An article Metal-free photoredox-catalysed formal C-H/C-H coupling of arenes enabled by interrupted Pummerer activation WOS:000508320900002 published article about ARYL SULFOXIDES; ALLOSTERIC INHIBITORS; ELECTRON-TRANSFER; ALPHA-ARYLATION; LIGHT; SALTS; TRANSFORMATIONS; PSEUDILINS; REDUCTION; SULFONIUM in [Aukland, Miles H.; Siauciulis, Mindaugas; West, Adam; Perry, Gregory J. P.; Procter, David J.] Univ Manchester, Dept Chem, Manchester, Lancs, England in 2020.0, Cited 53.0. SDS of cas: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
Aryl-aryl cross-coupling constitutes one of the most widely used procedures for the synthesis of high-value materials that range from pharmaceuticals to organic electronics and conducting polymers. The assembly of (hetero)biaryl scaffolds generally requires multiple steps; coupling partners must be functionalized before the key bond-forming event is considered. The development of selective C-H arylation processes in arenes-which sidestep the need for prefunctionalized partners-is thus crucial for streamlining the construction of these key architectures. Here we report an expedient, one-pot assembly of (hetero)biaryl motifs using photocatalysis and two non-prefunctionalized arene partners. The approach is underpinned by the functionalization of a C-H bond in an arene coupling partner using the interrupted Pummerer reaction. A unique pairing of the organic photoredox catalyst and the intermediate dibenzothiophenium salts enables highly selective reduction in the presence of sensitive functionalities. The utility of the metal-free, one-pot strategy is exemplified by the synthesis of a bioactive natural product and the modification of complex molecules of societal importance.
SDS of cas: 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Aukland, MH; Siauciulis, M; West, A; Perry, GJP; Procter, DJ or concate me.
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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem