I found the field of Chemistry very interesting. Saw the article Recyclable synthesis of mesityl iodonium(III) salts published in 2019.0. Product Details of 101-84-8, Reprint Addresses Dohi, T (corresponding author), Ritsumeikan Univ, Coll Pharmaceut Sci, 1-1-1 Nojihigashi, Kusatsu, Shiga 5258577, Japan.; Kita, Y (corresponding author), Ritsumeikan Univ, Res Org Sci & Technol, 1-1-1 Nojihigashi, Kusatsu, Shiga 5258577, Japan.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide
An efficient protocol for C-H condensation of hypervalent iodine compounds toward arenes in fluoroalcohols has been applied to the recyclable preparation of mesityl iodonium(III) salts. The electrophilicities of [hydroxy(tosyloxy)iodo]mesitylene (Mesl(OH)OTs) and iodomesitylene diacetate (Mesl(OAc)(2)) are suitably enhanced in 2,2,2-trifluoroethanol. A series of nucleophilic aromatic compounds react smoothly with Mesl(OH)OTs and Mesl(OAc)(2) or in situ hypervalent iodine(III) species, generated from iodomesitylene, to provide the target mesityl iodonium(III) salts in good yields at room temperature with broad functional group tolerance. This C-H condensation strategy merits high para-regioselectivities during the diaryliodonium(III) salt formation, but the major limitation in the case of low-reactive aromatic substrates is byproduct formation resulting from the self-condensation of the nucleophilic mesitylene ring in Mesl(OH)OTs and Mesl(OAc)(2). (C) 2019 Elsevier Ltd. All rights reserved.
Product Details of 101-84-8. About Diphenyl oxide, If you have any questions, you can contact Dohi, T; Hayashi, T; Ueda, S; Shoji, T; Komiyama, K; Takeuchi, H; Kita, Y or concate me.
Reference:
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