An article Liquid organic hydrogen carriers: Hydrogen storage by di-phenyl ether derivatives: An experimental and theoretical study WOS:000517501200017 published article about VAPOR-PRESSURES; THERMOCHEMISTRY; VAPORIZATION; ENTHALPIES; CARBAZOLE in [Verevkin, Sergey P.] Univ Rostock, Dept Phys Chem, D-18059 Rostock, Germany; [Verevkin, Sergey P.] Univ Rostock, Fac Interdisciplinary Res, Competence Ctr CALOR, D-18059 Rostock, Germany; [Verevkin, Sergey P.; Pimerzin, Andrey A.] Samara State Tech Univ, Chem Dept, Samara 443100, Russia; [Sun, Li-Xian] Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Sch Mat Sci & Engn, Guilin 541004, Peoples R China; [Sun, Li-Xian] Guilin Univ Elect Technol, Guangxi Collaborat Innovat Ctr Struct & Property, Guilin 541004, Peoples R China in 2020, Cited 35. Recommanded Product: 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
The liquid organic hydrogen carriers (LOHCs) are promising materials for hydrogen storage. The standard molar enthalpies of formation, Delta H-f(m)0 (liq/cr) of diphenyl ether substituted with amino substituents were measured by the high-precision combustion calorimetry. Enthalpies of vaporisation/sublimation Delta H-g(l,cr)m(0) (298.15 K) of these compounds were obtained by the transpiration method. Enthalpies of fusion were measured by DSC. Gas-phase enthalpies of formation Delta H-f(m)0 (g, 298.15 K) of substituted diphenyl ethers calculated by the G4 method were in an excellent agreement with the experimental results. Enthalpies of the hydrogenation/dehydrogenation reactions of diphenyl ether derivatives were estimated and compared with the data available for other potential LOHC. A set of thermodynamic properties of diphenyl ether derivatives of benchmark quality was recommended for thermochemical calculations. Equilibrium temperatures of hydrogenation/dehydrogenation processes were calculated and compared with those of benzene derivatives. Due to the high hydrogen storage capacity, as well as very low volatility, these compounds could be considered as seminal candidates for LOHC. (C) 2020 Published by Elsevier Ltd.
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