Bolton, Roger’s team published research in Journal of the Chemical Society [Section] B: Physical Organic in | CAS: 2944-47-0

Journal of the Chemical Society [Section] B: Physical Organic published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Category: ethers-buliding-blocks.

Bolton, Roger published the artcileSulfuryl chloride as an electrophile. IV. Steric hindrance to activation by the methoxy-group, Category: ethers-buliding-blocks, the publication is Journal of the Chemical Society [Section] B: Physical Organic (1970), 1770-2, database is CAplus.

The rates of reactions of sulfuryl chloride with a number of aromatic ethers have been studied in chlorobenzene solution The additivity principle, which holds in a number of examples of this reactions, fails when 2 substituents are placed ortho to the methoxyl group in anisole. 2,3,4,6-Tetramethylanisole substitutes Cl at a similar rate to that of 3-methylanisole, its calculated rate coefficient being 2000 times the exptl. value. Neither increasing the size of the alkyl group attached to the O atom nor using only 1 ortho substituent brought about any detectable effect due to steric factors.

Journal of the Chemical Society [Section] B: Physical Organic published new progress about 2944-47-0. 2944-47-0 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 2-Isopropylanisole, and the molecular formula is C10H14O, Category: ethers-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem