Category: 150-19-6

Sparkes, Emily I.; Egedeuzu, Chisom S.; Lias, Billie; Sung, Rehana; Caslin, Stephanie A.; Tabatabaei Dakhili, S. Yasin; Taylor, Peter G.; Quayle, Peter; Wong, Lu Shin published an article in 2021. The article was titled 《Biocatalytic Silylation: The Condensation of Phenols and Alcohols with Triethylsilanol》, and you may find the article in Catalysts.Recommanded Product: m-Methoxyphenol The information in the text is summarized as follows:

Silicatein-α (Silα), a hydrolytic enzyme derived from siliceous marine sponges, is one of the few enzymes in nature capable of catalyzing the metathesis of silicon-oxygen bonds. It is therefore of interest as a possible biocatalyst for the synthesis of organosiloxanes. To further investigate the substrate scope of this enzyme, a series of condensation reactions with a variety of phenols and aliphatic alcs. were carried out. In general, it was observed that Silα demonstrated a preference for phenols, though the conversions were relatively modest in most cases. In the two pairs of chiral alcs. that were investigated, it was found that the enzyme displayed a preference for the silylation of the S-enantiomers. Addnl., the enzyme′s tolerance to a range of solvents was tested. Silα had the highest level of substrate conversion in the nonpolar solvents n-octane and toluene, although the inclusion of up to 20% of 1,4-dioxane was tolerated. These results suggest that Silα is a potential candidate for directed evolution toward future application as a robust and selective biocatalyst for organosiloxane chem. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Recommanded Product: m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Recommanded Product: m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Reference of m-MethoxyphenolIn 2019 ,《Construction of Spirocyclic Tetrahydro-β-carbolines via Cross-Annulation of Phenols with Tryptamines in Water》 was published in Organic Letters. The article was written by Wang, Zemin; Niu, Jiabin; Zeng, Huiying; Li, Chao-Jun. The article contains the following contents:

Phenols are readily available by degradation of lignin resource. Palladium-catalyzed conversion of phenols to tetrahydro-β-carboline skeletons bearing a spirocycle at the C-1 position in water is reported. Various substituted phenols are successfully cross-annulated with different tryptamines via sequential C(Ar)-O bond cleavage of phenols, C-H bond activation of tryptamines, and C-N/C-C bond formations. This method provides a new protocol of converting lignin phenols into high-value-added compounds, such as natural product Komavine. In the experimental materials used by the author, we found m-Methoxyphenol(cas: 150-19-6Reference of m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Reference of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Chu, Wen-Dao; Liang, Tian-Tian; Ni, Hao; Dong, Zhi-Hong; Shao, Zhihui; Liu, Yong; He, Cheng-Yu; Bai, Ruopeng; Liu, Quan-Zhong published an article in Organic Letters. The title of the article was 《Palladium-Catalyzed Intermolecular Asymmetric Dearomative Annulation of Phenols with Vinyl Cyclopropanes》.Synthetic Route of C7H8O2 The author mentioned the following in the article:

Herein, the Pd(0)-catalyzed intermol. asym. dearomative [3+2] annulation of phenols with vinyl cyclopropanes via in situ generated ortho-quinone methide intermediates was reported. A series of highly functionalized spiro-[5,6]bicycles, e.g., I which bear three contiguous stereogenic centers including one all-carbon quaternary were obtained with excellent stereoselectivities. D. functional theory (DFT) calculations indicated that the reactions were controlled by thermodn. In the part of experimental materials, we found many familiar compounds, such as m-Methoxyphenol(cas: 150-19-6Synthetic Route of C7H8O2)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneSynthetic Route of C7H8O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

HPLC of Formula: 150-19-6In 2020 ,《Silver-Catalyzed para-Selective Amination and Aminative Dearomatization of Phenols with Azodicarboxylates in Water》 was published in Organic Letters. The article was written by Zhao, Ruinan; Zhou, Zhong; Liu, Jixiang; Wang, Xia; Zhang, Qian; Li, Dong. The article contains the following contents:

An efficient silver-catalyzed para-selective amination and aminative dearomatization of phenols with azodicarboxylates was developed. It afforded the para-aminophenols or amino cyclohexadieneones from free phenols depending on whether it has a para-substituent. The reaction proceeded smoothly in water under simple and mild conditions, giving the highly selective products in good yields within a short reaction time. It also showed broad substrate scope and good functional group compatibility. In the experimental materials used by the author, we found m-Methoxyphenol(cas: 150-19-6HPLC of Formula: 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.HPLC of Formula: 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Photoinduced Hydroxylation of Organic Halides under Mild Conditions》 were Cai, Yue-Ming; Xu, Yu-Ting; Zhang, Xin; Gao, Wen-Xia; Huang, Xiao-Bo; Zhou, Yun-Bing; Liu, Miao-Chang; Wu, Hua-Yue. And the article was published in Organic Letters in 2019. SDS of cas: 150-19-6 The author mentioned the following in the article:

Presented in this paper is photoinduced hydroxylation of organic halides, providing a mild access to a range of functionalized phenols and aliphatic alcs. These reactions generally proceed under mild reaction conditions with no need for a photocatalyst or a strong base and show a wide substrate scope as well as excellent functional group tolerance. This work highlights the unique role of NaI that allows a challenging transformation to proceed under mild reaction conditions. The results came from multiple reactions, including the reaction of m-Methoxyphenol(cas: 150-19-6SDS of cas: 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.SDS of cas: 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Enhanced visible light-mediated photocatalysis, antibacterial functions and fabrication of a 3-chlorophenol sensor based on ternary Ag2O·SrO·CaO》 was written by Subhan, Abdus Md; Rifat, Tanjila Parvin; Chandra Saha, Pallab; Alam, M. M.; Asiri, Abdullah M.; Rahman, Mohammed M.; Akter, Sonia; Raihan, Topu; Azad, A. K.; Uddin, Jamal. Quality Control of m-Methoxyphenol And the article was included in RSC Advances in 2020. The article conveys some information:

A novel multi-metal oxide nanocomposite, Ag2O·SrO·CaO, was synthesized by a facile co-precipitation method followed by calcinations. The synthesized nanocomposite was characterized by XRD, FESEM, EDS, TEM, FTIR spectroscopy and photoluminescence (PL) spectroscopy. The composite showed enhanced photocatalytic activity under visible light irradiation and excellent anti-bacterial performance against both Gram-pos. and Gram-neg. bacteria. Here, the synthesized Ag2O·SrO·CaO nanomaterials were deposited on a glassy carbon electrode (GCE) in the form of a thin film to fabricate the desired electrochem. sensor and subjected to I-V anal. of 3-chlorophenol (3-CP) in a phosphate buffer solution (PBS). A calibration curve was plotted from the linear relation of current vs. concentration and used to calculate the sensitivity (8.9684μA μM-1 cm-2), linear dynamic range (LDR, 0.1 nM to 0.01 mM) and lower limit of detection (DL, 97.12 ± 4.86 pM). The anal. parameters of the sensor such as response time, reproducibility and long-term stability in the detection of 3-CP were reliable. Finally, it was used to analyze real samples collected from various environmental sources and found to be acceptable. The experimental part of the paper was very detailed, including the reaction process of m-Methoxyphenol(cas: 150-19-6Quality Control of m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneQuality Control of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Modular bismacycles for the selective C-H arylation of phenols and naphthols》 was written by Jurrat, Mark; Maggi, Lorenzo; Lewis, William; Ball, Liam T.. Product Details of 150-19-6 And the article was included in Nature Chemistry in 2020. The article conveys some information:

Given the important role played by 2-hydroxybiaryls in organic, medicinal and materials chem., concise methods for the synthesis of this common motif are extremely valuable. In seeking to extend the lexicon of synthetic chemists in this regard, the authors have developed an expedient and general strategy for the ortho-arylation of phenols and naphthols using readily available boronic acids. The authors’ methodol. relies on in situ generation of a uniquely reactive Bi(V) arylating agent from a bench-stable Bi(III) precursor via telescoped B-to-Bi transmetalation and oxidation By exploiting reactivity that is orthogonal to conventional metal-catalyzed manifolds, diverse aryl and heteroaryl partners can be rapidly coupled to phenols and naphthols under mild conditions. Following arylation, high-yielding recovery of the Bi(III) precursor allows for its efficient re-use in subsequent reactions. Mechanistic interrogation of each key step of the methodol. informs its practical application and provides fundamental insight into the underexploited reactivity of organobismuth compounds In the part of experimental materials, we found many familiar compounds, such as m-Methoxyphenol(cas: 150-19-6Product Details of 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Product Details of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zhang, Yuanyuan; Liang, Yaoyu; Zhao, Xiaodan published their research in ACS Catalysis in 2021. The article was titled 《Chiral Selenide-Catalyzed, Highly Regio- and Enantioselective Intermolecular Thioarylation of Alkenes with Phenols》.Computed Properties of C7H8O2 The article contains the following contents:

Enantioselective electrophilic three-component thioarylation of alkenes by chiral selenide catalysis with free phenols as arylating sources is disclosed. A variety of chiral phenols, e.g., I, were prepared in high regio-, enantio-, and diastereoselectivities. Mechanistic studies revealed that this transformation went through carbon nucleophilic attack to give the products rather than the process of intramol. rearrangement of phenolic ether intermediates. The application of this organocatalytic method in the alkylation of methoxy-substituted benzenes elucidated its generality. The experimental part of the paper was very detailed, including the reaction process of m-Methoxyphenol(cas: 150-19-6Computed Properties of C7H8O2)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneComputed Properties of C7H8O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zhu, Da-Liang; Jiang, Shan; Wu, Qi; Wang, Hao; Li, Hai-Yan; Li, Hong-Xi published an article in 2021. The article was titled 《Nickel-Catalyzed Etherification of Phenols and Aryl Halides through Visible-Light-Induced Energy Transfer》, and you may find the article in Organic Letters.Safety of m-Methoxyphenol The information in the text is summarized as follows:

A visible-light-initiated, nickel-catalyzed O-arylation of phenols with arylhalides using t-BuNH(i-Pr) as the base and thioxanthen-9-one as the photosensitizer under visible light was reported. This photocoupling exhibited a broad substrate scope. In the experiment, the researchers used many compounds, for example, m-Methoxyphenol(cas: 150-19-6Safety of m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Safety of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Anand, Ashish; Sindogi, Kishorkumar; Dixit, Sheshagiri R.; Shetty, Richa P.; Pujar, Gurubasavaraj V.; Kulkarni, Manohar V.; Guru Row, Tayur N. published an article in ChemistrySelect. The title of the article was 《Comparative Investigation on the Crystal Structures, Hirshfeld Surface Analysis, Antitubercular Assays, and Molecular Docking of Regioisomeric 1,2,3-Triazoles》.HPLC of Formula: 150-19-6 The author mentioned the following in the article:

1,2,3-Triazole system is readily obtained by the click reaction in a facile and regioselective way. Regioselectivity is introduced under Copper(CuAAC), and Ruthenium(RuAAC) catalyzed azide-alkyne cycloaddition reaction furnishing 1,4 and 1,5-disubstituted triazoles, resp. These two regioisomeric systems offer discrete physicochem. and medicinal properties based on crucial binding interactions and biocompatibility with the biol. targets. In this regard, a comparative investigation on the coumarin-linked regioisomeric 1,2,3-triazoles via its crystal structure, Hirshfeld surface anal., and antitubercular assays and mol. docking are reported. It sheds light on the variation of in vitro antitubercular efficacy against Mycobacterium tuberculosis H37Rv followed by mol. docking studies that justify the prominent interactions at the binding site. Further, solid-state and Hirshfeld surface anal. provided significant crystallog. insights on the critical intermol. interactions that dictate the crystal packing in these systems. Thus structure-property correlation for these regioisomeric systems can open new avenues in drug design and discovery. The results came from multiple reactions, including the reaction of m-Methoxyphenol(cas: 150-19-6HPLC of Formula: 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneHPLC of Formula: 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem