Nojima, Kazuhiro et al. published their research in Chemosphere in 1976 | CAS: 5367-32-8

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Safety of 3-Methyl-4-nitroanisole

Studies of photochemistry of aromatic hydrocarbons. III. Formation of nitrophenols by the photochemical reaction of toluene in the presence of nitrogen monoxide and nitrophenols in rain was written by Nojima, Kazuhiro;Fukaya, Katsuhisa;Fukui, Shozo;Kanno, Saburo;Nishiyama, Shinichi;Wada, Yutaka. And the article was included in Chemosphere in 1976.Safety of 3-Methyl-4-nitroanisole This article mentions the following:

Photoreaction of toluene with NO gives o-cresol, m-nitrotoluene, p-nitrophenol (I), 2-methyl-6-nitrophenol (II), 3-methyl-4-nitrophenol, 2-methyl-4-nitrophenol (III), and 2-methyl-4,6-dinitrophenol, all identified by gas chromatog.-mass spectrometry. Mass fragmentation anal. showed that I, II, and III are present in rain. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8Safety of 3-Methyl-4-nitroanisole).

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Safety of 3-Methyl-4-nitroanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Manoharan, Ramasamy et al. published their research in Organic & Biomolecular Chemistry in 2018 | CAS: 16356-02-8

1,4-Dimethoxy-2-butyne (cas: 16356-02-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Application of 16356-02-8

Cobalt-catalyzed cyclization of benzamides with alkynes: a facile route to isoquinolones with hydrogen evolution was written by Manoharan, Ramasamy;Jeganmohan, Masilamani. And the article was included in Organic & Biomolecular Chemistry in 2018.Application of 16356-02-8 This article mentions the following:

The reaction of benzamides with alkynes assisted by an 8-aminoquinoline ligand in the presence of Co(OAc)2·4H2O and pivalic acid under an air atm. provided isoquinolone derivatives in good to excellent yields. In this reaction, the active Co(III) species is regenerated by the reaction of Co(I) species with pivalic acid under an air atm. with hydrogen evolution. The proposed mechanism was supported by competition experiments, deuterium labeling studies, radical scavenger experiments and kinetic studies. In the experiment, the researchers used many compounds, for example, 1,4-Dimethoxy-2-butyne (cas: 16356-02-8Application of 16356-02-8).

1,4-Dimethoxy-2-butyne (cas: 16356-02-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Application of 16356-02-8

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Modi, Sandeep P. et al. published their research in Organic Syntheses in 1995 | CAS: 5367-32-8

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Synthetic Route of C8H9NO3

An efficient synthesis of indole-2-acetic acid methyl esters: methyl 5-methoxyindole-2-acetate (1H-indole-2-acetic acid, 5-methoxy-, methyl ester) was written by Modi, Sandeep P.;Oglesby, R. Christopher;Archer, Sydney. And the article was included in Organic Syntheses in 1995.Synthetic Route of C8H9NO3 This article mentions the following:

A general synthetic method for the preparation in 3 steps of indole-2-acetic acid Me esters from o-nitrophenylacetic acids is described. The overall yields are 30-40% and the reactions can be carried out on a large scale. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8Synthetic Route of C8H9NO3).

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Synthetic Route of C8H9NO3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Li, Dizao et al. published their research in Yaoxue Xuebao in 2005 | CAS: 1877-75-4

2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Name: 2-(4-Methoxyphenoxy)acetic acid

Synthesis and antitumor activity of A-ring modified hexacyclic analogs of camptothecin was written by Li, Dizao;Wang, Cunying;Pan, Xiandao;Liu, Hongyan;Fu, Zhaodi;Wu, Song. And the article was included in Yaoxue Xuebao in 2005.Name: 2-(4-Methoxyphenoxy)acetic acid This article mentions the following:

The biol. activity of A-ring modified analogs of camptothecin was improved. A-ring modified camptothecins were synthesized from 10-hydroxycamptothecin or 7-ethyl-10-hydroxycamptothecin (SN-38) in 3 or 4 steps. Their cytotoxicity was evaluated using MTT assay, and their in-vivo antitumor activity against mouse liver cancer H22 was tested. Five hexacyclic camptothecins are target compounds, and ten camptothecin derivatives are new compounds The modification of an 1,4-oxazin-2-one ring-fused with positions 9 and 10 of A-ring will reduce the antitumor activity of camptothecins. In the experiment, the researchers used many compounds, for example, 2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4Name: 2-(4-Methoxyphenoxy)acetic acid).

2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Name: 2-(4-Methoxyphenoxy)acetic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Diederichsen, Kyle M. et al. published their research in Joule in 2022 | CAS: 111-77-3

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Product Details of 111-77-3

Toward solvent-free continuous-flow electrochemically mediated carbon capture with high-concentration liquid quinone chemistry was written by Diederichsen, Kyle M.;Liu, Yayuan;Ozbek, Nil;Seo, Hyowon;Hatton, T. Alan. And the article was included in Joule in 2022.Product Details of 111-77-3 This article mentions the following:

The recent interest in electrochem. methods of carbon capture has thus far focused either on static adsorbent-type electrodes, which require complex gas distribution and release engineering, or aqueous flowing systems, which allow capture over large, distributed areas and release from a centralized point, but require large amounts of water. Here, we advance a concept for a flowing, electrochem. mediated carbon capture process by utilizing redox-active mols. that are liquid at room temperature, avoiding the need for large water feeds. To demonstrate the potential of this concept, we employed a liquid quinone sorbent with added glyme to aid in salt solubilization coupled to a ferrocene-derived counter electrolyte. We achieved good electrochem. stability and continuous capture and release of CO2 in a full bench scale process. Our concept for continuous-flow electrochem. CO2 capture suggests many areas for further study, particularly the need for novel cell concepts and designs. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Product Details of 111-77-3).

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Product Details of 111-77-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Li, Gaolin et al. published their research in Journal of Organic Chemistry in 2022 | CAS: 105-13-5

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Application of 105-13-5

Direct Synthesis of Amides from Benzonitriles and Benzylic Alcohols via a KOt-Bu-Mediated MPV-type Hydrogen Transfer Process was written by Li, Gaolin;Li, Meichen;Xia, Zhen;Tan, Ze;Deng, Wei;Fang, Chen. And the article was included in Journal of Organic Chemistry in 2022.Application of 105-13-5 This article mentions the following:

Meerwein-Ponndorf-Verley (MPV)-type reduction between benzonitriles and benzylic alcs. under transition-metal-free conditions has been demonstrated for the first time. Using simple KOt-Bu as the base, various benzonitriles can be efficiently reduced by benzylic alcs. via hydrogen transfer reduction, and the resultant Ph imine can react further with benzylic alcs. to give amides as the final product in which both the alcs. and the nitriles are incorporated. Preliminary mechanistic investigations indicated that the reaction may go through multiple MPV-type hydrogen transfer processes. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Application of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Application of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Wei, Shuangying et al. published their research in Electrochimica Acta in 2019 | CAS: 112-49-2

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Recommanded Product: 112-49-2

Glyme-based electrolytes for lithium metal batteries using insertion electrodes: An electrochemical study was written by Wei, Shuangying;Li, Zhenguang;Kimura, Kento;Inoue, Shoichi;Pandini, Loris;Di Lecce, Daniele;Tominaga, Yoichi;Hassoun, Jusef. And the article was included in Electrochimica Acta in 2019.Recommanded Product: 112-49-2 This article mentions the following:

We report an electrochem. study of end-capped glymes dissolving lithium salts as electrolyte solutions for lithium metal batteries. Various electrolyte formulations including triethylene and diethylene glycol di-Me ethers as solvents and lithium salts employing bis(fluorosulfonyl)imide (FSI–), bis(trifluoromethanesulfonyl)imide (TFSI–), and bis(pentafluoroethanesulfonyl)imide (BETI–) anions are explored. The ion transport properties, the lithium/electrolyte interphase characteristics and the electrochem. stability window are investigated by means of chronoamperometry, electrochem. impedance spectroscopy, galvanostatic cycling, and voltammetry measurements. The comparative study suggests electrochem. properties well suitable for lithium battery application which enable long cycling. The electrolyte solutions are studied in cells using an insertion cathode material, i.e., lithium iron phosphate (LiFePO4), and the high-energy lithium metal anode. The results reveal that the electrolyte composition has a remarkable effect on the cell performances, and indicate the solutions of LiTFSI salt in either glymes as the most adequate formulations for possible applications among the ones herein investigated. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2Recommanded Product: 112-49-2).

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Recommanded Product: 112-49-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Lifi, Mohamed et al. published their research in Journal of Chemical Thermodynamics in 2020 | CAS: 111-77-3

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Product Details of 111-77-3

Excess molar enthalpy measurement and modelling of (oxygenated compounds + hydrocarbon) mixtures: Binary and ternary mixtures containing 2-(2-methoxyethoxy)ethanol, 1-hexene and cyclohexane at (298.15 and 313.15) K was written by Lifi, Mohamed;Munoz-Rujas, Natalia;Montero, Eduardo A.;Negadi, Latifa;Aguilar, Fernando;Ezzahrae M′hamdi Alaoui, Fatima. And the article was included in Journal of Chemical Thermodynamics in 2020.Product Details of 111-77-3 This article mentions the following:

NEW measurements and modeling data of excess molar enthalpy HE at atm. pressure and temperatures of (298.15 and 313.15) K using a quasi-isothermal flow calorimeter are presented in this work for the ternary system diethylene glycol monomethyl ether glycol (2-(2-methoxyethoxy)ethanol) + 1-hexene + cyclohexane and the corresponding binary systems over the whole composition range. All the binary and ternary systems present an endothermic behavior at the chosen temperatures The exptl. data of the binary and ternary systems were correlated using the modified Redlich-Kister equation, NRTL and UNIQUAC models. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Product Details of 111-77-3).

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Product Details of 111-77-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Xu, Xiao et al. published their research in Journal of Fluorescence in 2017 | CAS: 1877-75-4

2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Safety of 2-(4-Methoxyphenoxy)acetic acid

Quaternary Ammonium Polyamidoamine Dendrimer Modified Quantum Dots as Fluorescent Probes for p-Fluorophenoxyacetic Acid Detection in Aqueous Solution was written by Xu, Xiao;Cao, Yuan-Cheng;Liu, Jun′An;Lin, Yongjun. And the article was included in Journal of Fluorescence in 2017.Safety of 2-(4-Methoxyphenoxy)acetic acid This article mentions the following:

The wide use of pesticide p-fluorophenoxyacetic acid has caused the serious environmental contaminant. A novel fluorescent probe for sensitive detection of p-fluorophenoxyacetic acid in aqueous solutions based on 3.0G quaternary ammonium polyamidoamine (PAMAM) dendrimer modified quantum dots (QDs) (PAMAM@QDs) was reported. Through the solvent-evaporation method, quaternary ammonium PAMAM was employed to modify the QDs. Poloxamer 188 was used to improve the solubility and stability. The resultant PAMAM@QDs dispersed well in water. Fluorescence (FL) spectroscopic study showed that the FL intensity of the PAMAM@QDs was enhanced in the presence of p-fluorophenoxyacetic acid. Under optimal conditions, the enhanced FL intensity as a function of concentration matched very well in the range of 1 ∼ 200 μg/mL of p-fluorophenoxyacetic acid, while the lower limits of detection were found to be 0.16 μg/mL. These results show that PAMAM@QDs is a promising luminescent probe for the detection of pesticides. In the experiment, the researchers used many compounds, for example, 2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4Safety of 2-(4-Methoxyphenoxy)acetic acid).

2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Safety of 2-(4-Methoxyphenoxy)acetic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Nishiyama, Yutaka et al. published their research in Tetrahedron Letters in 2022 | CAS: 105-13-5

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Application of 105-13-5

Rhenium complex-catalyzed deoxygenation and silylation of alcohols with hydrosilane was written by Nishiyama, Yutaka;Xu, Shijie;Hanatani, Yuuki;Tsuda, Susumu;Umeda, Rui. And the article was included in Tetrahedron Letters in 2022.Application of 105-13-5 This article mentions the following:

The reduction of benzylic, tertiary, and allylic alcs. with hydrosilane was efficiently catalyzed by the rhenium complex, such as ReBr(CO)5, to give the corresponding deoxygenarated products, alkanes, in moderate to good yields. In the case of aliphatic secondary alc., the alkane was formed along with the formation of dehydrated products. On the other hand, in the case of primary and cyclic alcs., silylation of alcs. proceeded to form the corresponding silyl ethers. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Application of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Application of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem