Category: 52244-70-9

Akagawa, Kengo; Fujiwara, Takuma; Sakamoto, Seiji; Kudo, Kazuaki published the artcile< One-pot sequential alcohol oxidation and asymmetric α-oxyamination in aqueous media using recyclable resin-supported peptide catalyst>, HPLC of Formula: 52244-70-9, the main research area is enantioselective alc oxidation oxyamination peptide catalyst.

Oxidation of primary alcs. RCH2CH2OH (R = Ph, 4-O2NC6H4CH2CH2, CH2:CHCH2, etc.) to the corresponding aldehydes followed by an asym. α-oxyamination with a resin-supported peptide catalyst gave compounds I (R = Bn, phenethyl, allyl, Ph, etc.).

Chemical Communications (Cambridge, United Kingdom) published new progress about Enantioselective synthesis. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, HPLC of Formula: 52244-70-9.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Pandey, Ganesh; Laha, Ramkrishna; Mondal, Pradip Kumar published the artcile< Heterocyclization involving benzylic C(sp3)-H functionalization enabled by visible light photoredox catalysis>, HPLC of Formula: 52244-70-9, the main research area is nitrogen heterocycle preparation; amine heterocyclization ruthenium catalyst visible light mediated; oxygen heterocycle preparation; alc heterocyclization ruthenium catalyst visible light mediated.

A general and efficient method for heterocyclization involving benzylic C(sp3)-H functionalization enabled by visible light photoredox catalysis to access a wide range of structurally diverse oxygen as well as nitrogen heterocycles, e.g. I up to a gram scale was reported. The potential application of this new methodol. was demonstrated by the total synthesis of (-)-codonopsinine and (+)-centrolobine. Herein, it was proposed that selectfluor, unlike a fluorinating reagent, acts as an oxidative quencher and a hydrogen radical acceptor.

Chemical Communications (Cambridge, United Kingdom) published new progress about Alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, HPLC of Formula: 52244-70-9.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Jue, Zhaofan; Huang, Yahao; Qian, Jiahui; Hu, Peng published the artcile< Visible Light-Induced Unactivated δ-C(sp3)-H Amination of Alcohols Catalyzed by Iron>, COA of Formula: C11H16O2, the main research area is primary secondary tertiary alc amination visible light iron; C−H activation; amination; hydrogen transfer; iron; photocatalysis.

An iron-catalyzed remote C(sp3)-H amination of alcs. through 1,5-hydrogen atom transfer is developed. This protocol provides a method to generate δ-C(sp3)-N bonds from primary, secondary, and tertiary alcs. under mild conditions. A wide substrate scope and a good functional group tolerance are presented. Mechanistic studies show that a LMCT course of an Fe-OR species and a chlorine radical-induced hydrogen abstraction of an alc. are possible to generate the alkoxy radical intermediate.

ChemSusChem published new progress about Amination. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, COA of Formula: C11H16O2.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Chen, Fenglin; Chen, Ke; Zhang, Yao; He, Yuli; Wang, Yi-Ming; Zhu, Shaolin published the artcile< Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH>, Related Products of 52244-70-9, the main research area is nickel catalyzed reductive cross electrophile coupling; migratory electrophile coupling olefin hydroarylation ligand nickel controlled; diarylalkane structurally diverse preparation regioselectivity.

A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This general protocol allows the use of abundant and bench-stable alkyl bromides and aryl bromides for the synthesis of a wide range of structurally diverse 1,1-diarylalkanes in excellent yields and high regioselectivities under mild conditions. Authors also demonstrated that alkyl bromide could be replaced by the proposed olefin intermediate while using Pr bromide/Mn0 as a potential hydride source.

Journal of the American Chemical Society published new progress about Alkanes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (1,1-diarylalkanes). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Related Products of 52244-70-9.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem