Category: ethers-buliding-blocks

On June 4, 2021, Zhang, Qiaoling; Feng, Hang; Chen, Feng; He, Ze; Zeng, Qingle published an article.Computed Properties of 53136-21-3 The title of the article was Unusual Deoxidative Coupling Reaction of β-Sulfinyl Esters with Benzylic Trimethylammonium Salts. And the article contained the following:

A KOH-promoted unusual deoxidative coupling reaction of β-sulfinyl esters RS(O)(CH2)2C(O)2C(CH3)3 (R = 4-CH3C6H4, 2-pyridyl, 1H-1,3-benzodiazol-2-yl, etc.) with benzylic trimethylammonium salts ArN+(CH3)3-OTf (Ar = Bn, pyridin-2-ylmethyl, 1,2,3,4-tetrahydronaphthalen-1-yl, etc.) to produce thioethers RSAr is discovered for the first time. If quaternary ammonium salts synthesized from enantiomerically enriched amines are adopted, highly enantiomerically enriched benzyl thioethers (>95-99% ee) with configurations opposite to those of the enantiomerically enriched amines are obtained. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3

The Article related to thioether preparation, sulfinyl ester benzylic trimethylammonium salt deoxidative coupling reaction, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Computed Properties of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On November 7, 2012, Guan, Pei; Cao, Changsheng; Liu, Yun; Li, Yunfei; He, Pan; Chen, Qian; Liu, Gang; Shi, Yanhui published an article.Electric Literature of 53136-21-3 The title of the article was Efficient nickel/N-heterocyclic carbene catalyzed C-S cross-coupling. And the article contained the following:

The cross-coupling reaction of aryl halides with aliphatic and aromatic thiols catalyzed by readily available Ni(OAc)2 with N-heterocyclic carbene (NHC) is reported. Ni(OAc)2/NHC catalyst showed good activities toward various aryl halides in C-S coupling reaction, even with aryl chlorides. Reactions occurred in excellent yields, broad scope, and high tolerance of functional groups. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Electric Literature of 53136-21-3

The Article related to thioether aryl preparation, cross coupling aryl halide thiol nickel heterocyclic carbene catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Electric Literature of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On March 17, 2021, Hashimoto, Toru; Shiota, Keisuke; Funatsu, Kei; Yamaguchi, Yoshitaka published an article.Recommanded Product: 2-Methoxynaphthalene The title of the article was Cross-Coupling Reactions of Aryl Halides with Primary and Secondary Aliphatic Alcohols Catalyzed by an O,N,N-Coordinated Nickel Complex. And the article contained the following:

A synthesis of alkyl aryl ethers was achieved via the cross-coupling of aryl halides with primary and secondary aliphatic alcs. catalyzed by a bench-stable nickel complex supported by a monoanionic O,N,N-tridentate ligand. This nickel-catalyzed reaction proceeds smoothly in the absence of a phosphine ligand, affording alkyl aryl ethers in moderate to good yields. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Recommanded Product: 2-Methoxynaphthalene

The Article related to aryl halide aliphatic alc nickel catalyst cross coupling reaction, alkyl aryl ether preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: 2-Methoxynaphthalene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On January 13, 2010, Jean, Mickael; Renault, Jacques; van de Weghe, Pierre; Asao, Naoki published an article.Safety of Benzyl(4-bromophenyl)sulfane The title of the article was Gold-catalyzed C-S bond formation from thiols. And the article contained the following:

Ortho-Alkynylbenzoic acid alkyl esters act as alkylating agents of thiol derivatives with PPh3AuCl in combination with AgOTf in 1,2-dichloroethane at 80 °C. The corresponding sulfide compounds are obtained in good to excellent yields. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to sulfide preparation, gold catalyzed carbon sulfur bond formation alkynylbenzoic ester thiol, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On April 30, 2004, Ham, Jungyeob; Yang, Inho; Kang, Heonjoong published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was A facile one-pot synthesis of alkyl aryl sulfides from aryl bromides. And the article contained the following:

A convenient one-pot synthetic method for the formation of alkyl aryl sulfides, e.g., I, from various alkyl halides and lithium aryl thiolates that were prepared in situ by direct halogen-lithium exchange, is reported. The method was very quick, catalyst-free, and did not involve use of unstable aryl thiols. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to aryl bromide alkyl halide sulfurization alkylation, alkyl aryl sulfide preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zhao, Feng; Tan, Qi; Wang, Dahan; Deng, Guo-Jun published an article in 2020, the title of the article was Metal- and solvent-free direct C-H thiolation of aromatic compounds with sulfonyl chlorides.Quality Control of 2-Methoxynaphthalene And the article contains the following content:

A simple, efficient and green method for the direct thiolation of aromatic compounds using com. available sulfonyl chlorides as the sulfur source was developed under metal- and solvent-free conditions. The C-S bond was constructed via direct C-H functionalization of diverse aromatic compounds under an oxygen atm. In this process, various diaryl sulfides were synthesized in moderate to excellent yields. This protocol shows a broad substrate scope and good functional group tolerance. Moreover, a gram-scale experiment was also conducted to prove the prospect of this method for the scale-up synthesis of diaryl sulfides. Mechanistic studies indicate that this procedure probably undergoes a radical pathway. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Quality Control of 2-Methoxynaphthalene

The Article related to arene aryl sulfonyl chloride thiolation, sulfide diaryl preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Quality Control of 2-Methoxynaphthalene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Wang, Jianqiang; Shi, Fangmin; Dai, Dongyan; Xiong, Liping; Yang, Yongpo published an article in 2021, the title of the article was N-bromosuccinimide/HCl mediated reduction of sulfoxides to sulfides.Reference of Benzyl(4-bromophenyl)sulfane And the article contains the following content:

An efficient reduction of sulfoxides RS(O)R1 (R = Ph, Me, benzyl, etc.; R1 = Ph, 4-chlorophenyl, n-Bu, etc.) to sulfides RSR1 mediated by N-bromosuccinimide (NBS)/HCl system has been developed. This protocol shows good functional group compatibility as well as broad substrates scope with operational simplicity. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Reference of Benzyl(4-bromophenyl)sulfane

The Article related to sulfide preparation, sulfoxide reduction bromosuccinimide catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Reference of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On December 31, 2002, Bandgar, B. P.; Pandit, S. S.; Nagargoje, S. P. published an article.Reference of Benzyl(4-bromophenyl)sulfane The title of the article was Zinc-mediated simple and practical synthesis of sulfides. And the article contained the following:

A novel and inexpensive method for the synthesis of thioethers from alkyl halides and thiols using zinc was developed. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Reference of Benzyl(4-bromophenyl)sulfane

The Article related to alkyl halide reaction thiol zinc catalyst, sulfide preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Reference of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On July 19, 2019, Chen, Yang; Qi, Hongyi; Chen, Ning; Ren, Demin; Xu, Jiaxi; Yang, Zhanhui published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was Fluorium-Initiated Dealkylative Cyanation of Thioethers to Thiocyanates. And the article contained the following:

Thioethers are converted to thiocyanates via fluorium-initiated dealkylative cyanation. Selectfluor is used as the oxidant, and trimethylsilyl cyanide is used as the cyanation reagent. The well-streamlined procedure is user-friendly, operationally simple, and step-economical. The current mechanistic studies show that the sulfur radical cation and cyano radical are both involved. They combine to deliver cyanosulfonium, an intermediate toward thiocyanate after dealkylation. Alternatively, a nucleophilic mechanism is also possible. This dealkylative cyanation is also efficient in synthesizing thiocyanates with strongly electrophilic functionalities. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to thioether dealkylative cyanation, thiocyanate preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On February 28, 1995, Bandgar, B. P.; Ghorpade, Pushplata K.; Shrotri, Nirupama S.; Patil, S. V. published an article.Category: ethers-buliding-blocks The title of the article was Polymer-supported reactions in organic synthesis. Part II. Synthesis of some sulfides. And the article contained the following:

Thiophenoxide ions supported on Amberlite IRA-900 (chloride from) have been treated with arylalkyl halides as well as with aryl halides to get sulfides which are useful in crop protection. Isolation of pure products by simple filtration and evaporation is an important feature of this method. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Category: ethers-buliding-blocks

The Article related to sulfides synthesis polymer supported reagent, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Category: ethers-buliding-blocks

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem