COA of Formula: C12H10O. In 2020 SCI CHINA CHEM published article about C-H FUNCTIONALIZATION; CROSS-COUPLING REACTIONS; CATALYZED ARYLATION; PUMMERER REACTION; SULFONIUM SALTS; BOND FORMATION; ION RADICALS; ACTIVATION; ARENES; ALKYLATION in [Wu, Jie; Chen, Xiao-Yue; Wu, Yichen; Wang, Daoming; Wang, Peng] Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China; [Wang, Peng] Shanghai Inst Organ Chem, CAS Key Lab Energy Regulat Mat, Shanghai 200032, Peoples R China; [Wang, Zengwei; Peng, Qian] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China in 2020, Cited 86. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
Herein, we conceptualized a transient mediator approach that has the capability of para-selective C-H functionalization of monosubstituted aromatics. This approach is enabled by in situ generation of a versatile sulfonium salt via highly electrophilic phenoxathiine or thianthrene dication intermediate which can be readily generated from its sulfoxide with tri-fluoromethanesulfonic anhydride. Preliminary mechanistic study implied that the remarkable para selectivity might be related to the incredible electrophilicity of thianthrene dication intermediate. The versatility of this approach was demonstrated via para-borylation of various monosubstituted simple aromatics combining the sulfonium salt formation with further photocatalyzed transformation.
COA of Formula: C12H10O. About Diphenyl oxide, If you have any questions, you can contact Wu, J; Wang, ZW; Chen, XY; Wu, YC; Wang, DM; Peng, Q; Wang, P or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem