Month: November 2022

Xu, Xu et al. published their research in Journal of Organic Chemistry in 2020 | CAS: 103-16-2

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Name: 4-Benzyloxyphenol

Ruthenium-Catalyzed Meta-Selective C-H Difluoromethylation of Phenol Derivatives was written by Xu, Xu;Tao, Na;Fan, Wei-Tai;Tu, Guangliang;Geng, Jingyao;Zhang, Jingyu;Zhao, Yingsheng. And the article was included in Journal of Organic Chemistry in 2020.Name: 4-Benzyloxyphenol The following contents are mentioned in the article:

With pyrimidine as the directing group, we achieved the meta-selective difluoromethylation of phenol derivatives using ruthenium as a catalyst. This synthetic scheme provided an efficient method for the syntheses of fluorine-containing phenol derivatives A wide variety of phenol derivatives were well-suited, affording the corresponding products in moderate-to-good yields. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Name: 4-Benzyloxyphenol).

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Name: 4-Benzyloxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Lu, Xiao-Yu et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2015 | CAS: 1003858-50-1

2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.COA of Formula: C12H17BO3

Cu-Catalyzed cross-coupling reactions of epoxides with organoboron compounds was written by Lu, Xiao-Yu;Yang, Chu-Ting;Liu, Jing-Hui;Zhang, Zheng-Qi;Lu, Xi;Lou, Xin;Xiao, Bin;Fu, Yao. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2015.COA of Formula: C12H17BO3 The following contents are mentioned in the article:

A copper-catalyzed cross-coupling reaction of epoxides with arylboronates is described. This reaction is not limited to aromatic epoxides, because aliphatic epoxides are also suitable substrates. In addition, N-sulfonyl aziridines can be successfully converted into the products. This reaction provides convenient access to β-phenethyl alcs., which are valuable synthetic intermediates. This study involved multiple reactions and reactants, such as 2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1COA of Formula: C12H17BO3).

2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.COA of Formula: C12H17BO3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Meng, Chenkai et al. published their research in Molecules in 2020 | CAS: 103-16-2

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.HPLC of Formula: 103-16-2

Nickel-catalyzed removal of alkene protecting group of phenols, alcohols via chain walking process was written by Meng, Chenkai;Niu, Haolin;Ning, Juehan;Wu, Wengang;Yi, Jun. And the article was included in Molecules in 2020.HPLC of Formula: 103-16-2 The following contents are mentioned in the article:

An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alc. ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2HPLC of Formula: 103-16-2).

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.HPLC of Formula: 103-16-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Meng, Chenkai et al. published their research in Molecules in 2020 | CAS: 103-16-2

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Synthetic Route of C13H12O2

Nickel-catalyzed removal of alkene protecting group of phenols, alcohols via chain walking process was written by Meng, Chenkai;Niu, Haolin;Ning, Juehan;Wu, Wengang;Yi, Jun. And the article was included in Molecules in 2020.Synthetic Route of C13H12O2 The following contents are mentioned in the article:

An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alc. ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Synthetic Route of C13H12O2).

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Synthetic Route of C13H12O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Solovyev, Igor et al. published their research in Tetrahedron Letters in 2021 | CAS: 109-85-3

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Recommanded Product: 2-Methoxyethylamine

Novel 3,4-dihydro-1,4-oxazine (dehydromorpholine) sulfonamides and sulfones conveniently accessed from suitable a-diazoketones via O-H carbene insertion – Cyclization sequence was written by Solovyev, Igor;Dar’in, Dmitry;Krasavin, Mikhail. And the article was included in Tetrahedron Letters in 2021.Recommanded Product: 2-Methoxyethylamine The following contents are mentioned in the article:

A short and practically convenient, modular approach to hitherto unknown dehydromorpholine sulfones and sulfonamides from α-acyl-α-diazomethyl sulfones and sulfonamides, resp., was developed. It involves Rh(II) carbene insertion into the O-H bond of 2-bromoethanol followed by thermally promoted tandem SN2 displacement of the bromine atom by a primary amine and cyclodehydration. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Recommanded Product: 2-Methoxyethylamine).

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Recommanded Product: 2-Methoxyethylamine

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Frail, Paul R. et al. published their research in Chemistry of Materials in 2007 | CAS: 112-59-4

2-(2-(Hexyloxy)ethoxy)ethanol (cas: 112-59-4) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Related Products of 112-59-4

Modulation of Dark Conductivity over a 1 × 10-12 to 1 × 10-5 S/cm Range Through Ancillary Group Modification in Amorphous Solids of Ethyne-Bridged (Porphinato)zinc(II) Oligomers was written by Frail, Paul R.;Susumu, Kimihiro;Huynh, Michael;Fong, Jennie;Kikkawa, J. M.;Therien, Michael J.. And the article was included in Chemistry of Materials in 2007.Related Products of 112-59-4 The following contents are mentioned in the article:

2- And 4-probe dark conductivity (DC) data obtained for thin-film and solid-state samples of undoped PZnn oligomers show that the measured DCs for these species span an impressively wide range. Sterically unencumbered PZnn oligomers enable augmented interchain electronic coupling in the solid state and provide electronically functional thin films via direct spin-casting. This study involved multiple reactions and reactants, such as 2-(2-(Hexyloxy)ethoxy)ethanol (cas: 112-59-4Related Products of 112-59-4).

2-(2-(Hexyloxy)ethoxy)ethanol (cas: 112-59-4) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Related Products of 112-59-4

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Chen, Yantao et al. published their research in ChemistrySelect in 2022 | CAS: 109-85-3

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Related Products of 109-85-3

An Improved Synthesis of 1λ;6,2,4,6-Thiatriazine-1,3,5-trione Derivatives – the Sulfonimidamide-featured Triazinones was written by Chen, Yantao;Kollback, Johanna;Aurell, Carl-Johan. And the article was included in ChemistrySelect in 2022.Related Products of 109-85-3 The following contents are mentioned in the article:

N,N’-dicarbamoylation of 4-methylbenzenesulfonimidamide with carbonyldiimidazole, followed by a mono-nucleophilic substitution with amines and subsequential ring closure in one-pot, afforded 1λ6,2,4,6-thiatriazine-1,3,5-trione derivatives I [R = cyclohexyl, Ph, 3-pyridyl, etc.] in up to 83% yields. The protocol also worked well for aliphatic sulfonimidamides, such as Me sulfonimidamide. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Related Products of 109-85-3).

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Related Products of 109-85-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Yue, Wen-Jun et al. published their research in Journal of the American Chemical Society in 2021 | CAS: 109-85-3

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application of 109-85-3

Site-Selective Defluorinative sp3 C-H Alkylation of Secondary Amides was written by Yue, Wen-Jun;Day, Craig S.;Martin, Ruben. And the article was included in Journal of the American Chemical Society in 2021.Application of 109-85-3 The following contents are mentioned in the article:

A site-selective defluorinative sp3 C-H alkylation of secondary amides that rapidly and reliably incorporates gem-difluoroalkene motifs into previously unfunctionalized sp3 sites was disclosed. This protocol was distinguished by its mild conditions, wide scope and exquisite site-selectivity, thus unlocking a new platform to introduce carbonyl isosteres at saturated hydrocarbon sites. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Application of 109-85-3).

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application of 109-85-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Keefe, Melinda et al. published their research in CoatingsTech in 2011 | CAS: 112-59-4

2-(2-(Hexyloxy)ethoxy)ethanol (cas: 112-59-4) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Name: 2-(2-(Hexyloxy)ethoxy)ethanol

Art and industry: novel approaches to the evaluation and development of cleaning systems for artists’ acrylic latex paints was written by Keefe, Melinda;Tucker, Christopher;Behr, Anastasia Mardilovich;Meyers, Greg;Reinhardt, Carl;Boomgaard, Tom;Peitsch, Cory;Ormsby, Bronwyn;Soldano, Alexia;Phenix, Alan;Learner, Thomas. And the article was included in CoatingsTech in 2011.Name: 2-(2-(Hexyloxy)ethoxy)ethanol The following contents are mentioned in the article:

A method has been developed to quantify and differentiate the cleaning efficacies of traditional and novel aqueous, aliphatic hydrocarbon solvent, and water-in-oil microemulsion-based cleaning systems using high throughput tools and methodol. Cleaning solutions with good cleaning efficacy were identified from all three classes of formulations by screening hundreds of formulations on the high throughput tools. This study involved multiple reactions and reactants, such as 2-(2-(Hexyloxy)ethoxy)ethanol (cas: 112-59-4Name: 2-(2-(Hexyloxy)ethoxy)ethanol).

2-(2-(Hexyloxy)ethoxy)ethanol (cas: 112-59-4) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Name: 2-(2-(Hexyloxy)ethoxy)ethanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Kumaran, G. et al. published their research in Indian Journal of Chemistry in 1994 | CAS: 154548-95-5

Propanoicacid,2-(4-ethoxyphenoxy)-2-methyl- (cas: 154548-95-5) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Recommanded Product: 154548-95-5

A simple synthetic route to 3-phenoxybenzyl 2-methyl-2-(p-substituted phenoxy and thiophenoxy/naphthoxy)propyl ethers, structurally related to ethofenoprox was written by Kumaran, G.;Kulkarni, G. H.. And the article was included in Indian Journal of Chemistry in 1994.Recommanded Product: 154548-95-5 The following contents are mentioned in the article:

Some title compds, e.g., 4-FC6H4OCMe2CH2OCH2C6H4OPh-3, bearing a close structural resemblance to the powerful insecticide MTI-500 (4-EtOC6H4OCMe2CH2OCH2C6H4OPh-3) have been synthesized by a simple route for evaluating their insecticidal properties (data given). This study involved multiple reactions and reactants, such as Propanoicacid,2-(4-ethoxyphenoxy)-2-methyl- (cas: 154548-95-5Recommanded Product: 154548-95-5).

Propanoicacid,2-(4-ethoxyphenoxy)-2-methyl- (cas: 154548-95-5) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Recommanded Product: 154548-95-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem