Bolton, Roger’s team published research in Journal of the Chemical Society [Section] B: Physical Organic in | CAS: 2944-47-0

Journal of the Chemical Society [Section] B: Physical Organic published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Category: ethers-buliding-blocks.

Bolton, Roger published the artcileSulfuryl chloride as an electrophile. IV. Steric hindrance to activation by the methoxy-group, Category: ethers-buliding-blocks, the publication is Journal of the Chemical Society [Section] B: Physical Organic (1970), 1770-2, database is CAplus.

The rates of reactions of sulfuryl chloride with a number of aromatic ethers have been studied in chlorobenzene solution The additivity principle, which holds in a number of examples of this reactions, fails when 2 substituents are placed ortho to the methoxyl group in anisole. 2,3,4,6-Tetramethylanisole substitutes Cl at a similar rate to that of 3-methylanisole, its calculated rate coefficient being 2000 times the exptl. value. Neither increasing the size of the alkyl group attached to the O atom nor using only 1 ortho substituent brought about any detectable effect due to steric factors.

Journal of the Chemical Society [Section] B: Physical Organic published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Category: ethers-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Blanpin, Odette’s team published research in Anesthesie, Analgesie, Reanimation in 14 | CAS: 637-58-1

Anesthesie, Analgesie, Reanimation published new progress about 637-58-1. 637-58-1 belongs to ethers-buliding-blocks, auxiliary class Inhibitor, name is 4-(3-(4-Butoxyphenoxy)propyl)morpholine hydrochloride, and the molecular formula is C17H28ClNO3, Related Products of ethers-buliding-blocks.

Blanpin, Odette published the artcileThe local-anesthetic action of pramoxine hydrochloride (tronothane, Related Products of ethers-buliding-blocks, the publication is Anesthesie, Analgesie, Reanimation (1957), 225-31, database is CAplus.

Pramoxine (or tronothane) is p-butoxyphenyl morpholinopropyl ether-HCl (I). Its pharmacol. properties and toxicity are reported. L.D.50 (intravenous injection into caudal vein of the mouse) 132 mg./kg.; L.D.min. (slow intravenous infusion in guinea pigs) 108.7 ± 2.3 mg./kg.; L.D.50 (subcutaneous injection into the mouse) 1.47 g./kg. A 1% solution of I was used to determine its local tolerance (in the eye of a rabbit) and its effectiveness as a local anesthetic (also on rabbits). I was found to be 3.6 times as effective as cocaine-HCl when used as a local anesthetic on the skin surface and 1.5 times as effective as procaine-HCl (II) in infiltration tests on guinea pigs. In tests determining the reduction of the excitability of a frog muscle preparation (sciatic nerve to the gastrocnemius muscle in Ringer solution, pH 6) a 0.10% solution of I had about the same effect as a 0.01% solution of II. I is, therefore, an excellent surface anesthetic, but its use in eye surgery must be rigorously avoided because of its property of producing necrosis of the mucous membrane and muscle fibers.

Anesthesie, Analgesie, Reanimation published new progress about 637-58-1. 637-58-1 belongs to ethers-buliding-blocks, auxiliary class Inhibitor, name is 4-(3-(4-Butoxyphenoxy)propyl)morpholine hydrochloride, and the molecular formula is C17H28ClNO3, Related Products of ethers-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Baliah, V.’s team published research in Journal of the Indian Chemical Society in 70 | CAS: 2944-47-0

Journal of the Indian Chemical Society published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Recommanded Product: 2-Isopropylanisole.

Baliah, V. published the artcileEvidence for steric enhancement of resonance in 2-alkylanisoles from 13C NMR T1 relaxation times of methoxy-carbons and from atomic charges on methoxy-oxygens, Recommanded Product: 2-Isopropylanisole, the publication is Journal of the Indian Chemical Society (1993), 70(10), 841-2, database is CAplus.

The title study of MeOC6H4R-2 (R = H, alkyl) and MeOC6H3R1R2-2,6 (R1 = R2 = alkyl) confirmed the steric enhancement of resonance in these compounds

Journal of the Indian Chemical Society published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Recommanded Product: 2-Isopropylanisole.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Baerncopf, Jamie’s team published research in Forensic Science International in 312 | CAS: 93-04-9

Forensic Science International published new progress about 93-04-9. 93-04-9 belongs to ethers-buliding-blocks, auxiliary class Naphthalene,Ether, name is 2-Methoxynaphthalene, and the molecular formula is C11H10O, Quality Control of 93-04-9.

Baerncopf, Jamie published the artcilePrevalence of ignitable liquids in clothing with printing, Quality Control of 93-04-9, the publication is Forensic Science International (2020), 110312, database is CAplus and MEDLINE.

In this study, 141 shirts were evaluated to determine the prevalence of ignitable liquids in printed shirts. Both new and worn shirts were included in this study. Volatile components extracted from the shirts were noted and many of the most commonly encountered components could be contributed to human skin or laundry, personal hygiene, or personal care products. Volatile components that are known to be present in ignitable liquids were also identified, including toluene, C2-alkylbenzenes, and normal alkanes. An aromatic pattern consisting of toluene, C2-alkylbenzenes, and sometimes extending to the C3-alkylbenzenes or beyond was observed in 41% of the shirts in this study. This pattern was mainly visible in the aromatic extracted ion profile, though it was clearly identifiable in some total ion chromatograms. This high occurrence suggests that a caveat should be used if identifying an aromatic product in a clothing item with printing. Though several shirts showed multiple sequential n-alkanes, only one had a petroleum pattern that would be considered for identification.

Forensic Science International published new progress about 93-04-9. 93-04-9 belongs to ethers-buliding-blocks, auxiliary class Naphthalene,Ether, name is 2-Methoxynaphthalene, and the molecular formula is C11H10O, Quality Control of 93-04-9.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Zhang, Miao’s team published research in AIChE Journal in 67 | CAS: 1589-47-5

AIChE Journal published new progress about 1589-47-5. 1589-47-5 belongs to ethers-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ether, name is 2-Methoxypropan-1-ol, and the molecular formula is C4H8Cl2S2, Application In Synthesis of 1589-47-5.

Zhang, Miao published the artcileKinetics simulation of propylene epoxidation over different Ti species in TS-1, Application In Synthesis of 1589-47-5, the publication is AIChE Journal (2021), 67(8), e17261, database is CAplus.

A thorough exptl. investigation on the kinetic behavior of liquid-phase propylene epoxidation over TS-1 and tetrapropylammonium hydroxide (TPAOH) treated TS-1 catalysts was conducted in a fixed-bed reactor. The amounts of different coordinated Ti species in the catalysts were quantified by spectroscopies, and their catalytic performances of the epoxidation and alcoholysis of propylene oxide were measured by kinetic modeling. The study shows that the TPAOH treatment converted some of the tetrahedrally coordinated Ti to octahedrally coordinated Ti, and both species were active for the epoxidation and alcoholysis. The superior catalytic performance observed over the TPAOH treated TS-1 is due to two factors, the increased percentage of active sites, and reduced energy barrier for epoxidation on the octahedrally coordinated Ti. In addition, as the H2O2 conversion increases, the adsorption equilibrium constant of propylene oxide plays a more decisive role than the activation energy for the selectivity of propylene glycol monomethyl ethers.

AIChE Journal published new progress about 1589-47-5. 1589-47-5 belongs to ethers-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ether, name is 2-Methoxypropan-1-ol, and the molecular formula is C4H8Cl2S2, Application In Synthesis of 1589-47-5.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Plavich, M. L.’s team published research in Elektronnaya Promyshlennost in | CAS: 146370-51-6

Elektronnaya Promyshlennost published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Application of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene.

Plavich, M. L. published the artcileTechnologies for preparation of stable monochrome displays based on organic electroluminescent materials, Application of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, the publication is Elektronnaya Promyshlennost (2004), 101-108, database is CAplus.

OLEDs were prepared consisting of an ITO anode, PNAB hole-transport layer, organic luminophor [e.g., Alq3 or poly(phenylenevinylenes)], and two-layer cathode comprising an Al/Ca alloy (≤10% Ca) and a pure Al layer. Current-voltage (5-6 V threshold) and intensity-current relationships were given.

Elektronnaya Promyshlennost published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Application of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Plavich, M. L.’s team published research in Zhurnal Nauchnoi i Prikladnoi Fotografii in 48 | CAS: 146370-51-6

Zhurnal Nauchnoi i Prikladnoi Fotografii published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Product Details of C15H24O2.

Plavich, M. L. published the artcileInformation display devices based on organic luminophors, Product Details of C15H24O2, the publication is Zhurnal Nauchnoi i Prikladnoi Fotografii (2003), 48(3), 52-60, database is CAplus.

The development and properties of light-emitting devices based on the organic luminophors have been studied in the State Research University of Phys. Problems named after F.V. Lukin for more than 7 yr. The development of such devices is a relatively new field of optoelectronics, and some problems which encountered in this field are discussed in the present paper. The description of matrix monochrome indicator having 16×16 pixels size based on the recent studies is given. Exptl. elec. current-potential relationships and elec. current-brightness relationships for different light-emitting materials are considered.

Zhurnal Nauchnoi i Prikladnoi Fotografii published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Product Details of C15H24O2.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Homann, Julia’s team published research in ChemElectroChem in 9 | CAS: 134-96-3

ChemElectroChem published new progress about 134-96-3. 134-96-3 belongs to ethers-buliding-blocks, auxiliary class Immunology/Inflammation,COX,Natural product, name is 4-Hydroxy-3,5-dimethoxybenzaldehyde, and the molecular formula is C9H10O4, Computed Properties of 134-96-3.

Homann, Julia published the artcileDevelopment of a Method for Anodic Degradation of Lignin for the Analysis of Paleo-Vegetation Proxies in Speleothems, Computed Properties of 134-96-3, the publication is ChemElectroChem (2022), 9(6), e202101312, database is CAplus.

Here we present an electrochem. method for the anodic oxidation and subsequent degradation of lignin in speleothems to utilize the resulting lignin oxidation products (LOPs) as paleo-vegetation markers. LOPs were analyzed using an ultra-high performance liquid chromatog. (UHPLC) system coupled to a high-resolution mass spectrometer (HRMS). The method presented here achieved comparable or even higher LOP concentrations than established CuO and CuSO4 oxidation methods. The method represents a new tool for the anal. and reconstruction of paleo-vegetation and has the potential to be applied to other climate archives.

ChemElectroChem published new progress about 134-96-3. 134-96-3 belongs to ethers-buliding-blocks, auxiliary class Immunology/Inflammation,COX,Natural product, name is 4-Hydroxy-3,5-dimethoxybenzaldehyde, and the molecular formula is C9H10O4, Computed Properties of 134-96-3.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Dai, Guohua’s team published research in Soil Biology & Biochemistry in 168 | CAS: 134-96-3

Soil Biology & Biochemistry published new progress about 134-96-3. 134-96-3 belongs to ethers-buliding-blocks, auxiliary class Immunology/Inflammation,COX,Natural product, name is 4-Hydroxy-3,5-dimethoxybenzaldehyde, and the molecular formula is C9H10O4, Formula: C9H10O4.

Dai, Guohua published the artcilePlant-derived lipids play a crucial role in forest soil carbon accumulation, Formula: C9H10O4, the publication is Soil Biology & Biochemistry (2022), 108645, database is CAplus.

Plant and microbial residues are two main sources of soil organic carbon (SOC). While recent studies have extensively examined the distribution of microbial necromass in different ecosystems, how plant residues (in particular, non-lignin components) contribute to SOC accumulation is less clear, especially in forests which make up 50% of the global soil carbon storage. Filling this knowledge gap will help us better understand SOC accumulation patterns and their response to land-use changes. Here, we analyze plant- and microbial-derived biomarkers (including lignin phenols, amino sugars, free and hydrolysable lipids) in the topsoil of major forest types in China and compare their distribution patterns together with the existing data (for lignin phenols and amino sugars) in forests and grasslands distributed globally. At the global scale, forests contain significantly less microbial necromass in SOC compared with grasslands, suggesting higher contribution of plant-derived components to forest SOC. However, plant-derived lignin phenols do not seem to play a major role in SOC accumulation, given their neg. relationship with SOC contents. Instead, leaf- and root-derived hydrolysable lipids constitute a much higher proportion of SOC than lignin phenols in the investigated forests of China, even compared to grassland soils. Moreover, in contrast to lignin phenols, both SOC contents and the relative abundance of hydrolysable plant lipids in SOC increase with decreasing soil pH, increasing reactive iron and aluminum contents and with increasing lignin oxidation (indicated by acid-to-aldehyde ratios) in these forest soils. These results suggest that with increasing lignin decomposition, plant lipids and SOC accumulated via (oxyhydr)oxide protection. Collectively, our results demonstrate differential importance of plant-derived components in SOC accumulation in forests vs. grasslands and highlight that plant lipids play a more important part than lignin in forest SOC accumulation. Quant. investigations on the distribution of plant-derived lipids in addition to lignin in forest soils may help to elucidate pathways and hotspots of plant component-dominated SOC accrual.

Soil Biology & Biochemistry published new progress about 134-96-3. 134-96-3 belongs to ethers-buliding-blocks, auxiliary class Immunology/Inflammation,COX,Natural product, name is 4-Hydroxy-3,5-dimethoxybenzaldehyde, and the molecular formula is C9H10O4, Formula: C9H10O4.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Wu, Jing’s team published research in Journal of Enzyme Inhibition and Medicinal Chemistry in 37 | CAS: 6850-57-3

Journal of Enzyme Inhibition and Medicinal Chemistry published new progress about 6850-57-3. 6850-57-3 belongs to ethers-buliding-blocks, auxiliary class Amine,Benzene,Ether, name is (2-Methoxyphenyl)methanamine, and the molecular formula is C8H11NO, COA of Formula: C8H11NO.

Wu, Jing published the artcileDiscovery of novel paeonol-based derivatives against skin inflammation in vitro and in vivo, COA of Formula: C8H11NO, the publication is Journal of Enzyme Inhibition and Medicinal Chemistry (2022), 37(1), 817-831, database is CAplus and MEDLINE.

In this study, a series of paeonol derivatives I [R = NHMe, PhNH, BnNH, etc.] was designed and synthesized using a fragment growing approach, and their anti-inflammatory activities against lipopolysaccharide (LPS)-induced nitric oxide production in RAW264.7 cells were tested. Among them, compound I [R = 3-CF3C6H4NH] yielded the best results (IC50 = 2.14μM) with low toxicity (IC50 > 50μM). Preliminary mechanistic studies indicated that this compound could inhibit the TOPK-p38/JNK signalling pathway and phosphorylate downstream related proteins. A murine psoriasis-like skin inflammation model was used to determine its therapeutic effect.

Journal of Enzyme Inhibition and Medicinal Chemistry published new progress about 6850-57-3. 6850-57-3 belongs to ethers-buliding-blocks, auxiliary class Amine,Benzene,Ether, name is (2-Methoxyphenyl)methanamine, and the molecular formula is C8H11NO, COA of Formula: C8H11NO.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem