COA of Formula: C12H10O. Recently I am researching about C-H FUNCTIONALIZATION; COUPLING REACTIONS; ARYLSULFONIUM SALTS; SULFONIUM SALTS; ARYL HALIDES; BOND; ALKOXYLATION; ETHER; DIARYL; ACID, Saw an article supported by the Wuhan University of Technology; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21602165]; Chutian Scholar Program from Department of Education of Hubei Province; Hundred Talent Program of Hubei Province. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Ming, XX; Tian, ZY; Zhang, CP. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide
A mild and efficient protocol for O-arylation of alcohols and phenols (ROH) by triarylsulfonium triflates was developed under transition-metal-free conditions. Various alcohols, including primary, secondary and tertiary, and phenols bearing either electron-donating or electron-withdrawing groups on the aryl rings were smoothly converted to form the corresponding aromatic ethers in moderate to excellent yields. The reactions were conducted at 50 or 80 degrees C for 24 h in the presence of a certain base and showed good functional group tolerance. The base-mediated arylation with asymmetric triarylsulfonium salts could selectively transfer the aryl groups of sulfoniums to ROH, depending on their inherent electronic nature. The mechanistic studies revealed that the reaction might proceed through the nucleophilic attack of the in situ formed alkoxy or phenoxy anions at the aromatic carbon atoms of the C-S bonds of triarylsulfonium cations to furnish the target products.
COA of Formula: C12H10O. About Diphenyl oxide, If you have any questions, you can contact Ming, XX; Tian, ZY; Zhang, CP or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem