Category: 105-13-5

Switchable ROS Species Regulation Facilitates the Selective Oxidation of Benzyl Alcohols Enabled by an Organic Photocatalyst was written by Jia, Meng-Ze;Cui, Jing-Wang;Rao, Cai-Hui;Chen, Yun-Rui;Yao, Xin-Rong;Zhang, Jie. And the article was included in ACS Sustainable Chemistry & Engineering in 2022.Computed Properties of C8H10O2 This article mentions the following:

Benefiting from the regulation of ROS species through a simple and feasible strategy, an efficient and switchable photocatalytic protocol for the chemoselective synthesis of aldehydes and carboxylic acids via oxidation of primary alcs. under mild conditions was developed. Using the pyridinium derivative as a metal-free organic photocatalyst, a variety of benzyl alcs. can be converted into aldehydes or carboxylic acids under an air atm. at room temperature with high selectivity and yield via simple solvent regulation. A feasible tandem reaction combining the pyridinium-catalyzed alc.-to-aldehyde conversion and catalyst-free photoinduced oxidation of aromatic aldehydes provides a powerful and efficient approach for the one-pot oxidation of benzyl alcs. to carboxylic acids, while a small amount of water can effectively regulate the competition of electron transfer and energy transfer and inhibit the generation of carboxylic acids, facilitating highly efficient and selective oxidation of alcs. to aldehydes. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Computed Properties of C8H10O2).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Computed Properties of C8H10O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

An efficient photocatalytic synthesis of benzimidazole over cobalt-loaded TiO₂ catalysts under solar light irradiation was written by Kumaraswamy, Gullapelli;Sadanandam, Gullapelli;Ledwaba, Kabelo;Maroju, Ravichandar. And the article was included in Journal of Photochemistry and Photobiology, A: Chemistry in 2022.SDS of cas: 105-13-5 This article mentions the following:

Cobalt-loaded TiO₂ (Co-TiO₂) based photocatalysts have been successfully used in energy and environmental applications, but their application in synthesis of Benzimidazole from ortho phenylenediamines has never been reported. Benzimidazole is a very important class of heterocyclic compounds and it occupies a unique position in the field of pharmaceutical chem. Here, Co-TiO₂ photocatalysts were prepared using an impregnation method and characterized by XRD, UV-Vis DRS, FE-SEM, TEM and Raman techniques. The present study explores the photocatalytic synthesis of 2-Aryl Benzimidazoles over cobalt-loaded TiO₂ under solar light irradiation The cobalt-loaded TiO₂ catalysts exhibited excellent photocatalytic performance under solar light in the preparation of 2-Aryl Benzimidazoles. This efficient and higher photocatalytic activity can be attributed to the visible light active structure of Co-TiO₂ and surface-interacted cobalt species on TiO₂ support. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5SDS of cas: 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.SDS of cas: 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Direct Synthesis of Amides from Benzonitriles and Benzylic Alcohols via a KOt-Bu-Mediated MPV-type Hydrogen Transfer Process was written by Li, Gaolin;Li, Meichen;Xia, Zhen;Tan, Ze;Deng, Wei;Fang, Chen. And the article was included in Journal of Organic Chemistry in 2022.Application of 105-13-5 This article mentions the following:

Meerwein-Ponndorf-Verley (MPV)-type reduction between benzonitriles and benzylic alcs. under transition-metal-free conditions has been demonstrated for the first time. Using simple KOt-Bu as the base, various benzonitriles can be efficiently reduced by benzylic alcs. via hydrogen transfer reduction, and the resultant Ph imine can react further with benzylic alcs. to give amides as the final product in which both the alcs. and the nitriles are incorporated. Preliminary mechanistic investigations indicated that the reaction may go through multiple MPV-type hydrogen transfer processes. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Application of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Application of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Rhenium complex-catalyzed deoxygenation and silylation of alcohols with hydrosilane was written by Nishiyama, Yutaka;Xu, Shijie;Hanatani, Yuuki;Tsuda, Susumu;Umeda, Rui. And the article was included in Tetrahedron Letters in 2022.Application of 105-13-5 This article mentions the following:

The reduction of benzylic, tertiary, and allylic alcs. with hydrosilane was efficiently catalyzed by the rhenium complex, such as ReBr(CO)₅, to give the corresponding deoxygenarated products, alkanes, in moderate to good yields. In the case of aliphatic secondary alc., the alkane was formed along with the formation of dehydrated products. On the other hand, in the case of primary and cyclic alcs., silylation of alcs. proceeded to form the corresponding silyl ethers. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Application of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Application of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

A New Route to E-Stilbenes through the Transition-Metal-Free KOtBu/DMF-Promoted Direct Coupling of Alcohols with Phenyl Acetonitriles was written by Liu, Xiaoping;Sotiropoulos, Jean-Marc;Taillefer, Marc. And the article was included in European Journal of Organic Chemistry in 2022.Related Products of 105-13-5 This article mentions the following:

An alternative route to synthesize alkenes, based only on the KOtBu/DMF promoted activation and direct coupling of alcs. with Ph acetonitriles, was reported. A variation allowing, through a Csp³-Csp³ bond formation, the selective synthesis of N-Heteroarenes was also described. A mechanism for the olefination pathway proceeding via an original activation of alcs. under alkyl formates was provided. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Related Products of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.Related Products of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

BioMOF-Mn: An Antimicrobial Agent and an Efficient Nanocatalyst for Domino One-Pot Preparation of Xanthene Derivatives was written by Ghamari kargar, Pouya;Bagherzade, Ghodsieh;Beyzaei, Hamid;Arghavani, Soheila. And the article was included in Inorganic Chemistry in 2022.Recommanded Product: (4-Methoxyphenyl)methanol This article mentions the following:

In this paper, a new Mn-based metal-organic framework [UoB-6] was obtained via a one-step ultrasonic irradiation method with the ligand (H₂bdda: 4,4′-(1,4-phenylenebis(azaneylylidene))bis(methanelylidene))dibenzoic acid. The structural integrity of the synthesized BioMOF-Mn was corroborated by FT-IR, EDX, ICP, XRD, TEM, DLS, FESEM, and BET-BJH analyses. The aerobic oxidative domino reaction of benzyl alcs. or aldehydes with dimedone derivatives was performed in the presence of the UoB-6 catalyst to produce xanthene derivatives in good yields. Hot filtration and Hg poisoning tests proved the heterogeneous nature of the catalyst. Novel synthesized xanthene-based bis-aldehydes were introduced as potent HDAC1 inhibitors according to mol. docking calculations Finally, the inhibitory activities of Mn-MOF nanoparticles were evaluated on Escherichia coli and Candida albicans. The MIC, MBC, and MFC values were determined from 2048 to 4096μg·mL^-1 according to antimicrobial susceptibility testing methods. The inhibitory effects of antimicrobial agents can be exacerbated when loaded on BioMOFs. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Recommanded Product: (4-Methoxyphenyl)methanol).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.Recommanded Product: (4-Methoxyphenyl)methanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Acceptorless dehydrogenation of primary alcohols to carboxylic acids by self-supported NHC-Ru single-site catalysts was written by Yin, Shenxiang;Zheng, Qingshu;Chen, Jie;Tu, Tao. And the article was included in Journal of Catalysis in 2022.Recommanded Product: 105-13-5 This article mentions the following:

The acceptorless dehydrogenation of diverse aromatic and aliphatic primary alcs. to corresponding carboxylic acids was accomplished by self-supported NHC-Ru single-site catalysts under mild reaction conditions. Besides broad substrates with excellent activity, selectivity and good tolerance to sensitive functional groups, the solid single-site catalyst could be recovered and reused for more than 20 runs without deactivation. Remarkably, up to 1.8 x 10⁴ turnover numbers could be achieved by this newly developed sustainable protocol in gram scale at low catalyst loading, highlighting its potential in industry. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Recommanded Product: 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Recommanded Product: 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Efficient Synthesis of Imines by Oxidative Coupling Catalyzed by Ce-Mn Oxide Microspheres was written by Chutimasakul, Threeraphat;Tirdtrakool, Warinda;Na Nakhonpanom, Pakamon;Kreethatorn, Hemmarat;Jaruwatee, Pattamaporn;Bunchuay, Thanthapatra;Tantirungrotechai, Jonggol. And the article was included in ChemistrySelect in 2022.Safety of (4-Methoxyphenyl)methanol This article mentions the following:

Oxidative self-coupling of amines and cross-coupling with alcs. are important reactions for the synthesis of imines; however, catalytic systems for these reactions usually require expensive oxidant, complicated catalyst preparation, complex reaction set-up, and/or additives such as bases or cocatalysts. Here, authors report that amorphous cerium-manganese (Ce-Mn) oxides with hierarchical microsphere structure prepared by a facile method could exhibit excellent catalytic performance for the synthesis of various imines using air as the green oxidant under mild conditions. The Ce-Mn oxide heterogeneous catalysts could also be easily recovered and efficiently recycled without significant loss of activities. The excellent activities and the reusability of the Ce-Mn oxide microspheres offer potential advances in the synthesis of imine. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Safety of (4-Methoxyphenyl)methanol).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.Safety of (4-Methoxyphenyl)methanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Synthesis of Ag nanoparticles by Celery leaves extract supported on magnetic biochar substrate, as a catalyst for the reduction reactions was written by Taheri, Sahar;Heravi, Majid M.;Mohammadi, Pourya. And the article was included in Scientific Reports in 2022.Reference of 105-13-5 This article mentions the following:

In this study, a biochar/Fe₃O₄-Ag magnetic nanocatalyst was produced via a green path by using Celery stalk as a carbon-based substrate and Celery leaf extract as reducing and stabilizing agents to construct Ag nanoparticles. The synthesized nanocatalyst was determined using various techniques, such as UV-Vis spectroscopy, FT-IR spectroscopy, XRD (X-ray diffraction), SEM/EDX spectroscopy (SEM/energy-dispersive X-ray), TEM (transmission electron microscopy) and VSM (vibrating sample magnetometer). To survey the catalytic action of the biochar/Fe₃O₄-Ag nanocatalyst, it was used in the reduction reaction of disparate nitroaroms., aldehydes, and ketones. This catalyst demonstrated good characteristics in terms of the amount, reusability, recoverability, activity, and structural integrity of the catalyst during the reaction. In addition, biochar/Fe₃O₄-Ag could be detached magnetically and recycled multiple times without significantly reducing its catalytic performance. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Reference of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Reference of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Accelerated Decomposition of Potassium Permanganate in Ferrocenium Ion as Ferrocenium-Doped Manganese(IV) Oxide for Selective Oxidation of Alcohols was written by Chumkaeo, Peerapong;Poonsawat, Thinnaphat;Yunita, Isti;Temnuch, Natcha;Meechai, Titiya;Kumpan, Nuttapong;Khamthip, Achjana;Chuaitammakit, Laksamee Chaicharoenwimolkul;Chairam, Sanoe;Somsook, Ekasith. And the article was included in Synlett in 2022.Recommanded Product: 105-13-5 This article mentions the following:

Ferrocenium-doped manganese(IV) oxide (Fc⁺/MnO₂) was synthesized through accelerated decomposition of KMnO₄ in the presence of ferrocenium ion (Fc⁺) generated by concentrated sulfuric acid. The corresponding catalysts enabled highly efficient oxidation of alcs. with aldehyde or ketone. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Recommanded Product: 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Recommanded Product: 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem