The author of 《Modular Syntheses of Phenanthroindolizidine Natural Products》 were Jo, Young-In; Burke, Martin D.; Cheon, Cheol-Hong. And the article was published in Organic Letters in 2019. Application of 10365-98-7 The author mentioned the following in the article:
A highly concise strategy for the total synthesis of phenanthroindolizidines was developed. The one-pot iterative Suzuki-Miyaura reaction of aryl boronic acids with ortho-bromoaryl N-methyliminodiacetate (MIDA) boronate followed by a second Suzuki-Miyaura reaction with a suitable pyridyl bromide provided ortho-aza-terphenyls. Subsequent saturation of the triple bond, treatment with mesyl chloride, and reduction of the resulting dihydroindolizidinium ring afforded the hexahydroindolizines. A final vanadium-catalyzed oxidative electrocyclization provided the desired alkaloids in only three column-separation operations.3-Methoxyphenylboronic acid(cas: 10365-98-7Application of 10365-98-7) was used in this study.
3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Application of 10365-98-7
Referemce:
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