Category: 103-50-4

An article Photocatalytic primary alcohol oxidation on WO3 nanoplatelets WOS:000486208200042 published article about PHOTOREDOX CATALYSIS; SELECTIVE OXIDATION; OXYGEN-EVOLUTION; BENZYL ALCOHOL; OXIDES; WATER; NANOCOMPOSITES; NANOCRYSTALS; BINARY; RUTILE in [McDonald, Kori D.; Bartlett, Bart M.] Univ Michigan, Dept Chem, 930 North Univ Ave, Ann Arbor, MI 48109 USA in 2019, Cited 35. Product Details of 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

With the aid of direct heating through microwave irradiation in non-aqueous media, nanocrystalline tungsten(vi) oxide is achievable in 30 minutes at 200 degrees C, faster and at a lower temperature than conventional synthesis methods. Forming in a platelet morphology, these particles are as small as 20 nm with a BET surface area of 37 m(2) g(-1) WO3. These nanoplatelets are active for the photocatalytic oxidation of the 1 degrees alcohols benzyl alcohol (rate constant, k of 2.6 x 10(-3) h(-1)) and 5-(hydroxymethyl)-2-furfural (k of 0.01 h(-1)) using 10 mg of WO3 with 2 mL of 0.250 M substrate in acetonitrile and a 150 mW cm(-2) 460 nm blue LED source. As expected, these rate constants are larger than those observed for commercially prepared, micron-sized WO3. XPS analysis shows that during catalysis, the concentration of W5+ on the surface increases, but the nanoplatelets are stable under these reaction conditions. The overall morphology and size of the particles are retained through the reactions. Moreover, the nanoplatelets are recyclable-showing no loss in activity for four reaction cycles.

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An article An advanced optical clearing protocol allows label-free detection of tissue necrosis via multiphoton microscopy in injured whole muscle WOS:000604981700024 published article about 2ND-HARMONIC GENERATION; SHG MICROSCOPY; SKELETAL-MUSCLE; HIGH-RESOLUTION; MICROARCHITECTURE; REGENERATION; MORPHOMETRY; EXCITATION in [Schneidereit, Dominik; Broellochs, Anita; Ritter, Paul; Kreiss, Lucas; Schuermann, Sebastian; Friedrich, Oliver] Friedrich Alexander Univ Erlangen Nurnberg, Inst Med Biotechnol, Paul Gordan Str 3, D-91052 Erlangen, Germany; [Schneidereit, Dominik; Ritter, Paul; Kreiss, Lucas; Schuermann, Sebastian; Friedrich, Oliver] Friedrich Alexander Univ Erlangen Nurnberg, Grad Sch Adv Opt Technol SAOT, Paul Gordan Str 7, D-91052 Erlangen, Germany; [Mokhtari, Zeinab; Beilhack, Andreas] Wurzburg Univ, Med Sch, Interdisciplinary Ctr Clin Res, Lab Expt Stem Cell Transplantat,Dept Med 2, Zinklesweg 10, D-97078 Wurzburg, Germany; [Kroenke, Gerhard; Ackermann, Jochen A.; Faas, Maria; Grueneboom, Anika] Friedrich Alexander Univ Erlangen Nurnberg, Clin Internal Med 3, Ulmenweg 18, D-91054 Erlangen, Germany; [Kroenke, Gerhard; Ackermann, Jochen A.; Faas, Maria; Grueneboom, Anika] Friedrich Alexander Univ Erlangen Nurnberg, Clin Rheumatol & Immunol, Ulmenweg 18, D-91054 Erlangen, Germany; [Schuermann, Sebastian; Friedrich, Oliver] Muscle Res Ctr Erlangen MURCE, Henkestr 91, D-91052 Erlangen, Germany; [Friedrich, Oliver] Univ New South UNSW, Sch Med Sci SOMS, Kensington Campus,High St, Sydney, NSW 2052, Australia in 2021, Cited 60. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Product Details of 103-50-4

Rationale: Structural remodeling or damage as a result of disease or injury is often not evenly distributed throughout a tissue but strongly depends on localization and extent of damaging stimuli. Skeletal muscle as a mechanically active organ can express signs of local or even systemic myopathic damage, necrosis, or repair. Conventionally, muscle biopsies (patients) or whole muscles (animal models) are mechanically sliced and stained to assess structural alterations histologically. Three-dimensional tissue information can be obtained by applying deep imaging modalities, e.g. multiphoton or light-sheet microscopy. Chemical clearing approaches reduce scattering, e.g. through matching refractive tissue indices, to overcome optical penetration depth limits in thick tissues. Methods: Here, we optimized a range of different clearing protocols. We find aqueous solution-based protocols employing (20-80%) 2,2′-thiodiethanol (TDE) to be advantageous over organic solvents (dibenzyl ether, cinnamate) regarding the preservation of muscle morphology, ease-of-use, hazard level, and costs. Results: Applying TDE clearing to a mouse model of local cardiotoxin (CTX)-induced muscle necrosis, a complete loss of myosin-II signals was observed in necrotic areas with little change in fibrous collagen or autofluorescence (AF) signals. The 3D aspect of myofiber integrity could be assessed, and muscle necrosis in whole muscle was quantified locally via the ratios of detected AF, forward- and backward-scattered Second Harmonic Generation (fSHG, bSHG) signals. Conclusion: TDE optical clearing is a versatile tool to study muscle architecture in conjunction with label-free multiphoton imaging in 3D in injury/myopathy models and might also be useful in studying larger biofabricated constructs in regenerative medicine.

Welcome to talk about 103-50-4, If you have any questions, you can contact Schneidereit, D; Brollochs, A; Ritter, P; Kreiss, L; Mokhtari, Z; Beilhack, A; Kronke, G; Ackermann, JA; Faas, M; Gruneboom, A; Schurmann, S; Friedrich, O or send Email.. Product Details of 103-50-4

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Recently I am researching about PHENOLIC-COMPOUNDS; METAL-CATALYSTS; ENZYMATIC-HYDROLYSIS; CARBON; GUAIACOL; BIOMASS; CONVERSION; FUELS; HYDROCONVERSION; HYDROGENOLYSIS, Saw an article supported by the Future Scientists Program of China University of Mining and Technology [2020WLKXJ019]; Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX20_2006]. Published in ELSEVIER SCI LTD in OXFORD ,Authors: Hu, L; Wei, XY; Kang, YH; Guo, XH; Xu, ML; Zong, ZM. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Product Details of 103-50-4

Recently high yield of cycloalkanes originates from selective hydrodeoxygenation (HDO) of lignin-derived bio-oil under mild conditions, which still encounters the great challenges. Herein, mordenite-supported ruthenium bifunctional catalyst (Ru3%/M) was prepared by using the deposition-precipitation (DP) method for the HDO reaction of the petroleum ether-extractable portions (PEEP) from alkali catalytic ethanolysis of lignin (CEOL). Ru3%/M catalyst was characterized systematically by XRD, XPS, FTIRS, NH3-TPD, N-2-adsorption, SEM, and TEM, indicating that it had the moderate acid sites and uniform Ru nanoparticles dispersion. The synthesized catalyst was further tested for the HDO per-formance of diphenyl ether, oxybis(methylene)dibenzene, and anisole, respectively. Results showed that three lignin model compounds can be converted to high yield of cycloalkanes under 160 degrees C and 3 MPa H-2 in n-hexane. This catalyst showed the high catalytic activity for diphenyl ether HDO reaction, the con -version decreased slightly to 87.6% after five recycle times. Furthermore, catalyst feed mass was the key factor for HDO reaction of raw PEEP from CEOL, promoting the HDO reaction process to produce high yield of cycloalkanes. Interestingly, the mass ratio between catalyst feed and raw PEEP was 1, thus 74.36% relative content (RC) of cycloalkanes can be obtained. The upgraded PEEP from CEOL has potential to be used as clean liquid fuels. (C) 2021 Energy Institute. Published by Elsevier Ltd. All rights reserved.

Welcome to talk about 103-50-4, If you have any questions, you can contact Hu, L; Wei, XY; Kang, YH; Guo, XH; Xu, ML; Zong, ZM or send Email.. Product Details of 103-50-4

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In 2020 J ELECTROANAL CHEM published article about CATALYSTS; IDENTIFICATION; OXIDATION in [Tang, Fei; Liu, Tian; Jiang, Wulv; Gan, Lin] Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China in 2020, Cited 29. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. COA of Formula: C14H14O

In-situ Raman spectroelectrochemistry is a powerful tool to understand the structures and reaction mechanisms of electrochemical interfaces yet usually suffers from a low sensitivity and detection efficiency. Herein, we develop a windowless thin layer electrochemical cell design to improve the detection efficiency of in-situ Raman spectroscopy for practical nanoscale electrocatalysts. This was achieved by perforating a hole in the optical window of the cell, which not only eliminates the refraction of light by the window but also induces a meniscus thin electrolyte layer on the working electrode, thus significantly improving the detection efficiency of Raman spectra. We successfully applied thismethod to conduct in-situ Raman spectroscopy of structural evolutions of two representative Ni-Fe oxide catalysts (layered double hydroxides and spinel oxides) during oxygen evolution reaction (OER) electrocatalysis. It was shown that both catalysts underwent surface transformation to oxyhydroxides and formed active oxygen species at OER relevant potentials. However, the extent of the surface transformation was much lower on the Ni-Fe spinel catalyst, accounting for its lower OER activity. We further show that adding a carbon support can promote the surface transformation of Ni-Fe spinel to oxyhydroxides, thus significantly increasing the electrocatalytic activities. The established windowless thin layer method provides a new way to conduct in-situ electrochemical Raman spectroscopy of a wide range of materials and may be also combined with surface-enhanced Raman spectroscopic methods.

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Authors Wang, Z; Wang, G; Kang, TT; Liu, SW; Wang, L; Zou, HY; Chong, Y; Liu, Y in BMC published article about in [Wang, Ze; Kang, Tingting; Liu, Shuwei; Liu, Yi] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China; [Zou, Haoyang] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130012, Peoples R China; [Chong, Yu] Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, State Key Lab Radiat Med & Protect, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China; [Wang, Guan] Jilin Univ, China Japan Union Hosp, Dept Gastroenterol, Changchun 130033, Peoples R China; [Wang, Lu] Jilin Univ, Sch & Hosp Stomatol, Dept Oral Pathol, Changchun 130021, Peoples R China in 2021, Cited 39. HPLC of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Background Despite tremendous progress has been achieved in tumor theranostic over the past decade, accurate identification and complete eradication of tumor cells remain a great challenge owing to the limitation of single imaging modality and therapeutic strategy. Results Herein, we successfully design and construct BiVO4/Fe3O4@polydopamine (PDA) superparticles (SPs) for computed tomography (CT)/photoacoustic (PA)/magnetic resonance (MR) multimodal imaging and radiotherapy (RT)/photothermal therapy (PTT) synergistic therapy toward oral epithelial carcinoma. On the one hand, BiVO4 NPs endow BiVO4/Fe3O4@PDA SPs with impressive X-ray absorption capability due to the high X-ray attenuation coefficient of Bi, which is beneficial for their utilization as radiosensitizers for CT imaging and RT. On the other hand, Fe3O4 NPs impart BiVO4/Fe3O4@PDA SPs with the superparamagnetic property as a T-2-weighted contrast agent for MR imaging. Importantly, the aggregation of Fe3O4 NPs in SPs and the presence of PDA shell greatly improve the photothermal conversion capability of SPs, making BiVO4/Fe3O4@PDA SPs as an ideal photothermal transducer for PA imaging and PTT. By integrating advantages of various imaging modalities (CT/PA/MR) and therapeutic strategies (RT/PTT), our BiVO4/Fe3O4@PDA SPs exhibit the sensitive multimodal imaging feature and superior synergistic therapeutic efficacy on tumors. Conclusions Since there are many kinds of building blocks with unique properties appropriating for self-assembly, our work may largely enrich the library of nanomateirals for tumor diagnosis and treatment.

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Name: Benzyl ether. I found the field of Biotechnology & Applied Microbiology very interesting. Saw the article Isolation and characterization of 2-butoxyethanol degrading bacterial strains published in 2020, Reprint Addresses Woiski, C (corresponding author), Univ Stuttgart, Inst Sanit Engn Water Qual & Solid Waste Manageme, Dept Biol Waste Air Purificat, Bandtaele 2, D-70569 Stuttgart, Germany.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

A total of 11 bacterial strains capable of completely degrading 2-butoxyethanol (2-BE) were isolated from forest soil, a biotrickling filter, a bioscrubber, and activated sludge, and identified by 16S rRNA gene sequence analysis. Eight of these strains belong to the genus Pseudomonas; the remaining three strains are Hydrogenophaga pseudoflava BOE3, Gordonia terrae BOE5, and Cupriavidus oxalaticus BOE300. In addition to 2-BE, all isolated strains were able to grow on 2-ethoxyethanol and 2-propoxyethanol, ethanol, n-hexanol, ethyl acetate, 2-butoxyacetic acid (2-BAA), glyoxylic acid, and n-butanol. Apart from the only gram-positive strain isolated, BOE5, none of the strains were able to grow on the nonpolar ethers diethyl ether, di-n-butyl ether, n-butyl vinyl ether, and dibenzyl ether, as well as on 1-butoxy-2-propanol. Strains H. pseudoflava BOE3 and two of the isolated pseudomonads, Pseudomonas putida BOE100 and P. vancouverensis BOE200, were studied in more detail. The maximum growth rates of strains BOE3, BOE100, and BOE200 at 30 degrees C were 0.204 h(-1) at 4 mM, 0.645 h(-1) at 5 mM, and 0.395 h(-1) at 6 mM 2-BE, respectively. 2-BAA, n-butanol, and butanoic acid were detected as potential metabolites during the degradation of 2-BE. These findings indicate that the degradation of 2-BE by the isolated gram-negative strains proceeds via oxidation to 2-BAA with subsequent cleavage of the ether bond yielding glyoxylate and n-butanol. Since Gordonia terrae BOE5 was the only strain able to degrade nonpolar ethers like diethyl ether, the degradation pathway of 2-BE may be different for this strain.

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Recommanded Product: 103-50-4. Hernndez-Guerra, D; Hlavackov, A; Pramthaisong, C; Vespoli, I; Pohl, R; Slanina, T; Jahn, U in [Hernandez-Guerra, Daniel; Hlavackova, Anna; Pramthaisong, Chiranan; Vespoli, Ilaria; Pohl, Radek; Slanina, Tomas; Jahn, Ullrich] Czech Acad Sci, Inst Organ Chem & Biochem, Flemingovo Namesti 2, Prague 16610 6, Czech Republic published Photochemical C-H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot in 2019, Cited 54. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A mild, atom-economic, and metal-free alpha-C-H amination of ethers using relatively stable nonafluorobutanesulfonyl (nonaflyl, Nf) azide as the aminating reagent to give N-sulfonyl hemiaminals is reported. This enables unprecedented C(sp(3)) difunctionalization reactions, leading to diverse functionalized amino group containing compounds starting from simple ethers in one pot.

Recommanded Product: 103-50-4. Welcome to talk about 103-50-4, If you have any questions, you can contact Hernndez-Guerra, D; Hlavackov, A; Pramthaisong, C; Vespoli, I; Pohl, R; Slanina, T; Jahn, U or send Email.

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Recently I am researching about ORGANIC-COMPOUNDS; FRAGRANCE ALLERGENS; CONSUMER PRODUCTS; DUST, Saw an article supported by the Xunta de GaliciaXunta de GaliciaEuropean Commission; Spanish GovernmentSpanish GovernmentEuropean Commission [GRC-ED431C 2017/36, PGC2018-094613-B-I00]; EUEuropean Commission. Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Cobo-Golpe, M; Ramil, M; Cela, R; Rodriguez, I. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Recommanded Product: 103-50-4

The comprehensive identification of organic species existing in indoor environments is a key issue to understand their impact in human health. This study proposes the analysis of condensed water samples, collected with portable dehumidifiers, to characterize semi-volatile compounds in the gas phase of confined areas. Water samples are concentrated by solid-phase extraction (SPE). The obtained extracts are analysed by gas chromatography (GC) time-of-flight mass spectrometry (TOF-MS), following a nontarget screening data mining approach. In first term, spectra of deconvoluted compounds are compared with those in NIST low resolution library; thereafter, tentative identifications are verified using an inhouse database of accurate electron ionization (EI) MS spectra. Chromatographic (retention index) and spectral data are combined for unambiguous species identification. The potential of condensed water samples to reflect changes in the composition of indoor atmospheres, the match between data obtained using different dehumidifiers, and the relative concentration efficiency of condensed water compared to that attained by active sampling of moderate air volumes are discussed. A total of 141 semi-volatile compounds were identified (98 confirmed against authentic standards) in a set of 21 samples obtained from different homes and working places. This list contains more than 40 fragrances (including several potential allergens), solvents and intermediates in the production of polymeric materials, plasticizers and flame retardants. (C) 2020 Elsevier Ltd. All rights reserved.

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Recommanded Product: Benzyl ether. In 2019 ACS SUSTAIN CHEM ENG published article about NANOCRYSTALLINE MFI-ZEOLITES; HIERARCHICAL ZEOLITES; NANOSHEETS; MESOPORES; SELECTIVITY; ADSORPTION; GENERATION; PIPERIDINE; CRYSTALS; BETA in [Rani, Poonam; Srivastava, Rajendra] Indian Inst Technol Ropar, Dept Chem, Rupnagar 140001, Punjab, India in 2019, Cited 53. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A simple method for the synthesis of nano crystalline ZSM-5 and Beta zeolites with trimodal porosity was developed using starch coated silica nanospheres (as silica precursor) for generating interparticle porosity (50-200 nm); propyltriethoxysilane was used as an additive for generating intercrystalline mesopores (2-50 nm) in the presence of microporous zeolite porogen. Loading of starch and propyltriethoxysilane additive played a pivotal role in obtaining trimodal porosity with very small size zeolite nanoparticles having high surface area and pore volume. The possible growth mechanism for the fabrication of trimodal porous zeolite is presented. The resultant zeolite demonstrated excellent acidity and activity in the liquid phase acid catalyzed reactions such as esterification of hexanoic/oleic acid with benzyl alcohol, condensation of benzaldehyde and 2-hydroxyacetophenone, and Friedel-Crafts alkylation followed by ring closure reaction for the synthesis of vitamin E when compared to conventional zeolite with excellent recyclability. Such an economical starch mediated synthesis strategy can be extended to other zeolite frameworks and similar heterogeneous catalytic materials.

Welcome to talk about 103-50-4, If you have any questions, you can contact Rani, P; Srivastava, R or send Email.. Recommanded Product: Benzyl ether

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Recommanded Product: Benzyl ether. Authors Nagendra, B; Mondrone, G; Daniel, C; Rizzo, P; Guerra, G in AMER CHEMICAL SOC published article about in [Nagendra, Baku; Mondrone, Giovanni; Daniel, Christophe; Rizzo, Paola; Guerra, Gaetano] Univ Salerno, Dipartimento Chim & Biol, I-84084 Fisciano, SA, Italy; [Nagendra, Baku; Mondrone, Giovanni; Daniel, Christophe; Rizzo, Paola; Guerra, Gaetano] Univ Salerno, INSTM Res Unit, I-84084 Fisciano, SA, Italy in 2021, Cited 61. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Thermal release of guest molecules from poly(2,6-dimethyl-1,4-phenylene)oxide (PPO) films, exhibiting host-guest cocrystalline (CC) phases with orientation of their chain axes being preferentially parallel or perpendicular to the film plane (c(parallel to) and c(perpendicular to) orientations), is studied. TGA analyses show that, for all the considered CC PPO films, temperatures of guest release for CC films with c(parallel to) orientation are definitely higher than those for CC films with c(perpendicular to) orientation, with differences even higher than 100 degrees C. Correspondingly, DSC scans of CC films with c(perpendicular to) orientation show separated endothermic peaks of guest release and melting, while CC films with c(parallel to) orientation only exhibit one broad endothermic peak with superimposed guest release, glass transition (T-g), and melting (T-m) phenomena. This control of temperatures of guest release could be helpful to maximize the thermal stability of host-guest PPO co-crystalline phases and to tailor temperatures of active guest release.

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem