Category: ethers-buliding-blocks

Sagane, Fumihiro et al. published their research in Electrochemistry (Tokyo, Japan) in 2022 | CAS: 112-49-2

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. Ethers feature bent C閳ユ彊閳ユ弲 linkages. In dimethyl ether, the bond angle is 111鎺?and C閳ユ彊 distances are 141 pm. The barrier to rotation about the C閳ユ彊 bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Synthetic Route of C8H18O4

The effect of Mg morphology on the irregular behavior of the electrochemical quartz crystal microbalance in Mg[N(CF3SO2)2]2/glyme solutions was written by Sagane, Fumihiro;Muramatsu, Akiya. And the article was included in Electrochemistry (Tokyo, Japan) in 2022.Synthetic Route of C8H18O4 This article mentions the following:

Mg plating/stripping reaction in Mg[N(CF3SO2)2]2/glyme based solution is studied by electrochem. quartz crystal microbalance method. During the cyclic voltammetry, the apparent mass decrease is observed in spite of the neg. scan. The irregular response also appears in the Mg plating reaction with low constant c.d. apply. In the cases, Mg plating takes place locally and the size of each plating is relatively large of about 50娓璵. The cross-sectional image of the plated Mg is tree-like structure, i.e., the large Mg crystal connects to the substrate with small contact area. From the results, we conclude that the specific Mg morphol. causes the restoring force to the quartz substrate, resulting in the apparent mass decrease. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2Synthetic Route of C8H18O4).

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. Ethers feature bent C閳ユ彊閳ユ弲 linkages. In dimethyl ether, the bond angle is 111鎺?and C閳ユ彊 distances are 141 pm. The barrier to rotation about the C閳ユ彊 bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Synthetic Route of C8H18O4

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Driscoll, Darren M. et al. published their research in Journal of the Electrochemical Society in 2020 | CAS: 112-49-2

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Formula: C8H18O4

Rationalizing calcium electrodeposition behavior by quantifying ethereal solvation effects on Ca2+ coordination in well-dissociated electrolytes was written by Driscoll, Darren M.;Dandu, Naveen K.;Hahn, Nathan T.;Seguin, Trevor J.;Persson, Kristin A.;Zavadil, Kevin R.;Curtiss, Larry A.;Balasubramanian, Mahalingam. And the article was included in Journal of the Electrochemical Society in 2020.Formula: C8H18O4 This article mentions the following:

Ca-ion electrochem. systems have been pushed to the forefront of recent multivalent energy storage advances due to their use of earth-abundant redox materials and their high theor. specific densities in relation to monovalent or even other more widely explored multivalent-charge carriers. However, significant pitfalls in metal plating and stripping arise from electrolyte decomposition and can be related to the coordination environment around Ca2+ with both the neg. charged anion and the organic-aprotic solvent. In this study, we apply multiple spectroscopic techniques in conjunction with d. functional theory to evaluate the coordination environment of Ca2+ across a class of ethereal solvents. Through the combination of X-ray absorption fine structure and time-dependent d. functional theory, descriptive measures of the local geometry, coordination, and electronic structure of Ca-ethereal complexes provide distinct structural trends depending on the extent of the Ca2+-solvent interaction. Finally, we correlate these findings with electrochem. measurements of calcium tetrakis(hexafluoroisopropoxy)borate (CaBHFIP2) salts dissolved within this class of solvents to provide insight into the preferred structural configuration of Ca2+ electrolytic solutions for optimized electrochem. plating and stripping. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2Formula: C8H18O4).

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Formula: C8H18O4

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Peng, Xiaomei et al. published their research in Advanced Optical Materials in 2022 | CAS: 111-77-3

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Computed Properties of C5H12O3

Near-Infrared OLEDs Based on Functional Pyrazinyl Azolate Os(II) Phosphors and Deuteration was written by Peng, Xiaomei;Yeh, Chia-Hsiu;Wang, Sheng Fu;Yan, Jie;Gan, Shifeng;Su, Shi-Jian;Zhou, Xiuwen;Zhang, Ye-Xin;Chi, Yun. And the article was included in Advanced Optical Materials in 2022.Computed Properties of C5H12O3 This article mentions the following:

Near-IR (NIR) emitting Os(II) complexes [Os(L1)2(PPhMe2)2] (tz1), [Os(L2)2(PPhMe2)2] (tz2), and [Os(L3)2(PPhMe2)2] (tz3), bearing dual (1H-1,2,4-triazol-5-yl)pyrazine chromophoric chelates, are successfully developed. These pyrazine chelates tzn (n = 1, 2, 3) differ by the location and number of 4-(trifluoromethyl)phenyl appendage(s) on pyrazine, and the associated Os(II) complexes exhibit bathochromic shifted emission, higher quantum yield, and increased radiative lifetime in comparison to parent complex [Os(fprtz)2(PMe2Ph)2] (tz0). Moreover, partially deuterated pyrazine chelate L1-d is prepared using post-synthetic deuteration, from which the Os(II) complex tz1 shows a photoluminescence quantum yield (PLQY) of 12.2% in co-doped 4,4閳?bis(N-carbazolyl)biphenyl (CBP) thin film at 3 wt%. Further, the partially deuterated tz1-d exhibits a notable increase in PLQY to 17.8% upon co-deposited into CBP thin film, confirming the influence of C-H(D) stretching vibrations on the non-radiative transition processes. Finally, tz1-d is demonstrated to be suitable in the fabrication of efficient NIR organic light-emitting diodes (OLEDs), from which maximum external quantum efficiency of 3.77% and maximum radiance of 24.1 W sr-1 m-2 are recorded for emission with peak maximum at 776 nm. These experiments confirm the suppression of C-H vibration caused quenching by deuteration, which should be broadly applicable to the OLED emitters, especially in the NIR region. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Computed Properties of C5H12O3).

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Computed Properties of C5H12O3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Pandarus, Valerica et al. published their research in ChemCatChem in 2014 | CAS: 365564-07-4

2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 365564-07-4) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Name: 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

SiliaCat Diphenylphosphine Palladium(II) Catalyzed Borylation of Aryl Halides was written by Pandarus, Valerica;Marion, Olivier;Gingras, Genevieve;Beland, Francois;Ciriminna, Rosaria;Pagliaro, Mario. And the article was included in ChemCatChem in 2014.Name: 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane This article mentions the following:

Authors investigate the heterogeneously catalyzed direct synthesis of boronic acid pinacol esters using a wide range of aryl chlorides, bromides, and iodides, and bis(pinacolato)diboron as the borylating agent over the sol-gel entrapped SiliaCat diphenylphosphine palladium(II) catalyst. Optimization of the reaction conditions, scale-up of the optimized process, and anal. of palladium leaching enabled us to establish a new selective route for direct access to a diverse set of boronic acid pinacol esters. In the experiment, the researchers used many compounds, for example, 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 365564-07-4Name: 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane).

2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 365564-07-4) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Name: 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Oshchepkov, Aleksandr S. et al. published their research in Makrogeterotsikly in 2015 | CAS: 66943-05-3

1,4,7,10-Tetraoxa-13-azacyclopentadecane (cas: 66943-05-3) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.HPLC of Formula: 66943-05-3

Synthesis of 4-nitro- and 4-aminophenylazacrown ethers was written by Oshchepkov, Aleksandr S.;Oshchepkov, Maksim S.;Anisimov, Alexander V.;Fedorova, Olga A.. And the article was included in Makrogeterotsikly in 2015.HPLC of Formula: 66943-05-3 This article mentions the following:

The study was dedicated to finding optimal reaction conditions for the introduction of 4-nitro- and 4-aminophenyl substituents into the structure of azacrown ethers with a varied ratio of oxygen to nitrogen heteroatoms. The synthetic procedure was proposed for the synthesis of 4-nitroaryl derivatives of crown ethers. This method was remarkably simple, has easy work-up and affords the formation solely of the monoarylation product. In the experiment, the researchers used many compounds, for example, 1,4,7,10-Tetraoxa-13-azacyclopentadecane (cas: 66943-05-3HPLC of Formula: 66943-05-3).

1,4,7,10-Tetraoxa-13-azacyclopentadecane (cas: 66943-05-3) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.HPLC of Formula: 66943-05-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Horwitz, Gabriela et al. published their research in Physical Chemistry Chemical Physics in 2020 | CAS: 112-49-2

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.SDS of cas: 112-49-2

Electrochemical stability of glyme-based electrolytes for Li-O2 batteries studied by in situ infrared spectroscopy was written by Horwitz, Gabriela;Calvo, Ernesto J.;Mendez De Leo, Lucila P.;de la Llave, Ezequiel. And the article was included in Physical Chemistry Chemical Physics in 2020.SDS of cas: 112-49-2 This article mentions the following:

In situ subtractively normalized Fourier transform IR spectroscopy (SNIFTIRS) experiments were performed simultaneously with electrochem. experiments relevant to Li-air battery operation on gold electrodes in two glyme-based electrolytes: diglyme (DG) and tetraglyme (TEGDME), tested under different operational conditions. The results show that TEGDME is intrinsically unstable and decomposes at potentials between 3.6 and 3.9 V vs. Li+/Li even in the absence of oxygen and lithium ions, while DG shows a better stability, and only decomposes at 4.0 V vs. Li+/Li in the presence of oxygen. The addition of water to the DG based electrolyte exacerbates its decomposition, probably due to the promotion of singlet oxygen formation. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2SDS of cas: 112-49-2).

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.SDS of cas: 112-49-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Polyak, Daniel et al. published their research in Organic Letters in 2022 | CAS: 105-13-5

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).HPLC of Formula: 105-13-5

Homoallylboration of Aldehydes: Stereoselective Synthesis of Allylic-Substituted Alkenes and E-Alkenes was written by Polyak, Daniel;Xu, Bokai;Krauss, Isaac J.. And the article was included in Organic Letters in 2022.HPLC of Formula: 105-13-5 This article mentions the following:

In this study, the scope and reactivity of homoallylation with cyclopropylcarbinylboronates I (R = Et, but-3-en-1-yl, Ph, Bn, etc.) bearing various aliphatic and aromatic 浼? and 绾?substituents were explored. The 浼?alkyl substituted boronates I afforded E-disubstituted alkenyl secondary alcs. C6H5CH2CH2CH(OH)CH2CH2CH=CHR in high e.r., while aryl substituents promoted rearrangement. The 绾?alkyl substituents all resulted in diastereoselective homoallylation, while aryl substitution changed the outcome to cyclopropylcarbinylation. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5HPLC of Formula: 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).HPLC of Formula: 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Cemeris, M. et al. published their research in Koksnes Kimija in 1974 | CAS: 3929-47-3

3-(3,4-Dimethoxyphenyl)propan-1-ol (cas: 3929-47-3) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethers feature bent C閳ユ彊閳ユ弲 linkages. In dimethyl ether, the bond angle is 111鎺?and C閳ユ彊 distances are 141 pm. The barrier to rotation about the C閳ユ彊 bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Reference of 3929-47-3

Use of high-frequency conductometry in organic chemistry. IV. Acid-base properties of aromatic alcohols of the phenylpropane and guaiacylpropane series was written by Cemeris, M.;Galochkin, A. I.. And the article was included in Koksnes Kimija in 1974.Reference of 3929-47-3 This article mentions the following:

The acidities of phenylalkanols decreased in the order p-O2NC6H4CH2OH > PhCH2OH > PhCH:CHCH2OH > PhCH2CH2OH > PhCHEtOH > Ph(CH2)3OH; those of veratryl alcs. decreased in the order ZCH:CHCH2OH [Z = 3,4-(MeO)2C6H3] > Z(CH2)3OH > ZCHEtOH; those of guaiacylpropanols were comparable with that of PhCH2OH. In the experiment, the researchers used many compounds, for example, 3-(3,4-Dimethoxyphenyl)propan-1-ol (cas: 3929-47-3Reference of 3929-47-3).

3-(3,4-Dimethoxyphenyl)propan-1-ol (cas: 3929-47-3) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethers feature bent C閳ユ彊閳ユ弲 linkages. In dimethyl ether, the bond angle is 111鎺?and C閳ユ彊 distances are 141 pm. The barrier to rotation about the C閳ユ彊 bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Reference of 3929-47-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Oddon, Gilles et al. published their research in Tetrahedron Letters in 1993 | CAS: 60221-37-6

2-(2-(2-((Tetrahydro-2H-pyran-2-yl)oxy)ethoxy)ethoxy)ethan-1-ol (cas: 60221-37-6) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).COA of Formula: C11H22O5

Silacrown ethers: synthesis of macrocyclic diphenylpolyethylene glycol mono- and disilanes was written by Oddon, Gilles;Hosseini, Mir Wais. And the article was included in Tetrahedron Letters in 1993.COA of Formula: C11H22O5 This article mentions the following:

New mono- and disilacrown ethers I–IV [[k]OlSim: (k,l,m) = (8,3,1); (11,4,1); (16,6,2); (22,8,2), resp.] were prepared by reacting Ph2SiCl2 with HO(CH2CH2O)nH (n=2, 3) in the presence of base. Variation of the bases revealed that cations could act as templates and thus orient the synthesis towards the mono- or the disilanes. In the experiment, the researchers used many compounds, for example, 2-(2-(2-((Tetrahydro-2H-pyran-2-yl)oxy)ethoxy)ethoxy)ethan-1-ol (cas: 60221-37-6COA of Formula: C11H22O5).

2-(2-(2-((Tetrahydro-2H-pyran-2-yl)oxy)ethoxy)ethoxy)ethan-1-ol (cas: 60221-37-6) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).COA of Formula: C11H22O5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Maity, Tanmoy et al. published their research in Catalysis Communications in 2015 | CAS: 54916-28-8

1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone

Ligand free copper-catalyzed heterogeneous O-arylation reaction under green condition was written by Maity, Tanmoy;Saha, Debraj;Das, Soma;Bhunia, Susmita;Koner, Subratanath. And the article was included in Catalysis Communications in 2015.Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone This article mentions the following:

A highly porous Zn-based iso-reticular metal-organic framework (IRMOF-3) has been selected for covalent modification. Pyridine-2-aldehyde has been used to decorate the free amine group of IRMOF-3 in the porous matrix. Schiff base moiety thus generated has been availed to anchor copper(II) ions to prepare the desired catalyst that catalyzes O-arylation reactions heterogeneously under mild reaction conditions. Porous catalyst demonstrates size selectivity in products when various substrates undergo O-arylation with 浼?and 灏?naphthol. In the experiment, the researchers used many compounds, for example, 1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone).

1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Safety of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem