Category: 33100-27-5

Gamez, Francisco; Aviles-Moreno, Juan R.; Berden, Giel; Oomens, Jos; Martinez-Haya, Bruno published their research in Physical Chemistry Chemical Physics in 2021. The article was titled 《Proton in the ring: spectroscopy and dynamics of proton bonding in macrocycle cavities》.Reference of 1,4,7,10,13-Pentaoxacyclopentadecane The article contains the following contents:

The proton bond is a paradigmatic quantum mol. interaction and a major driving force of supramol. chem. The ring cavities of crown ethers provide an intriguing environment, promoting competitive proton sharing with multiple coordination anchors. This study shows that protons confined in crown ether cavities form dynamic bonds that migrate to varying pairs of coordinating atoms when allowed by the flexibility of the macrocycle backbone. Prototypic native crown ethers (12-crown-4, 15-crown-5 and 18-crown-6) and aza-crown ethers (cyclen, 1-aza-18-crown-6 and hexacyclen) are investigated. For each system, IR action spectroscopy experiments and ab initio Mol. Dynamics computations are employed to elucidate the structural effects associated with proton diffusion and its entanglement with the conformational and vibrational dynamics of the protonated host. The experimental part of the paper was very detailed, including the reaction process of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Reference of 1,4,7,10,13-Pentaoxacyclopentadecane)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Reference of 1,4,7,10,13-Pentaoxacyclopentadecane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Empirical Models of Stability of Crown Ether Complexes with Alkaline and Alkaline-Earth Metals in Selected Pure Solvents》 was published in Russian Journal of General Chemistry in 2020. These research results belong to Bondarev, N. V.. Product Details of 33100-27-5 The article mentions the following:

An approach to predict the stability constants of coronates from the properties of solvents, cations, and crown ethers has been developed based on exploratory and neural network methods for math. modeling of equilibrium in solutions Exploratory (factor, cluster, discriminant, canonical, decision trees), regression, and neural network (supervised and Kohonen network) models of the stability of crown ethers (12C4, 13C4, 14C4, 15C4, 15C5, 18C6, 21C7, 24C8, B12C4, B15C5, CH15C5, CH18C6, DCH18C6, DCH21C7, DB18C6, DB21C7, DB24C8, DB27C9, and DB30C10) complexes with cations of alkali (Li+, Na+, K+, Cs+, Rb+) and alk.-earth (Ca2+, Sr2+, Ba2+) metals in aqueous and non-aqueous (acetone, acetonitrile, DMSO, methanol, pyridine, DMF, dioxane, propylene carbonate, 1,2-dichloroethane, and nitrobenzene) solutions have been developed according to the properties of solvents (diameter of solvent mol., Kamlet-Taft parameter, Dimroth-Reichardt parameter, dielec. constant), crown ethers (Balaban topol. index), and cations (cation diameter) at 298.15 K.1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Product Details of 33100-27-5) was used in this study.

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Product Details of 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Angewandte Chemie, International Edition included an article by Aota, Yusuke; Kano, Taichi; Maruoka, Keiji. Reference of 1,4,7,10,13-Pentaoxacyclopentadecane. The article was titled 《Asymmetric Synthesis of Chiral Sulfoximines through the S-Alkylation of Sulfinamides》. The information in the text is summarized as follows:

Innovation in drug discovery critically depends on the development of new bioisosteric groups. Chiral sulfoximines, which contain a tetrasubstituted sulfur atom that bears one nitrogen, one oxygen, and two different carbon substituents, represent an emerging chiral bioisostere in medicinal chem. Chiral sulfoximines are conventionally prepared by a stereospecific nitrene transfer reaction to chiral sulfoxides; however, the number of readily available chiral sulfoxides remains limited. Herein, we report the asym. synthesis of a class of hitherto difficult-to-access chiral sulfoximines with two structurally similar alkyl chains. Our synthetic approach is based on the sulfur-selective alkylation of easily accessible chiral sulfinamides with com. available reagents under simple and safe conditions. This stereospecific S-alkylation offers a general and scalable approach to the asym. synthesis of chiral sulfoximines, which represent important substructures in bioactive mols. The experimental part of the paper was very detailed, including the reaction process of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Reference of 1,4,7,10,13-Pentaoxacyclopentadecane)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Reference of 1,4,7,10,13-Pentaoxacyclopentadecane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

SDS of cas: 33100-27-5In 2020 ,《Transforming Porous Organic Cages into Porous Ionic Liquids via a Supramolecular Complexation Strategy》 appeared in Angewandte Chemie, International Edition. The author of the article were Jie, Kecheng; Onishi, Nicole; Schott, Jennifer A.; Popovs, Ilja; Jiang, De-en; Mahurin, Shannon; Dai, Sheng. The article conveys some information:

Porous liquids are a type of porous materials that engineer permanent porosity into unique flowing liquids, exhibiting promising functionalities for a variety of applications. Here a Type I porous liquid is synthesized by transforming porous organic cages into porous ionic liquids via a supramol. complexation strategy. Simple phys. mixing of 18-crown-6 with task-specific anionic porous organic cages affords a porous ionic liquid with anionic porous organic cages as the anionic parts and 18-crown-6/potassium ion complexes as the cationic parts. In contrast, mixing of 15-crown-5 and anionic porous organic cages in a 2:1 ratio gives only solids, while the addition of excess 15-crown-5 affords a Type II porous liquid The permanent porosity in the cage-based porous liquids has been also confirmed by mol. simulation, positron (e+) annihilation lifetime spectroscopy, and enhanced gas sorption capacity compared with pure crown ethers. In the experimental materials used by the author, we found 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5SDS of cas: 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. SDS of cas: 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Name: 1,4,7,10,13-PentaoxacyclopentadecaneIn 2020 ,《Sorption of Metal Ions from Aqueous Solutions by Crown Ethers》 was published in Russian Journal of Physical Chemistry B. The article was written by Gromov, V. F.; Gerasimov, G. N.; Ikim, M. I.; Spiridonova, E. Yu.; Trakhtenberg, L. I.. The article contains the following contents:

The sorption of copper and lead ions by polymeric sorbents based on crosslinked polyacrylamide containing chem. bound or immobilized 15-crown-5 and 18-crown-6 was studied, as was the effect of various parameters on the efficiency of metal sorption from aqueous solutions It is shown that the sorption capacity of these sorbents increases dramatically with an increase in the content of crown ethers in them from 3 to 6 wt %. When aging sorbents containing 6 wt % 15-crown-5 or 18-crown-6, in an aqueous solution of copper chloride or lead acetate, resp., the salt concentration in the solution decreases by 3-4 orders of magnitude. When aging sorbents based on 18-crown-6 in a solution containing equivalent amounts of lead acetate or copper sulfate, the amount of absorbed copper did not exceed 5% of the amount of extracted lead, which indicates the high selectivity of such sorbents. In addition to this study using 1,4,7,10,13-Pentaoxacyclopentadecane, there are many other studies that have used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Name: 1,4,7,10,13-Pentaoxacyclopentadecane) was used in this study.

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Name: 1,4,7,10,13-Pentaoxacyclopentadecane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Underlying Polar and Nonpolar Modification MOF-Based Factors that Influence Permanent Porosity in Porous Liquids》 was written by Mahdavi, Hamidreza; Eden, Nathan T.; Doherty, Cara M.; Acharya, Durga; Smith, Stefan J. D.; Mulet, Xavier; Hill, Matthew R.. COA of Formula: C10H20O5This research focused onzirconium terephthalato MOF carbon dioxide adsorption; MOF modification; gas sorption; permanent porosity; porous liquids; zirconium-based metal−organic frameworks. The article conveys some information:

It is increasingly apparent that porous liquids (PLs) have unique use cases due to the combination of ready liquid handling and their inherently high adsorption capacity. Among the PL types, those with permanent porosity are the most promising. Although Type II and III PLs have economic synthetic methods and can be made from a huge variety of metal-organic frameworks (MOFs) and solvents, these nanocomposites still need to be stable to be useful. This work aims to systematically explore the possibilities of creating PLs using different MOF modification methods. This delivered underpinning insights into the mol.-level influence between solvent and MOF on the overall nanocomposite stability. Zirconium-based metal-organic frameworks were combined with two different solvents of varying chem. to deliver CO2 sorption capacities as high as 2.9 mmol g-1 at 10 bar. The results of the study could have far-reaching ramifications for future investigations in the PL field. After reading the article, we found that the author used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5COA of Formula: C10H20O5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. COA of Formula: C10H20O5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Poly(ethylene oxide) helical conformation and alkali metal cation selectivity studied using electrospray ionization mass spectrometry》 was written by Yin, Changna; Fu, Jie; Lu, Xiuyang. Recommanded Product: 33100-27-5 And the article was included in Rapid Communications in Mass Spectrometry in 2020. The article conveys some information:

The poly(ethylene oxide) (PEO)-alkali metal cation interaction is widely used in many areas. The conformation of the PEO-alkali metal cation complex has been studied extensively, but the conformational mechanism is still unclear. Simulations have been used to explain the mechanism, but there is a lack of exptl. data from long PEO chains to verify the simulation results. The relative peak abundance of PEO (iso-C10H21(OC2H4)nOH (naverage = 7,) where n denotes the number of ethylene oxide (EO) units) oligomers complexed to five alkali metal cations (Li+, Na+, K+, Rb+ and Cs+) was studied using pos. electrospray ionization mass spectrometry (ESI-MS). The ion selectivity of PEO oligomers to alkali metal cations corresponded to the peak abundance in competitive ESI-MS. PEO formed its first helix when the number of EO units reached six and the helix played an important role in the ion selectivity of PEO. For larger PEO oligomers with a helix, the ion selectivity of PEO depended on the degree of host-guest matching of the cations and the helix. The highest selectivity of PEO to K+ was due to K+ providing the best shape matching with the helical cavity. For smaller PEO oligomers without a helix, the selectivity was mainly determined by the surface charge d. of the cations. Conclusions : The formational mechanism of the PEO-alkali metal cation complex was predicted. The results gave straightforward evidence to explain the conformational mechanism of the PEO-alkali metal cation complex and provided exptl. data for further simulation studies. In the experiment, the researchers used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Recommanded Product: 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Recommanded Product: 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Ravuru, Shanmuk Srinivas; Jana, Animesh; De, Sirshendu published an article in Advanced Materials Interfaces. The title of the article was 《Discretization and Encapsulation of Palladium inside the Cavity of Crown Ether within the Interlayer of Layered Double Hydroxide for Enhanced Activity: A Case Study with Hydrogenation Reaction》.Electric Literature of C10H20O5 The author mentioned the following in the article:

The activity of the noble metal-based heterogeneous catalysts is limited by weak metal-support interactions, aggregation, and low surface to volume (S/V) ratio. The activity can be augmented in many ways. Among them, the discretization of the active sites and redistribution of electron d. around the metal atom is an important one. In this work, these two phenomena are studied concerning a model reaction, hydrogenation of p-nitrophenol (p-NP). Herein, 1,4,7,10,13-pentaoxacyclopentadecane ether is introduced in the basal space of layered double hydroxide (LDH) to encapsulate noble Pd0 atom inside the cavity of the crown mol. strategically. The modified LDH (Pda-ECC-L0.10@in situ CoAl LDH) augments the properties, like, high S/V ratio and nonaggregation of active sites by forming nonagglomerative discrete catalytic (DNSC) sites within the cavity of crown ether in the basal space. The developed catalyst exhibits higher turnover frequency demonstrating the improved activity due to the formed DNSC sites and redistributes electron d. around the Pd atoms by LDH layers and crown mols. Thus, the present material synthesis route can be considered as a stand-alone method for preparation of the supported sub-nanometer noble metal catalyst with higher activity and can be exploited for reactions where noble metal catalyst are used. In addition to this study using 1,4,7,10,13-Pentaoxacyclopentadecane, there are many other studies that have used 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Electric Literature of C10H20O5) was used in this study.

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Electric Literature of C10H20O5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Synthetic Route of C10H20O5In 2019 ,《Tunable Reduction of 2,4,6-Tri(4-pyridyl)-1,3,5-Triazine: From Radical Anion to Diradical Dianion to Radical Metal-Organic Framework》 appeared in Angewandte Chemie, International Edition. The author of the article were Tang, Shuxuan; Ruan, Huapeng; Feng, Rui; Zhao, Yue; Tan, Gengwen; Zhang, Li; Wang, Xinping. The article conveys some information:

The reduction of 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) with alkali metals resulted in four radical anion salts (1, 2, 4 and 5) and one diradical dianion salt (3). Single-crystal x-ray diffraction and ESR spectroscopy reveal that 1 contains the monoradical anion TPT.- stacked in one-dimensional (1D) with K+(18c6) and 2 can be viewed as a 1D magnetic chain of TPT.-, while 4 and 5 form radical metal-organic frameworks (RMOFs). 1D pore passages, with a diameter of 6.0 Å, containing solvent mols. were observed in 5. Variable-temperature EPR measurements show that 3 has an open-shell singlet ground state that can be excited to a triplet state, consistent with theor. calculation The work suggests that the direct reduction approach could lead to the formation of RMOFs. The results came from multiple reactions, including the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Synthetic Route of C10H20O5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Synthetic Route of C10H20O5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Sagane, Fumihiro; Ogi, Kenta; Konno, Akinori; Kanamura, Kiyoshi published an article in 2021. The article was titled 《The effect of the coordination ability on the Mg plating/stripping behavior in Mg(N(CF3SO2)2)2/glyme based electrolytes》, and you may find the article in Journal of the Electrochemical Society.Application of 33100-27-5 The information in the text is summarized as follows:

The effect of the coordination ability of the solvent species on the Mg plating/stripping behavior was investigated. The Mg plating reaction in Mg(N(CF3SO2)2)2/diglyme was inhibited by the equimolar of 15-crown-5 ether (15C5) to Mg2+-ion. On the other hand, Mg plating took place in the solution by reducing the amount of 15C5 less than that of Mg2+-ion. FT-IR spectra showed that 15C5 preferentially solvated Mg2+-ion in the glyme based solutions The theor. calculation indicated the interaction between Mg2+-ion and each O atom in 15C5 was stronger than that with diglyme or larger sized crown ether. The results showed that the coordination ability of the solvent species could be the critical for the Mg plating reaction. The experimental process involved the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application of 33100-27-5)

1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application of 33100-27-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem