Tag: 200-300

In 2022,Rao, Desaboini Nageswara; Ji, Xincai; Miller, Stephen C. published an article in Chemical Science. The title of the article was 《Silicon functionalization expands the repertoire of Si-rhodamine fluorescent probes》.Name: tert-Butyl (2-(2-hydroxyethoxy)ethyl)carbamate The author mentioned the following in the article:

Reported a broad range of silyl modifications that enabled brighter dyes, further red-shifting, new ways to modulate fluorescence and the introduction of handles for dye attachment, including fluorogenic labeling agents for nuclear DNA, SNAP-tag and HaloTag labeling. Modifications to the bridging silicon were therefore of broad utility to improve and expanded the applications of all Si-dyes.tert-Butyl (2-(2-hydroxyethoxy)ethyl)carbamate(cas: 139115-91-6Name: tert-Butyl (2-(2-hydroxyethoxy)ethyl)carbamate) was used in this study.

tert-Butyl (2-(2-hydroxyethoxy)ethyl)carbamate(cas: 139115-91-6) belongs to ethers.Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly. Name: tert-Butyl (2-(2-hydroxyethoxy)ethyl)carbamate

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Wang, Deqiang; Ding, Wanjian; Hou, Guohua; Zi, Guofu; Walter, Marc D. published their research in Chemistry – A European Journal in 2021. The article was titled 《Uranium versus Thorium: Synthesis and Reactivity of [η5-1,2,4-(Me3C)3C5H2]2U[η2-C2Ph2]》.Synthetic Route of C12H10S2 The article contains the following contents:

The synthesis, electronic structure, and reactivity of a uranium metallacyclopropene were comprehensively studied. Addition of diphenylacetylene (PhCCPh) to the uranium phosphinidene metallocene [η5-1,2,4-(Me3C)3C5H2]2U:P-2,4,6-tBu3C6H2 (1) yields the stable uranium metallacyclopropene, [η5-1,2,4-(Me3C)3C5H2]2U[η2-C2Ph2] (2). Based on d. functional theory (DFT) results the 5f orbital contributions to the bonding within the metallacyclopropene U-(η2-C:C) moiety increases significantly compared to the related ThIV compound [η5-1,2,4-(Me3C)3C5H2]2Th[η2-C2Ph2], which also results in more covalent bonds between the [η5-1,2,4-(Me3C)3C5H2]2U2+ and [η2-C2Ph2]2- fragments. Although the thorium and uranium complexes are structurally closely related, different reaction patterns are therefore observed For example, 2 reacts as a masked synthon for the low-valent uranium(II) metallocene [η5-1,2,4-(Me3C)3C5H2]2UII when reacted with Ph2E2 (E = S, Se), alkynes and a variety of hetero-unsaturated mols. such as imines, ketazine, bipy, nitriles, organic azides, and azo derivatives In contrast, five-membered metallaheterocycles are accessible when 2 is treated with isothiocyanate, aldehydes, and ketones.1,2-Diphenyldisulfane(cas: 882-33-7Synthetic Route of C12H10S2) was used in this study.

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Ethers do have nonbonding electron pairs on their oxygen atoms, and they can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Synthetic Route of C12H10S2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Ali, Mubarak; Nasir, Saima; Froehlich, Kristina; Ramirez, Patricio; Cervera, Javier; Mafe, Salvador; Ensinger, Wolfgang published their research in Advanced Materials Interfaces in 2021. The article was titled 《Size-Based Cationic Molecular Sieving through Solid-State Nanochannels》.SDS of cas: 33100-27-5 The article contains the following contents:

The mol. sieving behavior of soft-etched polyimide membranes having neg. charged nanochannels is described exptl. and theor. using alkali metal-crown ether cationic complexes and alkylammonium cations. To this end, the elec. conduction and current rectification obtained with different alkali electrolyte solutions (LiCl, NaCl, and KCl) and crown ether mols. (12-crown-4, 15-crown-5, and 18-crown-6) are studied. The results suggest that only the [Li(12C4)]+ complex can readily permeate through the nanochannels because significant current decreases are obtained in the cases of the [Na(15C5)]+ and [K(18C6)]+ complexes. In solutions of organic cations ranging from ammonium (NH4+) to alkylammonium (R4N+) with increasing mol. size, only the smaller ions can conduct high elec. currents, suggesting again that the membrane channels are in the nanometer range. Taken together, the observed current decreases and rectification phenomena demonstrate that the functionalized membranes allow a versatile combination of mol. and electrostatic sieving. In the experiment, the researchers used many compounds, for example, 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5SDS of cas: 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. SDS of cas: 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Long-Distance Chirality Transfer from P-Ligand to Prochiral Dihydrosilanes via Pd(II) Aryl Iodide Complex in Pd-Catalyzed Silylation of Aryl Iodide: A DFT Study》 was published in Journal of Organic Chemistry in 2020. These research results belong to Yang, Jing-Jing; Xu, Zheng; Nie, Yi-Xue; Lu, Si-Qi; Zhang, Jin; Xu, Li-Wen. Recommanded Product: 1-Iodo-2-methoxybenzene The article mentions the following:

The mechanism of Pd-catalyzed desym. monoarylation of dihydrosilanes with aryl iodides in the presence of chiral TADDOL-derived phosphoramidite ligand toward deeper understanding of the stereoselectivity has been investigated using hybrid d. functional theory (DFT) methodol. The full catalytic cycle for the favorable reaction pathway, which is initiated by the oxidative addition of aryl iodide to monoligated Pd0 leading to the silylation product, was calculated The DFT calculation results indicate that the enantio-discriminating transmetalation between Pd-Ar bond of the Pd(II) aryl iodide complex and Si-H bond of the prochiral dihydrosilane was the enantioselectivity-determining step. On the basis of the structure of the transition state, the attractive aryl-aryl interactions between the aryl group of ligand, aryl iodide, and dihydrosilane were found to play an important role for the chiral transference from the chiral ligand to asym. cleavage of the Si-H bond of the prochiral dihydrosilane. The results came from multiple reactions, including the reaction of 1-Iodo-2-methoxybenzene(cas: 529-28-2Recommanded Product: 1-Iodo-2-methoxybenzene)

1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Recommanded Product: 1-Iodo-2-methoxybenzene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Bis(diphenylamine)-Tethered Carbazolyl Anthracene Derivatives as Hole-Transporting Materials for Stable and High-Performance Perovskite Solar Cells》 was published in ACS Applied Energy Materials in 2020. These research results belong to Singh, Ashutosh; Abate, Seid Yimer; Pavan Kumar, Ch.; Wu, Wen-Ti; Hsiao, Jye-Chian; Wu, Feng-Ling; Lin, Jiann T’suen; Tao, Yu-Tai. COA of Formula: C14H15NO2 The article mentions the following:

Three new hole-transporting materials (HTMs), composed of N3,N6-bis(di-4-anisylamino)-9H-carbazole and anthracene moieties, have been developed for perovskite solar cell (PSC) application. Two of the new HTMs have better hole mobility and hole-extraction ability compared to spiro-OMeTAD. Accordingly, the best PSC based on mixed ion perovskite of Cs0.05FA0.79MA0.16PbI2.49Br0.51 and doped HTMs has better power conversion efficiency (18.65%) than the corresponding PSC based on doped spiro-OMeTAD (17.90%). Moreover, the PSCs based on these HTMs have negligible hysteresis and good temporal stability. The experimental process involved the reaction of Bis(4-methoxyphenyl)amine(cas: 101-70-2COA of Formula: C14H15NO2)

Bis(4-methoxyphenyl)amine(cas: 101-70-2) is a diphenylamine derivative used as a chemical additive for cured rubber.Bis(4-methoxyphenyl)amine is highly toxic and may potentially induce chromosome abberation.COA of Formula: C14H15NO2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《A peri-xanthenoxanthene centered columnar-stacking organic semiconductor for efficient, photothermally stable perovskite solar cells》 were Xu, Niansheng; Li, Yang; Wu, Ruihan; Zhu, Rui; Zhang, Jidong; Zakeeruddin, Shaik M.; Li, Hanying; Li, Ze-Sheng; Graetzel, Michael; Wang, Peng. And the article was published in Chemistry – A European Journal in 2019. Application In Synthesis of Bis(4-methoxyphenyl)amine The author mentioned the following in the article:

Modulating the structure and property of hole-transporting organic semiconductors is of paramount importance for high-efficiency and stable perovskite solar cells (PSCs). This work reports a low-cost peri-xanthenoxanthene based small-mol. P1, which is prepared at a total yield of 82% using a 3-step synthetic route from the low-cost starting material 2-naphthol. P1 mols. stack in 1-dimensional columnar arrangement characteristic of strong intermol. π-π interactions, contributing to the formation of a solution-processed, semicrystalline thin-film exhibiting one order of magnitude higher hole mobility than the amorphous one based on the state-of-the art hole-transporter, 2,2-7,7-tetrakis(N,N’-di-paramethoxy-phenylamine 9,9′-spirobifluorene) (spiro-OMeTAD). PSCs employing P1 as the hole-transporting layer attain a high efficiency of 19.8% at the standard AM 1.5 G conditions, and good long-term stability under continuous full sunlight exposure at 40°C. The experimental part of the paper was very detailed, including the reaction process of Bis(4-methoxyphenyl)amine(cas: 101-70-2Application In Synthesis of Bis(4-methoxyphenyl)amine)

Bis(4-methoxyphenyl)amine(cas: 101-70-2) is a diphenylamine derivative used as a chemical additive for cured rubber.Bis(4-methoxyphenyl)amine is highly toxic and may potentially induce chromosome abberation.Application In Synthesis of Bis(4-methoxyphenyl)amine

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Mechanochemical Pd(II)-Catalyzed Direct and C-2-Selective Arylation of Indoles》 were Das, Dharmendra; Bhutia, Zigmee T.; Chatterjee, Amrita; Banerjee, Mainak. And the article was published in Journal of Organic Chemistry in 2019. Safety of 1-Iodo-2-methoxybenzene The author mentioned the following in the article:

A mechanochem. method for the preparation of synthetically useful 2-arylindoles is developed using Pd(II) as the catalyst in the absence of phosphine ligands in a ball-mill. The developed protocol is highly C-2 selective and tolerant of structural variations with electron-rich and electron-deficient substituents both in indoles and iodoarenes. Arylation is possible in both unprotected indoles and N-protected indoles with the electron-donating group with the former substrate being relatively slower to react and little less yielding. Indoles with a deactivated five-membered ring could also take part in the reaction with ease. The scalability of the reaction was demonstrated by conducting the reaction in the gram scale. In general, the reactions were achieved in a shorter time than the conventional methods. The experimental process involved the reaction of 1-Iodo-2-methoxybenzene(cas: 529-28-2Safety of 1-Iodo-2-methoxybenzene)

1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Safety of 1-Iodo-2-methoxybenzene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Computationally Assisted Mechanistic Investigation into Hypervalent Iodine Catalysis: Cyclization of N-Allylbenzamide》 were Butt, Smaher E.; Das, Mirdyul; Sotiropoulos, Jean-Marc; Moran, Wesley J.. And the article was published in Journal of Organic Chemistry in 2019. Application of 529-28-2 The author mentioned the following in the article:

Previous exptl. work identified 2-iodoanisole as the best precatalyst for the oxidative cyclization of N-alkenylamides into 2-oxazolines. Herein, we describe our investigation into the effect on reaction rate based on the structure of the iodoarene precatalyst. We also reveal the mechanism of the cyclization based on DFT modeling and obtain a clear correlation between observed reaction rates and computationally derived activation energies for different iodoarenes. In addition, the rate-limiting step is shown to be the cyclization of the substrate which is zero order in the concentration of the iodoarene precatalyst. The rate of the cyclization is found to correlate with the ease of oxidation of the iodoarene, however the most easily oxidized iodoarenes generate iodine(III) species that decompose readily. Finally, loss of iodoarene from the cyclized intermediate can proceed by either ligand-coupling or SN2 displacement (reductive elimination), and this is shown to be substrate dependent. After reading the article, we found that the author used 1-Iodo-2-methoxybenzene(cas: 529-28-2Application of 529-28-2)

1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Application of 529-28-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Advanced Synthesis & Catalysis included an article by Ruan, Hongjie; Meng, Ling-Guo; Zhu, Lingqiong; Wang, Lei. Related Products of 882-33-7. The article was titled 《Visible-Light-Induced Hydroxysulfurization and Alkoxysulfurization of Styrenes in the Absence of Photocatalyst: Synthesis of β-Hydroxysulfides and β-Alkoxysulfides》. The information in the text is summarized as follows:

Hydroxysulfurization and alkoxysulfurization of styrenes using a visible-light synthetic strategy in the absence of photocatalyst and oxidant was devoleped. This strategy provided the corresponding β-hydroxysulfides and β-alkoxysulfides in moderate to good yields with high regioselectivity. The reaction was tolerated by a wide range of functional groups. This is the first example of ArSSAr/CBr4 system was introduced into organic transformation. The experimental process involved the reaction of 1,2-Diphenyldisulfane(cas: 882-33-7Related Products of 882-33-7)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.The C-O bonds that comprise simple ethers are strong. Related Products of 882-33-7 They are unreactive toward all but the strongest bases. Although generally of low chemical reactivity, they are more reactive than alkanes.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《A paradigm shift for a new class of proton exchange membranes with ferrocyanide proton-conducting groups providing enhanced oxidative stability》 was written by Zhang, Xiangwen; Li, Yi; Liu, Xin; Zhang, Junfeng; Yin, Yan; Guiver, Michael D.. Synthetic Route of C10H20O5 And the article was included in Journal of Membrane Science in 2020. The article conveys some information:

A new class of proton exchange membranes (PEMs) containing ferrocyanide groups as both proton-conducting/radical scavenger components are fabricated. Here, the ferrocyanide groups are bonded to a com. fluoroelastomer polymer main chain, resulting in ferrocyanide-coordinated PEMs (CFC) for proton exchange membrane fuel cells (PEMFCs). The CFC PEMs show a larger hydrophilic morphol. phase than Nafion 212 membrane, even in the CFC having lower ion exchange capacity, owing to stronger electrostatic forces among ferrocyanide groups than traditional sulfonic groups. Compared with Nafion 212, CFC membranes present inferior proton conductivity in water. However, they show much lower activation energy for proton transport in water, and considerably higher proton conductivity than Nafion 212 under low relative humidity (RH). This is related to the larger hydrophilic domains that may construct better-connected channels for proton transport, especially at low membrane hydration levels. As a result, CFC membranes exhibit better power output than Nafion 212 in PEMFC evaluations under low RH conditions. The chem. accelerated stress test (AST) demonstrates that the radical scavenging ability of ferrocyanide group is effective for greatly reducing electrochem. oxidation The experimental process involved the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Synthetic Route of C10H20O5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Synthetic Route of C10H20O5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem