Category: 10365-98-7

The author of 《Modular Syntheses of Phenanthroindolizidine Natural Products》 were Jo, Young-In; Burke, Martin D.; Cheon, Cheol-Hong. And the article was published in Organic Letters in 2019. Application of 10365-98-7 The author mentioned the following in the article:

A highly concise strategy for the total synthesis of phenanthroindolizidines was developed. The one-pot iterative Suzuki-Miyaura reaction of aryl boronic acids with ortho-bromoaryl N-methyliminodiacetate (MIDA) boronate followed by a second Suzuki-Miyaura reaction with a suitable pyridyl bromide provided ortho-aza-terphenyls. Subsequent saturation of the triple bond, treatment with mesyl chloride, and reduction of the resulting dihydroindolizidinium ring afforded the hexahydroindolizines. A final vanadium-catalyzed oxidative electrocyclization provided the desired alkaloids in only three column-separation operations.3-Methoxyphenylboronic acid(cas: 10365-98-7Application of 10365-98-7) was used in this study.

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Application of 10365-98-7

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《Open-Air Stereoselective Construction of C-Aryl Glycosides》 was published in Organic Letters in 2020. These research results belong to Lai, Mengnan; Othman, Karwan Abdulmajed; Yao, Hui; Wang, Qiuyuan; Feng, Yongkui; Huang, Nianyu; Liu, Mingguo; Zou, Kun. Safety of 3-Methoxyphenylboronic acid The article mentions the following:

A new methodol. of stereoselective C-glycosylation has been developed with 3,4-O-carbonate glycals and boronic acids, catalyzed by 1,2-bis(phenylsulfinyl)ethane palladium(II) acetate under open-air conditions at room temperature This mild method is simple in operation, wide in substrate range, and tolerant in alc./phenolic hydroxyl and amino groups. High to excellent yields were observed for all substrates tested, with the driving force mainly contributed by decarboxylation. Meanwhile, the high 1,4-trans-selectivity was achieved by steric effects as proposed. The experimental part of the paper was very detailed, including the reaction process of 3-Methoxyphenylboronic acid(cas: 10365-98-7Safety of 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Safety of 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
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In 2019,Organic Letters included an article by Peng, Jin-Bao; Li, Da; Geng, Hui-Qing; Wu, Xiao-Feng. Recommanded Product: 10365-98-7. The article was titled 《Palladium-Catalyzed Amide Synthesis via Aminocarbonylation of Arylboronic Acids with Nitroarenes》. The information in the text is summarized as follows:

A palladium-catalyzed aminocarbonylation of aryl boronic acids with nitroarenes for the synthesis of amides was developed. A wide range of substrates were well-tolerated and gave the corresponding amides in moderate to good yields. No external oxidant or reductant was needed in this procedure. This procedure provides a redox-economical process for the synthesis of amides. In addition to this study using 3-Methoxyphenylboronic acid, there are many other studies that have used 3-Methoxyphenylboronic acid(cas: 10365-98-7Recommanded Product: 10365-98-7) was used in this study.

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Recommanded Product: 10365-98-7

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《Synthesis and antiplasmodial activity of 1,2,3-triazole-naphthoquinone conjugates》 was written by Oramas-Royo, Sandra; Lopez-Rojas, Priscila; Amesty, Angel; Gutierrez, David; Flores, Ninoska; Martin-Rodriguez, Patricia; Fernandez-Prrez, Leandro; Estevez-Braun, Ana. SDS of cas: 10365-98-7This research focused ontriazole naphthoquinones copper catalyzed cycloaddition mol docking Plasmodium malaria; 1,2,3-triazole-naphthoquinones; Plasmodium falciparum; copper-catalyzed cycloaddition; docking; malaria. The article conveys some information:

A series of 34 1,2,3-triazole-naphthoquinone conjugates were synthesized via copper-catalyzed cycloaddition (CuAAC). They were evaluated for their in vitro antimalarial activity against chloroquine-sensitive strains of Plasmodium falciparum and against three different tumor cell lines (SKBr-3, MCF-7, HEL). The most active antimalarial compounds showed a low antiproliferative activity. Simplified analogs were also obtained and some structure-activity relationships were outlined. The best activity was obtained by compounds 3s and 3j, having IC50 of 0.8 and 1.2 μM, resp. Mol. dockings were also carried on Plasmodium falciparum enzyme dihydroorotate dehydrogenase (PfDHODH) in order to rationalize the results. In the experimental materials used by the author, we found 3-Methoxyphenylboronic acid(cas: 10365-98-7SDS of cas: 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.SDS of cas: 10365-98-7

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Zhu, Zhaoyang; Zhang, Xue; Guo, Xing; Wu, Qinghua; Li, Zhongxin; Yu, Changjiang; Hao, Erhong; Jiao, Lijuan; Zhao, Jianzhang published an article in 2021. The article was titled 《Orthogonally aligned cyclic BODIPY arrays with long-lived triplet excited states as efficient heavy-atom-free photosensitizers》, and you may find the article in Chemical Science.Synthetic Route of C7H9BO3 The information in the text is summarized as follows:

In photosensitizers, long triplet excited state lifetimes are key to their efficient electron transfer or energy transfer processes. Herein, we report a novel class of cyclic trimeric BODIPY arrays which were efficiently generated from easily accessible meso-mesityldipyrrinone and arylboronic acids in one pot. Arylboronic acid, for the first time, was used to provide a boron source for BODIPY derivatives Due to the well-defined and orthogonally aligned BODIPY cores as verified by X-ray crystallog., these BODIPY arrays show strong exciton coupling effects and efficient intersystem crossings, and are novel heavy-atom-free photosensitizers with a long-lived triplet excited state (lifetime up to 257.5 μs) and good reactive oxygen species generation efficiency (up to 0.72) contributed by both 1O2 and O2- under light irradiation The experimental part of the paper was very detailed, including the reaction process of 3-Methoxyphenylboronic acid(cas: 10365-98-7Synthetic Route of C7H9BO3)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Synthetic Route of C7H9BO3

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Ether – Wikipedia,
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The author of 《Asymmetric synthesis of functionalized phenylalanine derivatives via Rh-catalyzed conjugate addition and enantioselective protonation cascade》 were Jian, Jia-Hong; Zeng, Hao-Wei; Kuo, Ting-Shen; Wu, Ping-Yu; Wu, Hsyueh-Liang. And the article was published in Organic Letters in 2019. Quality Control of 3-Methoxyphenylboronic acid The author mentioned the following in the article:

The asym. conjugate addition of arylboronic acids to N-phthalimidodehydroalanine 1i catalyzed by Rh(I)/L1a enables the facile preparation of chiral functionalized phenylalanines. The reaction proceeds by a conjugate addition and enantioselective protonation cascade, affording a rhodium enolate that undergoes re-face protonation. The reaction tolerates various arylboronic acids and can be used in the gram-scale synthesis of (S)-phenylalanine hydrochloride, demonstrating the reaction scope and the synthetic feasibility of the process. In the experiment, the researchers used many compounds, for example, 3-Methoxyphenylboronic acid(cas: 10365-98-7Quality Control of 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Quality Control of 3-Methoxyphenylboronic acid

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Ether – Wikipedia,
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The author of 《Aerobic Homocoupling of Arylboronic Acids Catalyzed by Regenerable Pd(II)@MIL-88B-NH2(Cr)》 were Valiente, Alejandro; Carrasco, Sergio; Sanz-Marco, Amparo; Tai, Cheuk-Wai; Bermejo Gomez, Antonio; Martin-Matute, Belen. And the article was published in ChemCatChem in 2019. Category: ethers-buliding-blocks The author mentioned the following in the article:

A fast and operationally simple method for the aerobic homocoupling of arylboronic acids was described. The process was catalyzed by Pd(II) complexes supported on the metal-organic framework MIL-88B-NH2(Cr). The benefits of this approach include the use of a benign oxidant/solvent mixture at room temperature with catalytic amounts of base, easy recovery of the catalyst, and easy isolation of the products. Very high conversions and good yields were achieved for a variety of substrates, and the process was also carried out on a larger scale with the same efficiency. The catalyst was found to suffer deactivation due to progressive reduction and agglomeration of palladium into inactive metal clusters/particles. An innovative procedure for the oxidative redispersion and regeneration of the active Pd(II)@MOF species was presented.3-Methoxyphenylboronic acid(cas: 10365-98-7Category: ethers-buliding-blocks) was used in this study.

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Category: ethers-buliding-blocks

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《Decarbonylative Suzuki-Miyaura Cross-Coupling of Aroyl Chlorides》 was published in Organic Letters in 2020. These research results belong to Zhou, Tongliang; Xie, Pei-Pei; Ji, Chong-Lei; Hong, Xin; Szostak, Michal. Name: 3-Methoxyphenylboronic acid The article mentions the following:

Herein, we report a catalyst system for Pd-catalyzed decarbonylative Suzuki-Miyaura cross-coupling of aroyl chlorides with boronic acids to furnish biaryls. This strategy is suitable for a broad range of common aroyl chlorides and boronic acids. The synthetic utility is highlighted in the direct late-stage functionalization of pharmaceuticals and natural products capitalizing on the presence of carboxylic acid moiety. Extensive mechanistic and DFT studies provide key insight into the reaction mechanism and high decarbonylative cross-coupling selectivity. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Name: 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Name: 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Chemical Science included an article by Zhou, Tongliang; Ji, Chong-Lei; Hong, Xin; Szostak, Michal. SDS of cas: 10365-98-7. The article was titled 《Palladium-catalyzed decarbonylative Suzuki-Miyaura cross-coupling of amides by carbon-nitrogen bond activation》. The information in the text is summarized as follows:

The first palladium-catalyzed decarbonylative Suzuki-Miyaura cross-coupling of amides RC(O)NR1R2 [R = Ph, naphth-2-yl, benzo[d][1,3]dioxol-5-yl, etc.; R1 = Ac, Ms, Ts, Boc; R2 = Me, Ph, Boc; R1R2 = -C(O)(CH2)3C(O)-, -C(O)(CH2)2C(O)-] and N-benzoylphthalimide for the synthesis of biaryls RR3 (R3 = cyclopropyl, thiophen-3-yl, dimethyl-1,2-oxazol-4-yl, etc.) through the selective activation of the N-C(O) bond of amides has been reported. This new method relies on the precise sequence engineering of the catalytic cycle, wherein decarbonylation occurs prior to the transmetalation step. The reaction is compatible with a wide range of boronic acids R3B(OH)2 and amides, providing valuable biaryls in high yields (>60 examples). DFT studies support a mechanism involving oxidative addition, decarbonylation and transmetalation and provide insight into high N-C(O) bond activation selectivity. Most crucially, the reaction establishes the use of palladium catalysis in the biaryl Suzuki-Miyaura cross-coupling of the amide bond and should enable the design of a wide variety of cross-coupling methods in which palladium rivals the traditional biaryl synthesis from aryl halides and pseudohalides. In addition to this study using 3-Methoxyphenylboronic acid, there are many other studies that have used 3-Methoxyphenylboronic acid(cas: 10365-98-7SDS of cas: 10365-98-7) was used in this study.

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.SDS of cas: 10365-98-7

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Ether – Wikipedia,
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Reference of 3-Methoxyphenylboronic acidIn 2020 ,《Tetradentate Platinum(II) Complexes for Highly Efficient Phosphorescent Emitters and Sky Blue OLEDs》 was published in Chemistry of Materials. The article was written by Li, Guijie; Zhao, Xiangdong; Fleetham, Tyler; Chen, Qidong; Zhan, Feng; Zheng, Jianbing; Yang, Yun-Fang; Lou, Weiwei; Yang, Yuning; Fang, Kun; Shao, Zongzhou; Zhang, Qisheng; She, Yuanbin. The article contains the following contents:

A series of tetradentate Pt(II) emitters containing fused 5/6/6 metallocycles have been designed and synthesized. Mol. geometries play a critical role in determining the photophys. properties. Their emission spectra are significantly affected by the geometries of the mol. core skeletons, the substituents, even hydrogen atoms, and their positions, which are further supported by X-ray crystallog. analyses and theor. calculations The generation of excimer emissions is observed in the tetradentate 5/6/6 Pt(II) emitters for the first time and found to be concentration-dependent both in the solution and solid states. All of the Pt(II) emitters have high photoluminescent quantum efficiency of up to 100% and luminescent lifetime as short as 1.4 μs at room temperature, achieving a radiative rate of 7.14 × 105 s-1. Their emission color can be easily tuned to cover the whole visible region (λmax = 464-632 nm) through selective synthetic modification of the heteroaromatic rings of the ligands. Pt(1-ptz)-based sky blue organic light-emitting diode (OLED) demonstrates a maximum external quantum efficiency (EQE) of 14.5%, yet maintains an EQE of 12.7% at a high brightness of 1000 cd/m2. This work demonstrates that these tetradentate Pt(II) complexes can act as efficient phosphorescent emitters for OLED applications. After reading the article, we found that the author used 3-Methoxyphenylboronic acid(cas: 10365-98-7Reference of 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Reference of 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem