Recently I am researching about FUEL-CELLS; HIGH-PERFORMANCE; CATHODE; TRANSITION; HYDRATION; OXIDES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51802065]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [JZ2020HGTB0024]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M630702]. Application In Synthesis of Diphenyl oxide. Published in SPRINGER HEIDELBERG in HEIDELBERG ,Authors: Hong, T; Lu, WH; Ren, KK; Liu, T. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide
For materials as BaCo(0.4)Fe(0.4)Zr(0.1)Y(0.1)O(3-delta)with three independent mobile charge carriers, hole, oxygen ion, and proton, a peculiar twofold diffusion and transition from hydration to hydrogenation in proton uptake are investigated by electrical conductivity relaxation method in this work. At 700 degrees C, the water incorporation reaction would happen in the formation of both hydration and hydrogenation. The hydration reaction would happen at the sacrifice of oxygen vacancy, and then, the incorporated proton diffuses from outer layer to the inner bulk. But due to much higher chemical diffusion coefficient of proton than oxygen vacancy, the highly mobile protons are charge compensated by holes, instead of waiting for the less mobile oxygen vacancy, and thus causes the speeding increased hole concentration, i.e., increased conductivity. So in the hydration reaction, the decoupled diffusion of proton and oxygen vacancy would result in a non-monotonic conductivity relaxation curve, i.e., twofold diffusion. After that, the proton uptake reaction would transit to hydrogenation, as total decreased conductivity in a monotonic curve.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem