNPs) within the core while still having a small width should have a high magnetic resonance sensitivity and simultaneously a desirable circulation behaviour in biological systems. However, the preparation of such CWMs is still a challenge. Herein we report the fabrication of CWMsviatwo-stage self-assembly of SMNPs guided by a block copolymer and DNA, respectively. First, poly(ethylene glycol)-b-poly(4-vinylpyridine) co-assembled with SMNPs to form spherical composite micelles, guiding the clustering of multiple SMNPs within the core of the micelles. Then, at the second stage, DNA co-assembled with and guided the linear aggregation and fusion of the micelles, resulting in the CWM encapsulating a large number of SMNPs in the linear core. As a proof of concept, CWMs with aT(2)relaxivity as high as 704 mM(-1)s(-1)and a low MRI detection limit of 2.2 mu g mL(-1)(similar to 0.02 nM CWMs) were prepared; it is significant that theT(2)relaxivity of the SMNPs assembled in the CWMs is around 20 times that of the same SMNPs in the same amount but individually dispersed in the suspension. Additionally, although heavily loaded with SMNPs, the CWMs have a width as small as 20.5 nm and a core-shell structure with PEG as the shell. These features should make the CWMs very promising in their use as ultra-sensitive magnetic resonance imaging probes.

Product Details of 103-50-4. Welcome to talk about 103-50-4, If you have any questions, you can contact Zou, YL; Li, YR; Xu, JY; Huang, XY; Chen, DY or send Email.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Low-Temperature Fast Production of Carbon and Acetic Acid Dual-Promoted Pd/C Catalysts WOS:000489580300001 published article about SELECTIVE OXIDATION; PALLADIUM NANOPARTICLES; FORMIC-ACID; HYDROGENATION; FABRICATION; REDUCTION; GRAPHENE; PERFORMANCE; ADSORPTION; BIOMASS in [Yao, Xiuchao; Ni, Lin; Yu, Chang; Zhang, Mengdi; Wei, Qianbing; Huang, Huawei; Guo, Wei; Huang, Hongling; Chang, Jiangwei; Qiu, Jieshan] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Liaoning Key Lab Energy Mat & Chem Engn, Dalian 116024, Liaoning, Peoples R China; [Qiu, Jieshan] Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China in 2019, Cited 42. Product Details of 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The Pd/C catalysts are widely used in synthesis of fine chemicals in industry, but their production suffers from a complicated two-step process involving impregnation and reduction, and requires large amounts of solvents and reductant, which would lead to a series of issues such as time consumption, resource waste and environmental pollution. Herein, ultra-small Pd nanoparticles uniformly anchored on carbon nanotubes (Pd/CNTs) were synthesized by using a one-pot and low-temperature reduction strategy. The present process/technology is very sensitive to and controlled by the supports and solvents, and the carbon support and acetic acid synergistically play crucial and decisive roles in the fast production of Pd/C catalysts. Also, the used solvents can be recycled and reutilized, which meets the requirements of sustainable chemistry and green economy. When the as-obtained Pd/CNTs catalyst was used to catalyze the oxidation of benzyl alcohol to benzaldehyde, it achieved a conversion efficiency as high as 99.3 % and a high selectivity up to >99.9 %. The simple, scalable and environmentally friendly strategy can be extended to anchor Pd nanoparticles on various carbon substrates, which sheds a new light on the synthesis of Pd/C catalysts.

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Ether – Wikipedia,
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Recently I am researching about LIGNOCELLULOSE FRACTIONATION; REDUCTIVE FRACTIONATION; PHENOLIC MONOMERS; WOODY BIOMASS; DEPOLYMERIZATION; EFFICIENT; CHEMICALS; CONVERSION; NICKEL; HYDROGENATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21736003, 21876111, 21690083, 21676108]; Guangzhou Science and Technology Program Key Projects, China [201804020014]; Fundamental Research Funds for the Central Universities, SCUTFundamental Research Funds for the Central Universities. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Zhao, WJ; Li, X; Li, HW; Zheng, XL; Ma, HW; Long, JX; Li, XH. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Formula: C14H14O

Bulk chemicals produced from renewable resources are receiving considerable attention due to the increase in sustainable practices. In this study, a novel, efficient, and sustainable strategy has been proposed to produce versatile petroleum based monophenols from the natural aromatic polymer, lignin, via the selective cleavage of its specific chemical linkages by a cost-effective catalyst, Ni/MgO. The results demonstrate that 93.4% of lignin is converted, yielding 15.0% monophenols in the presence of 20% Ni/MgO. Importantly, 42.3% of these volatile chemicals are found to be 4-ethyl phenol (the yield is 6.31%), a widely used fine chemical currently obtained from the petrochemical industry. Further comparative investigations on the raw and recovered lignin using heteronuclear single quantum correlation-nuclear magnetic resonance (HSQC-NMR), Fourier transform infrared (FT-IR), quantitative C-13 NMR, and the alkaline nitrobenzene oxidation method reveal that the selective breakage of the ester bond between the p-hydroxyphenyl structural unit and the other fragments followed by decarboxylation is responsible for the good performance of the 4-ethyl phenol formation process. Therefore, the results of this work would provide new insights for producing value-added petrochemicals from renewable lignin.

Welcome to talk about 103-50-4, If you have any questions, you can contact Zhao, WJ; Li, X; Li, HW; Zheng, XL; Ma, HW; Long, JX; Li, XH or send Email.. Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem