The author of 《Aerobic Homocoupling of Arylboronic Acids Catalyzed by Regenerable Pd(II)@MIL-88B-NH2(Cr)》 were Valiente, Alejandro; Carrasco, Sergio; Sanz-Marco, Amparo; Tai, Cheuk-Wai; Bermejo Gomez, Antonio; Martin-Matute, Belen. And the article was published in ChemCatChem in 2019. Category: ethers-buliding-blocks The author mentioned the following in the article:
A fast and operationally simple method for the aerobic homocoupling of arylboronic acids was described. The process was catalyzed by Pd(II) complexes supported on the metal-organic framework MIL-88B-NH2(Cr). The benefits of this approach include the use of a benign oxidant/solvent mixture at room temperature with catalytic amounts of base, easy recovery of the catalyst, and easy isolation of the products. Very high conversions and good yields were achieved for a variety of substrates, and the process was also carried out on a larger scale with the same efficiency. The catalyst was found to suffer deactivation due to progressive reduction and agglomeration of palladium into inactive metal clusters/particles. An innovative procedure for the oxidative redispersion and regeneration of the active Pd(II)@MOF species was presented.3-Methoxyphenylboronic acid(cas: 10365-98-7Category: ethers-buliding-blocks) was used in this study.
3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Category: ethers-buliding-blocks
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem