In 2019,Chemical Science included an article by Zhang, Yitao; Takale, Balaram S.; Gallou, Fabrice; Reilly, John; Lipshutz, Bruce H.. Category: ethers-buliding-blocks. The article was titled 《Sustainable ppm level palladium-catalyzed aminations in nanoreactors under mild, aqueous conditions》. The information in the text is summarized as follows:
A 1 : 1 Pd : ligand complex, [t-BuXPhos(Pd-Π-cinnamyl)]OTf, was identified as a highly robust pre-catalyst for amination reactions leading to diarylamines, where loadings of metal were typically at 1000 ppm Pd, run in water at temperatures between rt and 45 °C. The protocol was exceptionally simple, readily scaled and compared very favorably vs. traditional amination conditions. It was shown to successfully led to key intermediates associated with several physiol. active compounds In the part of experimental materials, we found many familiar compounds, such as 1-Bromo-3-methoxybenzene(cas: 2398-37-0Category: ethers-buliding-blocks)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) can be used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemicals.Category: ethers-buliding-blocks
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem