Category: ethers-buliding-blocks. McDonald, KD; Bartlett, BM in [McDonald, Kori D.; Bartlett, Bart M.] Univ Michigan, Dept Chem, 930 North Univ Ave, Ann Arbor, MI 48109 USA published Photocatalytic primary alcohol oxidation on WO3 nanoplatelets in 2019, Cited 35. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.
With the aid of direct heating through microwave irradiation in non-aqueous media, nanocrystalline tungsten(vi) oxide is achievable in 30 minutes at 200 degrees C, faster and at a lower temperature than conventional synthesis methods. Forming in a platelet morphology, these particles are as small as 20 nm with a BET surface area of 37 m(2) g(-1) WO3. These nanoplatelets are active for the photocatalytic oxidation of the 1 degrees alcohols benzyl alcohol (rate constant, k of 2.6 x 10(-3) h(-1)) and 5-(hydroxymethyl)-2-furfural (k of 0.01 h(-1)) using 10 mg of WO3 with 2 mL of 0.250 M substrate in acetonitrile and a 150 mW cm(-2) 460 nm blue LED source. As expected, these rate constants are larger than those observed for commercially prepared, micron-sized WO3. XPS analysis shows that during catalysis, the concentration of W5+ on the surface increases, but the nanoplatelets are stable under these reaction conditions. The overall morphology and size of the particles are retained through the reactions. Moreover, the nanoplatelets are recyclable-showing no loss in activity for four reaction cycles.
Category: ethers-buliding-blocks. Welcome to talk about 103-50-4, If you have any questions, you can contact McDonald, KD; Bartlett, BM or send Email.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem