Category: 33100-27-5

Park, Sanghwan; Kim, Yun-Tae; Min, Hyegi; Moon, Seung Min; Lee, Seongwoo; Lee, Chang Young published their research in ACS Applied Materials & Interfaces in 2021. The article was titled 《Alkalide-Assisted Direct Electron Injection for the Noninvasive n-Type Doping of Graphene》.Application of 33100-27-5 The article contains the following contents:

Although the doping of graphene grown by chem. vapor deposition is crucial in graphene-based electronics, noninvasive methods of n-type doping have not been widely investigated in comparison with p-type doping methods. We developed a convenient and robust method for the noninvasive n-type doping of graphene, wherein electrons are directly injected from sodium anions into the graphene. This method involves immersing the graphene in solutions of [K(15-crown-5)2]Na prepared by dissolving a sodium-potassium (NaK) alloy in a 15-crown-5 solution The n-type doping of the graphene was confirmed by downshifted G and 2D bands in Raman spectra and by the Dirac point shifting to a neg. voltage. The electron-injected graphene showed no sign of structural damage, exhibited higher carrier mobilities than that of pristine graphene, and remained n-doped for over a month of storage in air. In addition, we demonstrated that electron injection enhances noncovalent interactions between graphene and metallomacrocycle mols. without requiring a linker, as used in previous studies, suggesting several potential applications of the method in modifying graphene with various functionalities. After reading the article, we found that the author used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application of 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application of 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Physical Chemistry Chemical Physics included an article by Lopez, Juan C.; Perez, Cristobal; Blanco, Susana; Shubert, V. Alvin; Temelso, Berhane; Shields, George C.; Schnell, Melanie. Recommanded Product: 1,4,7,10,13-Pentaoxacyclopentadecane. The article was titled 《Water induces the same crown shapes as Li+ or Na+ in 15-crown-5 ether: a broadband rotational study》. The information in the text is summarized as follows:

15-Crown-5 ether (15C5) and its complexes with water have been studied using broadband Fourier transform microwave spectroscopy in a supersonic jet. A new conformer of 15C5 has been observed and established as the new global min. out of a total of nine isolated structures. In addition, two 15C5-H2O and two 15C5-(H2O)2 clusters have been observed The cluster structures have been unambiguously identified through the observation of water 18O isotopologue spectra. In all the clusters, at least one water mol., located close to the axis of the 15C5 ring, interacts through two simultaneous hydrogen bonds to the endocyclic oxygen atoms. This interaction reshapes the 15C5 ring to reduce its rich conformational landscape to only two open structures, related to those found in complexes with Li+ or Na+ ions. In the most abundant 15C5-(H2O)2 form, the two water mols. repeat the same interaction scheme while binding to opposite sides of the ring. In the second most abundant dihydrated form the two water mols. lie on the same side of the ring. This finding is exceptionally rare because water-water interactions typically prevail over the formation of addnl. solute-water contacts, and it showcases the particular binding features of crown ethers. In the part of experimental materials, we found many familiar compounds, such as 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Recommanded Product: 1,4,7,10,13-Pentaoxacyclopentadecane)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Recommanded Product: 1,4,7,10,13-Pentaoxacyclopentadecane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Weirich, Luisa; Merten, Christian published their research in Physical Chemistry Chemical Physics in 2021. The article was titled 《Induced VCD and conformational chirality in host-guest complexes of a chiral ammonium salt with crown ethers》.Name: 1,4,7,10,13-Pentaoxacyclopentadecane The article contains the following contents:

The hydrogen bonded complexes of the chiral ammonium salt α-methylbenzyl ammonium chloride (MBA-H+Cl-) and the achiral crown ethers 18c6 and 15c5 serve as model systems to investigate the effect of host-guest complex formation on the conformational preferences of the macrocycles. We demonstrate that the intermol. interactions result in new VCD signatures, that can be assigned to vibrational modes of the crown ethers. Based on a detailed conformational anal., we investigate the origin of these signatures and discuss induced VCD (iVCD) and conformational chirality as possible sources of VCD intensity. The macrocycle in the MBA-H+/18c6 complex prefers either an achiral D3d-sym. conformation, which gives rise to iVCD, or chiral conformations, that feature individual contributions to the VCD spectrum. For the MBA-H+/15c5 complex, the contributions of the macrocycle to the VCD signatures are less pronounced and found to arise solely from conformational chirality. Therefore, anal. of the VCD signatures confirms that the small chiral guest mol. is able to affect the conformational preferences of a macrocyclic host. The study thus demonstrates the suitability of VCD spectroscopy for the characterization of analogous supramol. host-guest complexes. The results came from multiple reactions, including the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Name: 1,4,7,10,13-Pentaoxacyclopentadecane)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Name: 1,4,7,10,13-Pentaoxacyclopentadecane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

McKee, Nida A.; McKee, Michael L. published their research in Physical Chemistry Chemical Physics in 2021. The article was titled 《Evaluation of packing single and multiple atoms and molecules in the porous organic cage CC3-R》.Application of 33100-27-5 The article contains the following contents:

The absorption of multiple atoms and mols., including Kr, Xe, CH4, CO2, C2H2, H2O, and SF6, within CC3-R, a Porous Organic Cage (POC), was calculated and analyzed. The CC3-R mol. has one central cavity and four window sites. Most adsorbents were modeled with either one unit in the central cavity, four units in the window sites, or with five units in both sites. For Xe, the most favorable site was the central one. The CO2 mol. binds about 3 kcal mol-1 in free energy more strongly than CH4 in the central cavity of CC3-R at 300 K which may be enough to allow useful discrimination. Four C2H2 units and four CO2 units are calculated to bind similarly inside CC3-R (ΔH(298 K) = -8.6 and -7.7 kcal mol-1 per unit, resp.). Since H2O is smaller, more waters can easily fit inside. For twelve water mols., the binding enthalpy per water is ΔH(298 K) = -16.4 kcal mol-1. For comparison, the binding enthalpy of (H2O)12 at the same level of theory (B3LYP/6-31G(d,p)-D3BJ//M06-2X/6-31G(d)) is predicted to be -12.3 kcal mol-1 per water. Finally, the dimerization of CC3-R and the association of CC3-R with CC3-S was studied as well as 3 to 9 iodine atoms enclosed in CC3-R. In addition to this study using 1,4,7,10,13-Pentaoxacyclopentadecane, there are many other studies that have used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application of 33100-27-5) was used in this study.

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application of 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Chemistry – A European Journal included an article by Schwarz, Christopher; Scharf, Lennart T.; Scherpf, Thorsten; Weismann, Julia; Gessner, Viktoria H.. Application In Synthesis of 1,4,7,10,13-Pentaoxacyclopentadecane. The article was titled 《Isolation of the Metalated Ylides [Ph3P-C-CN]M (M = Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation》. The information in the text is summarized as follows:

The isolation and structural characterization of the cyanido-substituted metalated ylides [Ph3P-C-CN]M (1-M; M = Li, Na, K) are reported with lithium, sodium, and potassium as metal cations. In the solid-state, most different aggregates could be determined depending on the metal and addnl. Lewis bases. The crown-ether complexes of sodium (1-Na) and potassium (1-K) exhibited different structures, with sodium preferring coordination to the nitrogen end, whereas potassium binds in an unusual η2-coordination mode to the two central carbon atoms. The formation of the yldiide was accompanied by structural changes leading to shorter C-C and longer C-N bonds. This could be attributed to the delocalization of the free electron pairs at the carbon atom into the antibonding orbitals of the CN moiety, which was confirmed by IR spectroscopy and computational studies. Detailed d. functional theory calculations show that the changes in the structure and the bonding situation were most pronounced in the lithium compounds due to the higher covalency. In the experiment, the researchers used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application In Synthesis of 1,4,7,10,13-Pentaoxacyclopentadecane)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application In Synthesis of 1,4,7,10,13-Pentaoxacyclopentadecane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Isolation of cyclic penta(ethylene oxide) from mixtures with its linear analog by combining selective intercalation into graphite oxide and solvent approaches》 were Ruiz, Daniel; Alegria, Angel; Barroso-Bujans, Fabienne. And the article was published in Separation and Purification Technology in 2019. Recommanded Product: 33100-27-5 The author mentioned the following in the article:

Cyclic oligomers of poly(ethylene oxide)s intercalate slower into graphite oxide (GO) than their linear analogs from the melt. In present study these kinetic differences are exploited to isolate 15-crown-5 (15C5) from mixtures with linear penta(ethylene glycol) (5EG) by using 2 approaches: (a) melt intercalation and solvent extraction and (b) intercalation from solution and filtration. In both cases fractions highly enriched in the cyclic component are obtained by using an appropriate selection of the solvent. Solvents that do not penetrate the interlayer space of GO (such as CCl4 and toluene) increases the cyclic fraction from 50% in the initial mixture to values ≤99%. On the contrary, solvents that penetrate the interlayer space of GO produce fractions with low content of 15C5. The ability of nonpenetrating solvents to achieve an effective isolation of 15C5 demonstrates that separation is driven by a faster intercalation of 5EG into unswollen GO, without solvent assistance, and the permanence of 15C5 in solution These results are discussed in the light of data collected by x-ray diffraction, DSC and gel permeation chromatog. This study provides substantial evidence of a very promising separation method for a topol. purification of cyclic poly(ethylene oxide)s with GO. In the part of experimental materials, we found many familiar compounds, such as 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Recommanded Product: 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Recommanded Product: 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Ke, Quanli; Khalil, Ibrahim; Smeyers, Brent; Li, Zheng; de Oliveira-Silva, Rodrigo; Sels, Bert; Sakellariou, Dimitrios; Dusselier, Michiel published their research in Angewandte Chemie, International Edition in 2021. The article was titled 《A Cooperative OSDA Blueprint for Highly Siliceous Faujasite Zeolite Catalysts with Enhanced Acidity Accessibility》.Computed Properties of C10H20O5 The article contains the following contents:

A cooperative OSDA strategy is demonstrated, leading to novel high-silica FAU zeolites with a large potential for disruptive acid catalysis. In bottom-up synthesis, the symbiosis of choline ion (Ch+) and 15-crown-5 (CE) was evidenced, in a form of full occupation of the sodalite (sod) cages with the trans Ch+ conformer, induced by the CE presence. CE itself occupied the supercages along with addnl. gauche Ch+, but in synthesis without CE, no trans was found. The cooperation, and thus the fraction of trans Ch+, was closely related to the Si/Al ratio, a key measure for FAU stability and acidity. As such, a bottom-up handle for lowering the Al-content of FAU and tuning its acid site distribution is shown. A mechanistic study demonstrated that forming sod cages with trans Ch+ is key to the nucleation of high-silica FAU zeolites. The materials showed superior performances to com. FAU zeolites and those synthesized without cooperation, in the catalytic degradation of polyethylene. In the experiment, the researchers used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Computed Properties of C10H20O5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Computed Properties of C10H20O5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Li, Zezhong John; Srebnik, Simcha published their research in Physical Chemistry Chemical Physics in 2021. The article was titled 《Expanding carbon capture capacity: uncovering additional CO2 adsorption sites in imine-linked porous organic cages》.Related Products of 33100-27-5 The article contains the following contents:

With an increasing need to develop carbon capture technologies, research regarding the use of cage-based porous materials has garnered great interest. Typically, the study of gas adsorption in porous organic cages (POCs) has focused on the gas uptake inside the cage cavity. By using mol. dynamics simulation, this study reveals the presence of eight sites outside the cavity of a 15-crown-5 ether-substituted imine-linked POC which could enhance carbon dioxide adsorption capacity. Adsorption on these sites is likely stabilized by the functional groups on the cage vertices and the imine groups on the faces of the POC. These external adsorption sites have a higher CO2 adsorption capacity and greater sensitivity to temperature and pressure changes than the sites within the cage cavity. These characteristics are particularly favorable for applications based on pressure- and temperature-swing separation In the experimental materials used by the author, we found 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Related Products of 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Related Products of 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Application of 33100-27-5In 2020 ,《An electrospray ionization mass spectrometric study of beryllium chloride solutions and complexes with crown ether and cryptand macrocyclic ligands》 appeared in Journal of Coordination Chemistry. The author of the article were Raymond, Onyekachi; Henderson, William; Lane, Joseph R.; Brothers, Penelope J.; Plieger, Paul G.. The article conveys some information:

The speciation of beryllium chloride solutions was studied using electrospray ionization mass spectrometry in both pos. and neg. ion modes. The majority of observed species were mixed beryllium-chlorido-oxido-hydroxido species, with the degree of hydration of the observed ions depending on the number of chloride ions. The observed species contain between 1 and 6 Be ions. The interactions of BeCl2 with a selection of crown ether ligands and cryptand[2.2.2] were also studied using ESI MS. These ligands have low affinity for Be2+, instead the observed ions are dominated by species formed from adventitious Na+ or K+ ions. The crown ether 12-crown-4 showed the most complex spectra, as a result of greater interactions with Be2+, as evidenced by observed ions such as [BeX(12-crown-4)]+ (X = Cl or OH). The interactions of crown ethers with beryllium ions (as well as coordinated Cl- or OH- ancillary ligands) were studied using D. Functional Theory [B3LYP/6-311++G(dp)], where the species [BeX(crown ether)]+ (X = Cl or OH) are considerably more stable than [Be(crown ether)]2+ species, with 12-crown-4 forming the most stable complex. The combination of ESI MS and DFT studies indicates that full encapsulation of the Be2+ by crown ethers is unfavorable, and coordination with an accompanying hydroxide or chloride is preferred. The results came from multiple reactions, including the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application of 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application of 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Huang, Xianli; Zhuang, Dongmei; Chen, Zhihui; Gong, Hao; Wang, Tao; He, Jianping; Zhang, Xiaogang published their research in Journal of Electroanalytical Chemistry in 2021. The article was titled 《The investigation for electrodeposition behavior of lithium metal in a crown ether/propylene carbonate electrolyte》.Recommanded Product: 33100-27-5 The article contains the following contents:

It is so far an efficient way for depressing dendrite growth to adjust the electrolyte composition Therefore, the authors study the electrochem. behavior of Li metal electrodeposited in a LiPF6-propylene carbonate (PC) electrolyte by adding two kinds of crown ether. The effect of crown ether concentration on the Coulombic efficiency of Li electrodes has be evaluated, and the electrodeposition behavior of Li metal on neg. electrode has be analyzed by cyclic voltammetric curve, electrodeposition curve and Li metal deposition morphol. A certain amount of crown ether (15-crown-5 and 12-crown-4) can preferentially coordinate with Li ion in the electrolyte and form complex compounds, which reduce the Li ions concentration in the hot spot and level the Li electrode greatly by inhibiting the preferential growth of Li dendrite. A uniform and dense nano-columnar Li layer could be obtained at the c.d. of 2.0 mA cm-2 when the deposition amount is 1.0 mAh cm-2, and the concentration of 15-crown-5 and 12-crown-4 ether are 0.3M and 0.2M, resp. Gaussian calculation results show that the Li-crown complex has a relatively lower lowest unoccupied mol. orbit (LUMO), where electrons could be injected during the charging process, leading to decreased Coulombic efficiency. In the experiment, the researchers used many compounds, for example, 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Recommanded Product: 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Recommanded Product: 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem