Category: 103-50-4

An article Starch Coated Silica Nanospheres Parenting the Growth of Trimodal Porous Zeolites for Catalysis Involving Large Molecules WOS:000470331800012 published article about NANOCRYSTALLINE MFI-ZEOLITES; HIERARCHICAL ZEOLITES; NANOSHEETS; MESOPORES; SELECTIVITY; ADSORPTION; GENERATION; PIPERIDINE; CRYSTALS; BETA in [Rani, Poonam; Srivastava, Rajendra] Indian Inst Technol Ropar, Dept Chem, Rupnagar 140001, Punjab, India in 2019, Cited 53. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. SDS of cas: 103-50-4

A simple method for the synthesis of nano crystalline ZSM-5 and Beta zeolites with trimodal porosity was developed using starch coated silica nanospheres (as silica precursor) for generating interparticle porosity (50-200 nm); propyltriethoxysilane was used as an additive for generating intercrystalline mesopores (2-50 nm) in the presence of microporous zeolite porogen. Loading of starch and propyltriethoxysilane additive played a pivotal role in obtaining trimodal porosity with very small size zeolite nanoparticles having high surface area and pore volume. The possible growth mechanism for the fabrication of trimodal porous zeolite is presented. The resultant zeolite demonstrated excellent acidity and activity in the liquid phase acid catalyzed reactions such as esterification of hexanoic/oleic acid with benzyl alcohol, condensation of benzaldehyde and 2-hydroxyacetophenone, and Friedel-Crafts alkylation followed by ring closure reaction for the synthesis of vitamin E when compared to conventional zeolite with excellent recyclability. Such an economical starch mediated synthesis strategy can be extended to other zeolite frameworks and similar heterogeneous catalytic materials.

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Recently I am researching about CONJUGATED MAGNETIC NANOPARTICLES; EFFICIENT; CATALYST, Saw an article supported by the Ahvaz Branch, Islamic Azad University. Published in MAIK NAUKA/INTERPERIODICA/SPRINGER in NEW YORK ,Authors: Sedighinia, E; Badri, R; Kiasat, AR. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Product Details of 103-50-4

The application of yttrium iron garnet (YIG) superparamagnetic nanoparticles as a new recyclable and highly efficient heterogeneous magnetic catalyst for one-pot synthesis of pyrano[2,3-c]pyrazole derivatives under solvent-free conditions, as well as etherification and esterification reactions are described. The advantages of the proposed method include the lack of organic solvents, clean reaction, rapid removal of the catalyst, short reaction times, excellent yields, and recyclability of the catalyst.

Product Details of 103-50-4. Welcome to talk about 103-50-4, If you have any questions, you can contact Sedighinia, E; Badri, R; Kiasat, AR or send Email.

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HPLC of Formula: C14H14O. In 2020 CHINESE J CATAL published article about HIGH-INDEX FACETS; OXYGEN REDUCTION; CONCAVE NANOCUBES; FUEL-CELLS; NANOPARTICLES; MECHANISM; ELECTROOXIDATION; NUCLEATION; GROWTH; CO in [Kim, Hee Jin; Ahn, Yong-Deok; Kim, Jeonghyeon; Choi, Sang-Il] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea; [Kim, Hee Jin; Ahn, Yong-Deok; Kim, Jeonghyeon; Choi, Sang-Il] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Daegu 41566, South Korea; [Kim, Kyoung-Su; Hong, Jong Wook] Univ Ulsan, Dept Chem, Ulsan 44610, South Korea; [Jeong, Yeon Uk] Kyungpook Natl Univ, Sch Mat Sci & Engn, Daegu 41566, South Korea in 2020, Cited 40. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Bimetallic Pt-based catalysts have been extensively investigated to enhance the performance of direct methanol fuel cells (DMFCs) because CO, a by-product, reduces the activity of the pure Pt catalysts. Herein, we synthesized Pt-Pb hexagonal nanoplates as a model catalyst for the methanol oxidation reaction (MOR) and further controlled the Pt and Pb distributions on the surface of the nanoplates through acetic acid (HAc) treatment. As a result, we obtained Pt-Pb nanoplates and HAc-treated Pt-Pb nanoplates with homogeneous and heterogeneous distributions of the Pt-Pb alloy surfaces, respectively. We showed that the MOR activity and stability of the Pt-Pb nanoplates improved compared to those of the HAc-treated Pt-Pb nanoplates, mainly due to the enhanced CO tolerance and the modified electronic structure of Pt under the influence of the oxophilic Pb. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

HPLC of Formula: C14H14O. Bye, fridends, I hope you can learn more about C14H14O, If you have any questions, you can browse other blog as well. See you lster.

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An article alpha-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride WOS:000489676400043 published article about O-ACYLATIVE CLEAVAGE; BOND; ACTIVATION; CHLORIDE; LIGANDS; REAGENT; HALIDES in [Parker, Bernard F.; Hosoya, Hiromu; Tsurugi, Hayato; Mashima, Kazushi] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan; [Parker, Bernard F.; Arnold, John] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA in 2019, Cited 34. Recommanded Product: 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

alpha-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the corresponding benzyl chlorides, where SiCl4 has the dual function of oxygen scavenger and chloride source with the formation of a silyl ether or silica as the only byproduct. The reaction mechanism has two successive trans-etherification steps that are mediated by the niobium catalyst, first forming one equivalent of benzyl chloride along with the corresponding silyl ether intermediate that undergoes the same reaction pathway to give the second equivalent of benzyl chloride and silyl ether.

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An article Adapting the concepts of nonaqueous sol-gel chemistry to metals: synthesis and formation mechanism of palladium and palladium-copper nanoparticles in benzyl alcohol WOS:000539907400001 published article about ACETIC-ACID; NANOCLUSTER NUCLEATION; OXIDE NANOPARTICLES; ETHYLENE-GLYCOL; GROWTH; SURFACE; ADSORPTION; CRYSTALLIZATION; HYDROGENATION; DECOMPOSITION in [Staniuk, Malwina; Rechberger, Felix; Tervoort, Elena; Niederberger, Markus] Swiss Fed Inst Technol, Dept Mat, Lab Multifunct Mat, Vladimir Prelog Weg 5, CH-8093 Zurich, Switzerland in 2020, Cited 58. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Category: ethers-buliding-blocks

Benzyl alcohol is a versatile reaction medium for the synthesis of different types of nanoparticles. Its ability to act as an oxygen source gave access to metal oxide nanoparticles, while its reducing properties can be harnessed for the preparation of metals. Here we report the synthesis of Pd and PdCu nanoparticles in benzyl alcohol supplemented by a detailed mechanistic study for both systems. To elucidate the chemical formation mechanism of the Pd nanoparticles, we performed in situ attenuated total reflection ultraviolet-visible (ATR-UV-vis) and Fourier transform infrared spectroscopy (ATR-FTIR), providing information on the organic as well as on the inorganic side of the reaction. Potential gaseous products were analyzed by in situ gas chromatography (GC) and mass spectrometry (MS). We observed the formation of benzaldehyde, toluene, and dibenzyl ether as the three main organic products. The formation of the PdCu alloy nanoparticles was studied by ex situ powder X-ray diffraction (PXRD). A time-resolved study of the synthesis at 100 degrees C indicated that initially three types of particles formed, composed of an alloy with high Pd content, an alloy with high content of copper, and palladium particles, and only later in the reaction course they transformed into an alloy with a Pd-to-Cu ratio close to 1. [GRAPHICS] .

Welcome to talk about 103-50-4, If you have any questions, you can contact Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M or send Email.. Category: ethers-buliding-blocks

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Tang, F; Liu, T; Jiang, WL; Gan, L in [Tang, Fei; Liu, Tian; Jiang, Wulv; Gan, Lin] Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China published Windowless thin layer electrochemical Raman spectroscopy of Ni-Fe oxide electrocatalysts during oxygen evolution reaction in 2020, Cited 29. COA of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

In-situ Raman spectroelectrochemistry is a powerful tool to understand the structures and reaction mechanisms of electrochemical interfaces yet usually suffers from a low sensitivity and detection efficiency. Herein, we develop a windowless thin layer electrochemical cell design to improve the detection efficiency of in-situ Raman spectroscopy for practical nanoscale electrocatalysts. This was achieved by perforating a hole in the optical window of the cell, which not only eliminates the refraction of light by the window but also induces a meniscus thin electrolyte layer on the working electrode, thus significantly improving the detection efficiency of Raman spectra. We successfully applied thismethod to conduct in-situ Raman spectroscopy of structural evolutions of two representative Ni-Fe oxide catalysts (layered double hydroxides and spinel oxides) during oxygen evolution reaction (OER) electrocatalysis. It was shown that both catalysts underwent surface transformation to oxyhydroxides and formed active oxygen species at OER relevant potentials. However, the extent of the surface transformation was much lower on the Ni-Fe spinel catalyst, accounting for its lower OER activity. We further show that adding a carbon support can promote the surface transformation of Ni-Fe spinel to oxyhydroxides, thus significantly increasing the electrocatalytic activities. The established windowless thin layer method provides a new way to conduct in-situ electrochemical Raman spectroscopy of a wide range of materials and may be also combined with surface-enhanced Raman spectroscopic methods.

Welcome to talk about 103-50-4, If you have any questions, you can contact Tang, F; Liu, T; Jiang, WL; Gan, L or send Email.. COA of Formula: C14H14O

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An article A Catalyst System Based on Copper(II) Bromide Supported on Zeolite HY with a Hierarchical Pore Structure in Benzyl Butyl Ether Synthesis WOS:000563657300010 published article about ALCOHOLS; PHASE in [Bayguzina, A. R.; Gallyamova, L., I; Agliullin, M. R.; Khusnutdinov, R., I] Russian Acad Sci, Inst Petr Chem & Catalysis, Ufa 450075, Republic Of Bas, Russia in 2020, Cited 22. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Safety of Benzyl ether

Novel catalyst systems based on CuBr2 supported on zeolite HY with a hierarchical pore structure have been proposed for benzyl butyl ether synthesis by the intermolecular dehydration of benzyl and butyl alcohols. It has been shown that catalyst systems with a CuBr(2)content of similar to 10 wt % provide a benzyl butyl ether yield of similar to 95% at 150 degrees C.

Welcome to talk about 103-50-4, If you have any questions, you can contact Bayguzina, AR; Gallyamova, LI; Agliullin, MR; Khusnutdinov, RI or send Email.. Safety of Benzyl ether

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Application In Synthesis of Benzyl ether. Authors Wang, Z; Wang, G; Kang, TT; Liu, SW; Wang, L; Zou, HY; Chong, Y; Liu, Y in BMC published article about in [Wang, Ze; Kang, Tingting; Liu, Shuwei; Liu, Yi] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China; [Zou, Haoyang] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130012, Peoples R China; [Chong, Yu] Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China; [Wang, Guan] Jilin Univ, China Japan Union Hosp, Dept Gastroenterol, Changchun 130033, Peoples R China; [Wang, Lu] Jilin Univ, Sch & Hosp Stomatol, Dept Oral Pathol, Changchun 130021, Peoples R China in 2021, Cited 39. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Background Despite tremendous progress has been achieved in tumor theranostic over the past decade, accurate identification and complete eradication of tumor cells remain a great challenge owing to the limitation of single imaging modality and therapeutic strategy. Results Herein, we successfully design and construct BiVO4/Fe3O4@polydopamine (PDA) superparticles (SPs) for computed tomography (CT)/photoacoustic (PA)/magnetic resonance (MR) multimodal imaging and radiotherapy (RT)/photothermal therapy (PTT) synergistic therapy toward oral epithelial carcinoma. On the one hand, BiVO4 NPs endow BiVO4/Fe3O4@PDA SPs with impressive X-ray absorption capability due to the high X-ray attenuation coefficient of Bi, which is beneficial for their utilization as radiosensitizers for CT imaging and RT. On the other hand, Fe3O4 NPs impart BiVO4/Fe3O4@PDA SPs with the superparamagnetic property as a T-2-weighted contrast agent for MR imaging. Importantly, the aggregation of Fe3O4 NPs in SPs and the presence of PDA shell greatly improve the photothermal conversion capability of SPs, making BiVO4/Fe3O4@PDA SPs as an ideal photothermal transducer for PA imaging and PTT. By integrating advantages of various imaging modalities (CT/PA/MR) and therapeutic strategies (RT/PTT), our BiVO4/Fe3O4@PDA SPs exhibit the sensitive multimodal imaging feature and superior synergistic therapeutic efficacy on tumors. Conclusions Since there are many kinds of building blocks with unique properties appropriating for self-assembly, our work may largely enrich the library of nanomateirals for tumor diagnosis and treatment.

About Benzyl ether, If you have any questions, you can contact Wang, Z; Wang, G; Kang, TT; Liu, SW; Wang, L; Zou, HY; Chong, Y; Liu, Y or concate me.. Application In Synthesis of Benzyl ether

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Category: ethers-buliding-blocks. Liu, BY; Liao, ZT; Xiao, X; Gan, SZ; Luo, RC; Wu, Y; Chen, HY; Fang, YX; Dong, JX in [Liu, Baoyu; Liao, Zhantu; Xiao, Xin; Gan, Shengzhi; Luo, Rongchang; Fang, Yanxiong; Dong, Jinxiang] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou Key Lab Clean Transportat Energy Chem, Guangzhou 510006, Guangdong, Peoples R China; [Chen, Huiyong] Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China; [Chen, Huiyong] Northwest Univ, Chem Engn Res Ctr, Minist Educ Adv Use Technol Shanbei Energy, Shaanxi Res Ctr Engn Technol Clean Coal Convers, Xian 710069, Shaanxi, Peoples R China; [Wu, Ying] South China Univ Technol, Sch Chem & Chem Technol, Guangzhou 510640, Guangdong, Peoples R China; [Dong, Jinxiang] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China published Fine-Tuned Hierarchical Architecture of MWW Zeolites for Highly Efficient Alkylation via Suitable Accommodation in 2020, Cited 40. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

The hierarchical structure of zeolites plays a crucial role in determining their catalytic performance. Here, the effect of the hierarchical architecture and surface topology of pillared MWW zeolites on the catalytic properties of liquid alkylation between mesitylene and benzyl alcohol was investigated. Pillared MWW zeolite catalysts exhibited excellent activity (similar to 100% conversion) due to their elegant pore architecture, which could largely improve the accessibility of bulk molecules toward active sites on the external surface. In addition, molecular simulation showed that lamellar MWW zeolites with a 12-membered ring semicup surface topology could more effectively accommodate and stabilize the large intermediates formed in alkylation reactions compared with MFI zeolites, resulting in outstanding selectivity for 2-benzyl-1,3,5-trimethylbenzene (similar to 100%). The Thiele modulus (phi) and effectiveness factor (eta) verified that the resultant pillared MWW zeolites possessed a high degree of utilization without internal diffusion constraints under the present reaction conditions.

Category: ethers-buliding-blocks. About Benzyl ether, If you have any questions, you can contact Liu, BY; Liao, ZT; Xiao, X; Gan, SZ; Luo, RC; Wu, Y; Chen, HY; Fang, YX; Dong, JX or concate me.

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Authors Poole, CF in ELSEVIER published article about POLYCYCLIC AROMATIC-HYDROCARBONS; OPEN-TUBULAR COLUMNS; ENERGY RELATIONSHIPS; SEPARATION CHARACTERISTICS; STATIONARY PHASES; ADSORPTION MECHANISM; NONTARGET ANALYSIS; SOLVENT SYSTEMS; SELECTIVITY; DESCRIPTORS in [Poole, Colin F.] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA in 2020, Cited 68. SDS of cas: 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The Wayne State University (WSU) experimental descriptor database is utilized to bench mark the current capability of the solvation parameter model for use as a quantitative structure-retention relationship tool for estimating retention in gas and reversed-phase liquid chromatography. The prediction error for the retention factors of varied compounds on six open-tubular columns for gas chromatography (Rtx-5 SIL MS, DB-35 ms, RtxCLPesticides, HP-88, HP-INNOWAX and SLB-IL76) and three packed columns for reversed phase liquid chromatography (SunFire C-18 , XBridge Shield RP18, and XBridge Phenyl) is used to establish expectations related to current practices. Each column data set was divided into a training set for calibration and a test set for validation employing a roughly 1 to 2 split, such that each test set contained about 40 to 80 varied compounds. The average absolute error for the prediction of retention factors by gas chromatography varied from about 0.1 to 0.4 on the retention factor scale with the larger error typical of stationary phases ranked as the most polar (or cohesive). For reversed-phase liquid chromatography the average error for the prediction of retention factors was 0.3 to 0.5 and generally larger than for gas chromatography. Statistical filters where utilized to identify a group of polycyclic aromatic compounds without hydrogen-bonding functional groups with a larger prediction error on the SunFire C-18 column than for other compounds of smaller size, flexible structure or containing hydrogen-bonding functional groups. The heterogeneity of the retention mechanism is speculated to be the main contribution to the prediction error for both gas and liquid chromatography using the solvation parameter model. (C) 2020 Elsevier B.V. All rights reserved.

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