Month: November 2022

Catalytic pyrolysis of lignin using low-cost materials with different acidities and textural properties as catalysts was written by Han, Tong;Ding, Saiman;Yang, Weihong;Joensson, Paer. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2019.Formula: C9H12O3 The following contents are mentioned in the article:

Catalytic fast pyrolysis of lignin was performed using low-cost materials with different acidities and textural properties as catalysts in the present work. The main focus is to understand the role of low-cost catalysts in the fast pyrolysis of lignin. The four most commonly used low-cost catalysts, ilmenite (FeTiO₃), bentonite (Al-Si-OH), activated carbon (AC) and red mud (RM), were selected. The results show that bentonite, red mud and activated carbon effectively enhance the dehydration reaction, which is regarded as the dominant way to eliminate oxygen during the pyrolysis process, due to the existence of strong acidic sites. However, only activated carbon is found to be effective in promoting the production of monocyclic aromatic hydrocarbons (MAHs). Two metallic catalysts, i.e., bentonite and red mud, have strong acidities but quite low surface areas and less porous structures. Therefore, the dehydrated intermediates produced are especially easy to repolymerize to form char or coke without the restriction of obtaining a porous structure during the pyrolysis process. Activated carbon has not only a certain acidity but also a rich porous structure. Lignin fast pyrolysis-derived oxygenates can diffuse and react on the well-dispersed active sites within the pores of activated carbons. The catalytic performance of the activated carbon are supposed to be determined by the pore size. Only pores of similar size to lignin fast pyrolysis-derived oxygenates (0.6-1 nm) seems to be effective for the production of MAHs. Pores larger or smaller than lignin fast pyrolysis-derived oxygenates both tend to cause coke deposition rather than MAHs formation. This study involved multiple reactions and reactants, such as 4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1Formula: C9H12O3).

4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Formula: C9H12O3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Biodegradation of lignin and the associated degradation pathway by psychrotrophic Arthrobacter sp. C2 from the cold region of China was written by Jiang, Cheng;Cheng, Yi;Zang, Hailian;Chen, Xi;Wang, Yue;Zhang, Yuting;Wang, Jinming;Shen, Xiaohui;Li, Chunyan. And the article was included in Cellulose (Dordrecht, Netherlands) in 2020.Product Details of 2380-78-1 The following contents are mentioned in the article:

Degradation of most of the lignocellulose-rich agricultural residue in the cold regions of China is limited due to the cold climate. Lignin is the main component of lignocellulose, and the effective degradation of lignin is one of the most crucial processes in degrading lignocellulose. Psychrotrophic lignin-degrading bacteria and cold adapted ligninolytic enzymes have promising potential for the degradation and transformation of lignin, which are conducive to the resource utilization of lignocelluloses and energy-saving production under cold conditions. In this study, a newly psychrotrophic bacterial strain, Arthrobacter sp.C2, was isolated. The optimal enzyme activity conditions and lignin degradation pathways of C2 were investigated using sodium lignin sulfonate as substrate. The optimal conditions for enzyme activity included an initial pH of 6.74, a temperature of 14.9°C, an incubation time of 6.87 days, and an inoculum size of 2.24%. Under the optimal conditions, the lignin peroxidase and manganese peroxidase activities and the degradation rate reached 29.8 U/L, 56.4 U/L and 40.1%, resp. The biodegradation products including acids, phenols, aldehydes and alcs. were analyzed by gas chromatog.-mass spectrometry and Fourier transform IR spectroscopy. Further, the potential degradation pathways were proposed according to the results obtained in this study and those presented in the relevant literature. This study not only provides valuable psychrotrophic strain resources for the sustainable utilization of lignocellulose in cold regions, but also supplies potential application options for energy-saving production of useful chems. using cold adapted enzymes. This study involved multiple reactions and reactants, such as 4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1Product Details of 2380-78-1).

4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Product Details of 2380-78-1

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Microwave-assisted lignin liquefaction in hydrazine and ethylene glycol: Reaction pathways via response surface methodology was written by Nde, Divine B.;Barekati-Goudarzi, Mohamad;Muley, Pranjali D.;Khachatryan, Lavrent;Boldor, Dorin. And the article was included in Sustainable Materials and Technologies in 2021.Synthetic Route of C9H12O3 The following contents are mentioned in the article:

Microwave assisted liquefaction (MAL) of alkali lignin in ethylene glycol (EG) in the presence of hydrazine was carried out using response surface methodol. Dielec. properties of mixtures of lignin/EG at different hydrazine concentrations were determined to enhance the understanding of the MAL process. MAL parameters were hydrazine concentration (1-3%), temperature (100-180 °C), time (5-45 min) with the maximum microwave heating power limited to 750 W. Lignin/EG ratio was fixed at 1 g:10 mL. Dielec. properties were significantly influenced by hydrazine concentration and temperature Major products from the liquefaction process (as % of peak areas) were grouped into guaiacol and derivatives (17-42%), Nitrogen compounds (0-27%), and Hydroxylated products (8-22%), and their yields were modelled with polynomial equations. Product yields were significantly influenced by process parameters. Optimum parameters for maximizing yields of guaiacol and nitrogen containing compounds were 0.5%, 180 °C, 25 min and 2.5%, 130, 25 min for hydrazine concentration, temperature, and time, resp. Low hydrazine concentration increases guaiacol yield at higher temperatures, indicating that at high temperatures hydrazine behaves as a hydrogen donor for lignin liquefaction. The yield of nitrogen containing compounds increases at relatively low temperatures and high concentration of hydrazine. Apart from playing the resp. roles of liquefaction solvent and hydrogen donor, EG and hydrazine also take part in the reaction thereby significantly modifying the composition of reaction products. A mechanistic reaction mechanism was proposed to explain the formation of the liquefaction products. This study involved multiple reactions and reactants, such as 4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1Synthetic Route of C9H12O3).

4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Synthetic Route of C9H12O3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Intelligent detection of flavor changes in ginger during microwave vacuum drying based on LF-NMR was written by Sun, Yanan;Zhang, Min;Bhandari, Bhesh;Yang, Peiqiang. And the article was included in Food Research International in 2019.Category: ethers-buliding-blocks The following contents are mentioned in the article:

Low-field NMR (LF-NMR) and electronic nose combined with Gas chromatog. mass spectrometry (GC-MS) were used to collect the data of moisture state and volatile substances to predict the flavor change of ginger during drying. An back propagation artificial neural network (BP-ANN) model was established with the input values of LF-NMR parameters and the output values of sensors for different flavor substances obtained from electronic nose. The results showed that fresh ginger contained three water components: bound water (T₂₁), immobilized water (T₂₂) and free water (T₂₃), with the corresponding peak areas of A₂₁, A₂₂ and A₂₃, resp. During drying, the changes of A₂₁ and A₂₂ were not significant, while A₂₃ and A_Total decreased significantly (p < .05). Linear discriminant anal. (LDA) of electronic nose data showed that samples with different drying time can be well distinguished. Hierarchical clustering anal. (HCA) confirmed that the electronic nose characteristic sensor data S₄, S₅, S₈ and S₁₃ corresponded with the data measured by GC-MS. The correlation anal. between LF-NMR parameters and characteristic sensors showed that A₂₃ and A_Total were significantly correlated with the volatile components (p < .05). The results of the BP-ANN prediction showed that the model fitted well and had strong approximation ability (R > 0.95 and error < 3.65%) and stability, which indicated that the ANN model can accurately predict the flavor change during ginger drying based on LF-NMR parameters. This study involved multiple reactions and reactants, such as 4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1Category: ethers-buliding-blocks).

4-Hydroxy-3-methoxyphenethanol (cas: 2380-78-1) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: ethers-buliding-blocks

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In-silico Studies of the Antiproliferative Activity of New Anilinoquinazoline Derivatives Against NSCLC Cells. was written by Abdulwahab, Muhammad Kumayl;Tan, Ke Han;Dzulkeflee, Rashidi;Leong, Kok Hoong;Heh, Choon Han;Ariffin, Azhar. And the article was included in Journal of Molecular Structure in 2021.Reference of 109-85-3 The following contents are mentioned in the article:

The current reversible epidermal growth factor (EGFR) tyrosine kinase inhibitors of non-small cell lung cancer (NSCLC) have been resisted by T790M mutation, while the irreversible inhibitors introduced to overcome the mutation have faced resistance from C979S mutation. In the effort to discover potentially improved reversible EGFR inhibitors, a series of new anilinoquinazoline derivatives with modification on the 2^nd carbon on the aniline ring was synthesized. The derivatives were tested for their antiproliferative activity against NSCLC cell lines with wild-type (A549), exon 19 deletion mutated (H1650) and L858R+T790M (H1975) mutated EGFR kinases. Three derivatives (4-6) performed better than the standard drug, gefitinib, in all cell lines. Derivative 5 recorded the lowest IC₅₀ values in all cell lines (A549: 24.60 ± 0.75 μM, H1650: 14.83 ± 0.54 μM, H1975: 21.72 ± 1.21 μM). A mol. docking study followed by mol. dynamics simulations was performed on derivative 5 and gefitinib using wild-type EGFR kinase (WT-EGFR) and L858R+T790M mutated kinase (LRTM-EGFR) to provide an understanding of their binding mechanisms. In WT-EGFR kinase, derivative 5 recorded better hydrogen bonding occupancy with MET793 (94.16%) and binding energy profile (-35.287 kcal/mol) as compared to gefitinib (91.80%, -26.071 kcal/mol). In LRTM-EGFR kinase, derivative 5 recorded better hydrogen bonding occupancy with MET793 (93.68%) as compared to gefitinib (91.48%). Derivative 5 also recorded addnl. hydrogen bonding interactions with ASP855, with a total of 60.61% occupancy as well as a better energy profile (-42.867 kcal/mol) as compared to gefitinib (-41.778 kcal/mol). This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Reference of 109-85-3).

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Reference of 109-85-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Curcumin activates G protein-coupled receptor 97 (GPR97) in a manner different from glucocorticoid was written by Harada, Naoki;Arahori, Yumi;Okuyama, Mai;Luis, Paula B.;Joseph, Akil I.;Kitakaze, Tomoya;Goshima, Naoki;Schneider, Claus;Inui, Hiroshi;Yamaji, Ryoichi. And the article was included in Biochemical and Biophysical Research Communications in 2022.Reference of 33171-05-0 The following contents are mentioned in the article:

Curcumin is a yellow pigment in turmeric (Curcuma longa) with various physiol. effects in the body. To elucidate the mol. mechanisms by which bioactive compounds exert their function, identification of their mol. targets is crucial. In this study, we show that curcumin activates G protein-coupled receptor 97 (GPR97). Curcumin dose-dependently activated serum-response element-, but not serum-response factor-response element-, nuclear factor of activated T-cell-response element-, or cAMP-response element-, mediated transcription in cells overexpressed with GPR97. The structure-activity relationship indicated that (i) the double-bonds of the central 7-carbon chain were essential for activation; (ii) a methoxy group on the aromatic ring was required for maximal activity; (iii) the addition of glucuronic acid moiety or a methoxy group to the aromatic ring, but not the methylation of the aromatic p-hydroxy group, eliminated the activity; (iv) the stability of curcumin would be related to receptor activation. Both mutant GPR97(T250A) lacking the cleavage at GPCR proteolysis site and mutant GPR97(ΔN) lacking the N-terminal extracellular region were activated by curcumin and its related compounds similar to wild-type GPR97. In contrast, the synthetic glucocorticoid beclomethasone dipropionate and L-Phe activated wild-type GPR97 and GPR97(T250A), but not GPR97(ΔN). Moreover, curcumin exerted an additive effect on the activation of wild-type GPR97 with beclomethasone dipropionate, but not with L-Phe. Taken together, these results indicate that curcumin activates GPR97 coupled to Gi/Go subunit, and suggest that curcumin and glucocorticoid activate GPR97 in a different manner. This study involved multiple reactions and reactants, such as Bisdemethoxycurcumin (cas: 33171-05-0Reference of 33171-05-0).

Bisdemethoxycurcumin (cas: 33171-05-0) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Reference of 33171-05-0

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Curcuminoids Inhibit Angiogenic Behaviors of Human Umbilical Vein Endothelial Cells via Endoglin/Smad1 Signaling was written by Chou, Yi-Fan;Lan, Yu-Hsuan;Hsiao, Jun-Han;Chen, Chiao-Yun;Chou, Pei-Yu;Sheu, Ming-Jyh. And the article was included in International Journal of Molecular Sciences in 2022.Name: Bisdemethoxycurcumin The following contents are mentioned in the article:

Angiogenesis is primarily attributed to the excessive proliferation and migration of endothelial cells. Targeting the vascular endothelial growth factor (VEGF) is therefore significant in anti-angiogenic therapy. Although these treatments have not reached clin. expectations, the upregulation of alternative angiogenic pathways (endoglin/Smad1) may play a critical role in drug (VEGF-neutralizing agents) resistance. Enhanced endoglin expression following a VEGF-neutralizing therapy (semaxanib) was noted in patients. Treatment with an endoglin-targeting antibody augmented VEGF expression in human umbilical vein endothelial cells (HUVECs). Therefore, approaches that inhibit both the androgen and VEGF pathways enhance the HUVECs cytotoxicity and reverse semaxanib resistance. The purpose of this study was to find natural-occurring compounds that inhibited the endoglin-targeting pathway. Curcuminoids targeting endoglin were recognized from two thousand compounds in the Traditional Chinese Medicine Database@Taiwan (TCM Database@Taiwan) using Discovery Studio 4.5. Our results, obtained using cytotoxicity, migration/invasion, and flow cytometry assays, showed that curcumin (Cur) and demethoxycurcumin (DMC) reduced angiogenesis. In addition, Cur and DMC downregulated endoglin/pSmad1 phosphorylation. The study first showed that Cur and DMC demonstrated antiangiogenic activity via the inhibition of endoglin/Smad1 signaling. Synergistic effects of curcuminoids (i.e., curcumin and DMC) and semaxanib on HUVECs were found. This might be attributed to endoglin/pSmad1 downregulation in HUVECs. Combination treatment with curcuminoids and a semaxanib is therefore expected to reverse semaxanib resistance. This study involved multiple reactions and reactants, such as Bisdemethoxycurcumin (cas: 33171-05-0Name: Bisdemethoxycurcumin).

Bisdemethoxycurcumin (cas: 33171-05-0) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Name: Bisdemethoxycurcumin

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Natural Antioxidant Extracted Waste Cooking Oil as Sustainable Biolubricant Formulation in Tribological and Rheological Applications was written by Singh, Nisha;Agarwal, Priyanka;Porwal, Suheel K.. And the article was included in Waste and Biomass Valorization in 2022.Recommanded Product: 33171-05-0 The following contents are mentioned in the article:

Developing eco-friendly formulations using waste cooking oil as renewable biomass is of great interest and com. importance in the fuels and lubricant industry. This manuscript reports novel study on preparing a biolubricant formulations as WCO-1, WCO-2 and WCO-3 by blending the curcumin extracted soybean waste cooking oil in three different compositions viz 10%, 20%, 30% volume/volume with the mineral base oil N-150. Curcumin was extracted as a natural antioxidant in 0.5 wt% waste cooking oil to inhibit thermal oxidation This study comprises a detailed anal. in terms of tribol., rheol. and thermophys. characteristics such as viscosity, viscosity index, pour point and flash point parameters of the biolubricant by standard ASTM methods. Further, tribol. and rheol. anal. was done by the four-ball wear tester and Anton Paar, MCR-72, resp. The thermophys. evaluation of WCO formulated biolubricant has shown excellent properties. The viscosity index of the formulated biolubricant increases with an increase in the concentration of waste cooking oil. In contrast, the pour point has also been depressing at lower temperature conditions. Thus, WCO based biolubricant was found to be more effective at extreme temperature conditions than the mineral base oil (N-150). Rheol. studies have indicated the non-Newtonian behavior of the biolubricant with an increase in shear rate. Whereas, tribol. anal. demonstrates that wear scar diameter has significantly reduced from 0.685 to 0.573 mm, and the coefficient of friction decreased from 0.117 to 0.080 with respect to the mineral base oil. Thus, a straightforward green approach has been discovered by directly utilizing waste cooking oil for biolubricant formulation. This study involved multiple reactions and reactants, such as Bisdemethoxycurcumin (cas: 33171-05-0Recommanded Product: 33171-05-0).

Bisdemethoxycurcumin (cas: 33171-05-0) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Recommanded Product: 33171-05-0

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Customized facilitated transport membranes by mixed strategy for ethylene/ethane separation was written by Xu, Mi;Jiang, Bin;Dou, Haozhen;Yang, Na;Xiao, Xiaoming;Tantai, Xiaowei;Sun, Yongli;Zhang, Luhong. And the article was included in Separation and Purification Technology in 2021.Recommanded Product: 2-Methoxyethylamine The following contents are mentioned in the article:

Mixed strategy has been widely utilized to design novel membranes or tailor membrane structure, however the construction of facilitated transport membranes (FTMs) with mixed strategy has rarely been reported. In this work, eight kinds of mixed protic ionic liquid (MPIL) derived FTMs (MPIL-FTMs) were designed with mixed strategy for highly efficient ethylene/ethane separation by impregnating MPILs and ethylene transport carrier into porous support. The morphol. of MPIL-FTMs were characterized by SEM and AFM, and their mol. interactions were investigated by ¹H NMR, FTIR and DSC. The MPIL-FTMs exhibited long-term stability and various ethylene permeability-ethylene/ethane selectivity combinations, which indicated mixed strategy could easily customize the separation performances of MPIL-FTMs. Moreover, a fundamental law for mixed strategy was obtained that the two parent PILs with similar chem. structure and mol. interactions favored the synchronous improvement of C₂H₄ permeability and C₂H₄/C₂H₆ selectivity. For example, the C₂H₄ permeability of the [BA][Pyr][NO₃] derived MPIL-FTM reached up to 561.0 Barrer with improved C₂H₄/C₂H₆ selectivity of 26.7, which were superior to most of reported membranes, thus breaking through the ubiquitous trade-off effect. This study proves the mixed strategy is a promising platform for the design of high-performance FTMs as well as their structure modification, and the marriage of mixed strategy with diversity of ILs creates enormous opportunities to construct advanced membranes for energy-intensive gas separations This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Recommanded Product: 2-Methoxyethylamine).

2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 2-Methoxyethylamine

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Equilibrium Solubility Determination and Correlation of Monobenzone in Fifteen Monosolvents at a Series of Temperatures was written by Li, Rongrong;Wang, Wei;Chen, Xianlang;Chen, Hong;Bao, Huanhuan;Zhu, Yuwei;Zhao, Jia;Han, Deman. And the article was included in Journal of Chemical & Engineering Data in 2020.Reference of 103-16-2 The following contents are mentioned in the article:

This study reports the equilibrium solubility for monobenzone in methanol, ethanol, n-propanol, isopropanol, n-butanol, acetonitrile, Et acetate, acetone, 1,4-dioxane, cyclohexane, N,N-dimethylformamide (DMF), N-methyl-2-pyrrolidinone (NMP), n-hexane, n-octanol, and water that was determined by the isothermal method between 283.15 and 313.15 K under p = 101.1 kPa. The maximum value of monobenzone solubility was 0.6316 in mole fraction at 313.15 K dissolved in Et acetate, but the least data was achieved in water. The solubility of monobenzone increased with the rising temperature and the order followed in the 15 pure solvents was Et acetate (0.6316, 313.15 K) > 1,4-dioxane (0.4350, 313.15 K) > methanol (0.1356, 313.15 K) > acetonitrile (0.1247, 313.15 K) > (ethanol, isopropanol) > n-propanol (0.09942, 313.15 K) > n-butanol (0.08346, 313.15 K) > n-octanol (0.03546, 313.15 K) > cyclohexane (8.020×10^-3, 313.15 K) > n-hexane (3.133 x 10^-3, 313.15 K) > NMP (2.372 x 10^-4, 313.15 K) > DMF (1.145 x 10^-4, 313.15 K) > acetone (4.032 x 10^-5, 313.15 K) > water (3.019 x 10^-5, 313.15 K). There was no existence of processes such as solvation or polymorphic transformation during the entire experiment Several models covering the modified Apelblat, λh, Wilson, and non-random two-liquid models were applied to correlate and calculate monobenzone solubility data in fifteen monosolvents. Results showed that the modified Apelblat equation provided the best results with the exptl. ones. The largest relative average deviation and root-mean-square deviation were no more than ² and 1.81 x 10^-3, resp. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Reference of 103-16-2).

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Reference of 103-16-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem