Tag: 200-300

On June 30, 2017, Sinai, Adam; Meszaros, Adam; Balogh, Adam; Zwillinger, Marton; Novak, Zoltan published an article.Product Details of 157869-15-3 The title of the article was Hexafluorosilicic Acid as a Novel Reagent for the Desilylation of Silylacetylenes: Application in Sequential Sonogashira Coupling and Click Reaction. And the article contained the following:

Hexafluorosilicic acid was utilized as a novel, cheap, readily available, and environmentally benign alternative reagent for the desilylation of 1-trimethylsilylacetylenes. The applicability of the aqueous solution of the hexafluorosilicic acid was demonstrated in the sequential coupling of aryl halides and ethynyltrimethylsilane to afford internal acetylenes, benzofurans, and triazoles in one-pot Sonogashira-Sonogashira and Sonogashira-CuAAC reactions. The experimental process involved the reaction of 2-((4-Methoxyphenyl)ethynyl)aniline(cas: 157869-15-3).Product Details of 157869-15-3

The Article related to arylalkyne preparation, aryl iodide silylacetylene sequential sonogashira coupling click chem, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Product Details of 157869-15-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Tang, Lin; Wu, Chaoting; Hu, Qiyan; Li, Qian; Zhang, Wu published an article in 2018, the title of the article was Cross-coupling reactions using porous multipod Cu2O microcrystals as recoverable catalyst in aqueous media.Related Products of 157869-15-3 And the article contains the following content:

Porous multipod Cu2O microcrystals were found to be an efficient, highly recyclable and eco-friendly catalyst for the cross-coupling reactions of aryl halides and terminal alkynes with high yields in aqueous media. Noteworthy, the Cu2O catalyst can be reused for several times without significant decrease in catalytic activity. The experimental process involved the reaction of 2-((4-Methoxyphenyl)ethynyl)aniline(cas: 157869-15-3).Related Products of 157869-15-3

The Article related to aryl halide alkyne terminal copper sonogashira coupling catalyst, alkyne aryl preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Related Products of 157869-15-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On January 15, 2022, Wang, Tao; Guo, Jiarui; Xu, Yongli; Wang, Xiaobo; Wang, Yan; Feng, Dandan; Liu, Lantao published an article.Computed Properties of 53136-21-3 The title of the article was Synthesis of benzyl thioether derivatives via N-heterocyclic carbene palladium(II)-catalyzed cross coupling of benzylammonium salts with thiophenols. And the article contained the following:

A new route to benzyl thioether derivatives has been developed via the N-heterocyclic carbene palladium(II)-catalyzed cross coupling of benzylammonium salts with thiophenols. Under the optimal conditions, different benzylammonium salts could be well tolerated. Meanwhile, various kinds of aryl thiophenols and heteroaryl thiophenols could be used as efficient substrates, generating broad array of benzyl thioethers in good to high yields within hours. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3

The Article related to benzyl thioether preparation, benzylammonium salt thiophenol cross coupling, nitrogen heterocyclic carbene palladium catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Computed Properties of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zhang, Yonghong; Li, Yiming; Zhang, Xiaomei; Jiang, Xuefeng published an article in 2015, the title of the article was Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions.Related Products of 53136-21-3 And the article contains the following content:

We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomols. including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Related Products of 53136-21-3

The Article related to sulfide preparation, aryltriazene preparation halide copper sulfate sodium thiosulfate, aryl amine diazotization amine, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Related Products of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On August 15, 2006, Ma, Ming-you published an article.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene The title of the article was Synthesis of 1-[(2-ethylhexyl)oxy]-4-methoxybenzene under ultrasound conditions. And the article contained the following:

1-[(2-Ethylhexyl)oxy]-4-methoxybenzene (MOEHOB) was synthesized by the reaction of 4-methoxyphenol (MOPh) with 2-ethylhexyl bromide in argon atm. under supersonic irradiation in the solution of sodium ethoxide. Reaction yields reached 86-88%. The optimum reaction conditions: molar ratio of MOPh/ethylhexyl bromide was 1:1.5, the concentration of sodium ethoxide was 2.5 mol/L, the frequency of the ultrasound was 40 kHz, the reaction time was 5-6 h. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

The Article related to ethylhexyloxy methoxy benzene preparation, methoxyphenol ethylhexylbromide williamson ether synthesis ultrasound, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On July 29, 2015, Jiang, Xuefeng; Li, Yiming; Xie, Weisi published a patent.Computed Properties of 53136-21-3 The title of the patent was Process for the preparation of aryl alkyl sulfide or aryl aryl sulfide compounds via thiolation of benzenediazonium tetrafluoroborate with aryl(alkyl)thiosulfuric acid sodium salt. And the patent contained the following:

The invention relates to process for the preparation of aryl alkyl sulfide or aryl aryl sulfide compounds of formula ArSR [Ar = (un)substituted Ph or heteroaryl; R is alkyl and alkyl containing aryl group] via thiolation of benzenediazonium tetrafluoroborate [ArN2+BF4-] with aryl(alkyl)thiosulfuric acid sodium salt [RSSO3Na] under the catalysis of visible light and photosensitive reagent. For example, benzyl 4-methoxyphenyl sulfide was prepared by thiolation reaction of 4-methoxybenzenediazonium tetrafluoroborate with sodium benzyl thiosulfate catalyzed by Ru(bpy)3Cl2•6H2O in the presence of fluorescent light. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3

The Article related to aryl alkyl sulfide preparation benzenediazonium tetrafluoroborate alkylthiosulfuric acid photocatalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Computed Properties of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On June 4, 2021, Zhang, Qiaoling; Feng, Hang; Chen, Feng; He, Ze; Zeng, Qingle published an article.Computed Properties of 53136-21-3 The title of the article was Unusual Deoxidative Coupling Reaction of β-Sulfinyl Esters with Benzylic Trimethylammonium Salts. And the article contained the following:

A KOH-promoted unusual deoxidative coupling reaction of β-sulfinyl esters RS(O)(CH2)2C(O)2C(CH3)3 (R = 4-CH3C6H4, 2-pyridyl, 1H-1,3-benzodiazol-2-yl, etc.) with benzylic trimethylammonium salts ArN+(CH3)3-OTf (Ar = Bn, pyridin-2-ylmethyl, 1,2,3,4-tetrahydronaphthalen-1-yl, etc.) to produce thioethers RSAr is discovered for the first time. If quaternary ammonium salts synthesized from enantiomerically enriched amines are adopted, highly enantiomerically enriched benzyl thioethers (>95-99% ee) with configurations opposite to those of the enantiomerically enriched amines are obtained. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3

The Article related to thioether preparation, sulfinyl ester benzylic trimethylammonium salt deoxidative coupling reaction, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Computed Properties of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On November 7, 2012, Guan, Pei; Cao, Changsheng; Liu, Yun; Li, Yunfei; He, Pan; Chen, Qian; Liu, Gang; Shi, Yanhui published an article.Electric Literature of 53136-21-3 The title of the article was Efficient nickel/N-heterocyclic carbene catalyzed C-S cross-coupling. And the article contained the following:

The cross-coupling reaction of aryl halides with aliphatic and aromatic thiols catalyzed by readily available Ni(OAc)2 with N-heterocyclic carbene (NHC) is reported. Ni(OAc)2/NHC catalyst showed good activities toward various aryl halides in C-S coupling reaction, even with aryl chlorides. Reactions occurred in excellent yields, broad scope, and high tolerance of functional groups. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Electric Literature of 53136-21-3

The Article related to thioether aryl preparation, cross coupling aryl halide thiol nickel heterocyclic carbene catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Electric Literature of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On January 13, 2010, Jean, Mickael; Renault, Jacques; van de Weghe, Pierre; Asao, Naoki published an article.Safety of Benzyl(4-bromophenyl)sulfane The title of the article was Gold-catalyzed C-S bond formation from thiols. And the article contained the following:

Ortho-Alkynylbenzoic acid alkyl esters act as alkylating agents of thiol derivatives with PPh3AuCl in combination with AgOTf in 1,2-dichloroethane at 80 °C. The corresponding sulfide compounds are obtained in good to excellent yields. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to sulfide preparation, gold catalyzed carbon sulfur bond formation alkynylbenzoic ester thiol, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On April 30, 2004, Ham, Jungyeob; Yang, Inho; Kang, Heonjoong published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was A facile one-pot synthesis of alkyl aryl sulfides from aryl bromides. And the article contained the following:

A convenient one-pot synthetic method for the formation of alkyl aryl sulfides, e.g., I, from various alkyl halides and lithium aryl thiolates that were prepared in situ by direct halogen-lithium exchange, is reported. The method was very quick, catalyst-free, and did not involve use of unstable aryl thiols. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to aryl bromide alkyl halide sulfurization alkylation, alkyl aryl sulfide preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem