Koelsch, C. F. et al. published their research in Journal of the American Chemical Society in 1944 | CAS: 5367-32-8

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Related Products of 5367-32-8

Synthesis of Et quininate from m-cresol was written by Koelsch, C. F.. And the article was included in Journal of the American Chemical Society in 1944.Related Products of 5367-32-8 This article mentions the following:

m-MeC6H4OH (54 g.) in 150 ml. AcOH and 20 ml. H2SO4, treated at 8-10° with 35 g. NaNO2 in a little H2O, gives the NO compound; this was added to 50 ml. HNO3 and 150 ml. H2O at 40-50° and the crude NO2 compound was treated with Me2SO4 and NaOH to give 50-6 g. of 3,4-Me(O2N)C6H3OMe (I), m. 55°. I and (CO2Et)2 with EtONa in ether, heated 4 hrs. at 45°, treated with ice H2O and then with 30% NaOH and H2O2, give 71-6% of 5-methoxy-2-nitro-α-toluic acid (II); reduction of the K salt of II in H2O with Raney Ni at 30-lb. H pressure gives the the corresponding amino acid, m. 122-4° (decomposition), distillation of which yields 5-methoxyoxindole (III), pale pink, m. 152-4°. II with EtOH-HCl gives 55% of the Et ester (IV), pale yellow, b1 185°, m. 57-9°. Reduction of IV with Raney Ni and H at 30-lb. pressure gives Et 2-amino-5-methoxy-α-toluate (V), whose Ac derivative m. 104-5°; distillation of IV gives III. V with (CHO)2 at 25° gives 88% of glyoxal bis(2-carbethoxymethyl)-4-methoxyanil (VI), yellow, m. 108-9°. VI (7 g.) and 1 g. Na in 20 ml. EtOH, boiled 5 min. and acidified with 3 ml. AcOH, give 0.3 g. of Et quininate (VII), m. 65-7°. The action of C5H5N, piperidine or K2CO3 in hot quinoline yields no VII. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8Related Products of 5367-32-8).

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Related Products of 5367-32-8

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Gakhar, H. K. et al. published their research in Journal of the Indian Chemical Society in 1984 | CAS: 57179-35-8

3-Hydroxy-5-methoxybenzaldehyde (cas: 57179-35-8) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Product Details of 57179-35-8

[1,3,4]Thiadiazolo[2,3-c][1,2,4]triazines was written by Gakhar, H. K.;Prabha, Usha;Gill, J. K.. And the article was included in Journal of the Indian Chemical Society in 1984.Product Details of 57179-35-8 This article mentions the following:

The cyclocondensation of aminotriazinethiones I (R = Me, Ph) with R1CHO [R1 = Ph, O2NC6H4, (un)substituted 3,4-(methylenedioxy)phenyl, HO(MeO)C6H3] gave thiadiazolotriazines II. I (R = Me) in ether was treated with HCl gas, the ether was decanted, the residue was placed in EtOH, PhCHO and NaOAc were added, and the mixture was refluxed to give II (R = Me, R1 = Ph). In the experiment, the researchers used many compounds, for example, 3-Hydroxy-5-methoxybenzaldehyde (cas: 57179-35-8Product Details of 57179-35-8).

3-Hydroxy-5-methoxybenzaldehyde (cas: 57179-35-8) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Product Details of 57179-35-8

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Chan, Chun-Wo et al. published their research in Advanced Synthesis & Catalysis in 2011 | CAS: 56619-93-3

N-(3-Methoxyphenyl)pivalamide (cas: 56619-93-3) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Ethers can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Quality Control of N-(3-Methoxyphenyl)pivalamide

Palladium(II)-Catalyzed Direct ortho-C-H Acylation of Anilides by Oxidative Cross-Coupling with Aldehydes using tert-Butyl Hydroperoxide as Oxidant was written by Chan, Chun-Wo;Zhou, Zhongyuan;Yu, Wing-Yiu. And the article was included in Advanced Synthesis & Catalysis in 2011.Quality Control of N-(3-Methoxyphenyl)pivalamide This article mentions the following:

An efficient palladium-catalyzed C-H acylation with aldehydes using tert-Bu hydroperoxide (TBHP) transforms various anilides into synthetically useful 2-aminobenzophenone derivatives under mild conditions (40°, 3 h). The acylation reaction exhibits excellent regioselectivity and functional group tolerance, and simple aromatic aldehydes, functionalized aliphatic aldehydes and heteroaromatic aldehydes are effective coupling partners. The acylation reaction is probably initiated by a rate-limiting electrophilic C-H cyclopalladation (kH/kD=3.6; ρ+=-0.74) to form an arylpalladium complex, followed by acyl radical functionalization. In the experiment, the researchers used many compounds, for example, N-(3-Methoxyphenyl)pivalamide (cas: 56619-93-3Quality Control of N-(3-Methoxyphenyl)pivalamide).

N-(3-Methoxyphenyl)pivalamide (cas: 56619-93-3) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Ethers can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Quality Control of N-(3-Methoxyphenyl)pivalamide

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Munoz, Juan de M. et al. published their research in Advanced Synthesis & Catalysis in 2012 | CAS: 365564-07-4

2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 365564-07-4) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Recommanded Product: 365564-07-4

Cross-Coupling in Flow using Supported Catalysts: Mild, Clean, Efficient and Sustainable Suzuki-Miyaura Coupling in a Single Pass was written by Munoz, Juan de M.;Alcazar, Jesus;de la Hoz, Antonio;Diaz-Ortiz, Angel. And the article was included in Advanced Synthesis & Catalysis in 2012.Recommanded Product: 365564-07-4 This article mentions the following:

A mild, clean, practical, sustainable and high yielding procedure for Suzuki-Miyaura cross-coupling in a single pass using a silica-supported palladium catalyst is described. The catalyst can be used in more than 30 reactions and for more than 8 h of continuous processing without a decrease in reactivity due to the low leaching observed Different halides/pseudo-halides and organoboron compounds can be used without modifying the standard procedure. In the experiment, the researchers used many compounds, for example, 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 365564-07-4Recommanded Product: 365564-07-4).

2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 365564-07-4) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Recommanded Product: 365564-07-4

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Peddagopu, Nishant et al. published their research in European Journal of Inorganic Chemistry in 2021 | CAS: 112-49-2

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.SDS of cas: 112-49-2

A One-Pot Synthesis of “K(hfa) glyme” Adducts: Effect of the Polyether Length on the Ion Coordination Sphere was written by Peddagopu, Nishant;Sanzaro, Salvatore;Rossi, Patrizia;Paoli, Paola;Malandrino, Graziella. And the article was included in European Journal of Inorganic Chemistry in 2021.SDS of cas: 112-49-2 This article mentions the following:

Potassium complexes are starting to gather more and more interest from academia and industry because of their intriguing application possibilities. Novel adducts of potassium hexafluoroacetylacetonato [K(hfa)] with polyethers (monoglyme, diglyme, triglyme, and tetraglyme) were synthesized through a single step reaction and characterized through FTIR spectroscopy as well as 1H and 13C NMR spectroscopy. Single crystal x-ray diffraction studies enabled the identification of fascinating K coordination polymeric networks. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2SDS of cas: 112-49-2).

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.SDS of cas: 112-49-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Pramila, T. et al. published their research in Journal of Pharmaceutical Sciences and Research in 2020 | CAS: 1877-75-4

2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Related Products of 1877-75-4

Synthesis and characterization of aryloxy derivatives of bis-azetinone for anticancer activity was written by Pramila, T.. And the article was included in Journal of Pharmaceutical Sciences and Research in 2020.Related Products of 1877-75-4 This article mentions the following:

A series of novel aryloxy bis azetinones have been synthesized using benzocaine as a starting compound Benzocaine reacted with benzyl bromide to give N-benzylated benzocaine which underwent nucleophillic addition reaction with hydrazine hydrate to yield 4-(benzylamino)benzohydrazide, further treatment with palladium catalyst gave 4-aminobenzohydrazide. 4-Aminobenzohydrazide was reacted with benzaldehyde to yield (4E,10E)-N’-benzylidene-4-(benzylideneamino)benzohydrazide, which on further reacting with different substituted phenoxyacetyl chlorides gave aryloxy bis azetinone derivatives I (R = H, 4-OMe, 3-Br, etc.). The synthesized compounds were screened for in-vitro anticancer activity and were found to be active. In the experiment, the researchers used many compounds, for example, 2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4Related Products of 1877-75-4).

2-(4-Methoxyphenoxy)acetic acid (cas: 1877-75-4) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).Related Products of 1877-75-4

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Willemsens, Bert et al. published their research in ACS Symposium Series in 2004 | CAS: 56619-93-3

N-(3-Methoxyphenyl)pivalamide (cas: 56619-93-3) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Safety of N-(3-Methoxyphenyl)pivalamide

Dihydro-7-benzofurancarboxylic acid: An intermediate in the synthesis of the enterokinetic agent R108512 was written by Willemsens, Bert;Copmans, Alex;Beerens, Dirk;Leurs, Stef;de Smaele, Dirk;Rey, Max;Farkas, Silke. And the article was included in ACS Symposium Series in 2004.Safety of N-(3-Methoxyphenyl)pivalamide This article mentions the following:

A facile and scalable method for the synthesis of 4-amino-5-chloro-2,3-dihydro-7-benzofurancarboxylic acid, an intermediate in the synthesis of the enterokinetic agent R108512, was developed. The key step in the synthesis is a Zn mediated ring closure of Me 4-(acetylamino)-3-bromo-2-(2-bromoethoxy)-5-chlorobenzoate. The ring closure can be achieved without preliminary activation of the Zn on condition that the O content in the reaction mixture is <0.5%. The new process eliminates hazardous chems. (ethylene oxide) and low temperature reactions (-70°, BuLi). In the experiment, the researchers used many compounds, for example, N-(3-Methoxyphenyl)pivalamide (cas: 56619-93-3Safety of N-(3-Methoxyphenyl)pivalamide).

N-(3-Methoxyphenyl)pivalamide (cas: 56619-93-3) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Safety of N-(3-Methoxyphenyl)pivalamide

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Toupalas, Georgios et al. published their research in ACS Catalysis in 2022 | CAS: 105-13-5

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Recommanded Product: (4-Methoxyphenyl)methanol

Pd-Catalyzed Direct Deoxygenative Arylation of Non-π-Extended Benzyl Alcohols with Boronic Acids via Transient Formation of Non-Innocent Isoureas was written by Toupalas, Georgios;Thomann, Gianin;Schlemper, Lukas;Rivero-Crespo, Miguel A.;Schmitt, Hendrik L.;Morandi, Bill. And the article was included in ACS Catalysis in 2022.Recommanded Product: (4-Methoxyphenyl)methanol This article mentions the following:

Authors report the direct arylation of non-derivatized alcs. with boronic acids and demonstrate that a Pd catalyst, in combination with a carbodiimide, can be used to forge a C-C bond via the transient formation of non-innocent isoureas from the corresponding alcs. Besides further polarizing the C-O bond, the transiently generated isourea contains a masked base that is released during the reaction to enable catalytic turnover under exogenous base-free conditions. The developed concept was benchmarked against the coupling of non-π-extended benzyl alcs. and boronic acids and led to the formation of a C-C bond between differently decorated coupling partners. Notably, the strategic generation of non-innocent isoureas endows this C-O cleavage reaction with high orthogonality over conventional electrophiles and enables the employment of highly base-sensitive boronic acids. Addnl., the preformed isoureas can be leveraged for rapid (5 min reaction time) exogenous base-free coupling reactions, which work under conventional thermal conditions and do not rely on customized catalysts or specialized equipment. The synthetic investigations were also complemented by preliminary mechanistic studies. More broadly, the presented work bridges a conceptual gap between two important research areas, i.e., carbodiimide-mediated alc. activation and deoxygenative transition metal-catalyzed coupling chem., providing a promising blueprint for direct catalytic deoxygenative reactions. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Recommanded Product: (4-Methoxyphenyl)methanol).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Recommanded Product: (4-Methoxyphenyl)methanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zhu, Ziyue et al. published their research in Organic Letters in 2021 | CAS: 112-49-2

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.SDS of cas: 112-49-2

Chemoselective N- and O-Difluoromethylation of 2-Pyridones, Isoquinolinones, and Quinolinones with TMSCF2Br was written by Zhu, Ziyue;Krishnamurti, Vinayak;Ispizua-Rodriguez, Xanath;Barrett, Colby;Prakash, G. K. Surya. And the article was included in Organic Letters in 2021.SDS of cas: 112-49-2 This article mentions the following:

An operationally simple protocol for direct N- and O-difluoromethylation of 2-pyridones, quinolinones, and isoquinolinones using com. available TMSCF2Br was disclosed. The chemoselectivity was modulated by simple variations in temperature, solvent, and strength of the base. Diverse, synthetically relevant functional groups were tolerated, including functional groups that have reported reactivity with TMSCF2Br. Gram-scale reactions to prepare both N- and O-difluoromethyl compounds were included. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2SDS of cas: 112-49-2).

2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.SDS of cas: 112-49-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zouari, H. B. et al. published their research in Journal of Photochemistry and Photobiology, A: Chemistry in 2021 | CAS: 111-77-3

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.Name: 2-(2-Methoxyethoxy)ethanol

Influence of in situ photo-induced silver nanoparticles on the ageing of acrylate materials was written by Zouari, H. B.;Dabert, M.;Asia, L.;Wong-Wah-Chung, P.;Baba, M.;Balan, L.;Israeli, Y.. And the article was included in Journal of Photochemistry and Photobiology, A: Chemistry in 2021.Name: 2-(2-Methoxyethoxy)ethanol This article mentions the following:

The present work aims to investigate the impact of a low amount of photo-induced silver nanoparticles (0.2 and 0.4 weight% of Ag NPs) on the stability of acrylate materials (carriers of ester and ether groups) under the combined effect of oxygen and light. Different techniques were implemented to monitor the structural changes at different scales. The determination of the influence of AgNPs required a preliminary investigation of the pure acrylate polymer under the same exptl. conditions. The polymer underwent a post-polymerization of the residual vinyl groups and a photo-oxidative degradation This degradation induced chem. modifications evidenced by IR spectroscopy and architectural changes resulting from chain scission reactions. These reactions were not only responsible for the steaming of volatile organic compounds, detected by HS-SPME/GC-MS but also for the increase in mesh size controlled by thermoporosimetry. As regards the polymer/Ag NPs composite, the higher the amount of filler dispersed in the matrix, the greater the rate of degradation-. This behavior was due to the photocatalytic effect of Ag NPs, regardless of the loading in nanoparticles. As a result of irradiation, the nanoparticles migrate to the surface of the film and coalesce, thus inducing an increase in size distribution and a gradient structuring as revealed by TEM anal. The outcomes of this investigation are important for the development of new composite material with new functionalities (antibacterial, optical, conductive properties) for industrial applications as in textile industry. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Name: 2-(2-Methoxyethoxy)ethanol).

2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides.Name: 2-(2-Methoxyethoxy)ethanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem