I found the field of Chemistry very interesting. Saw the article Highly Efficient and Selective N-Alkylation of Amines with Alcohols Catalyzed by in Situ Rehydrated Titanium Hydroxide published in 2020. Safety of Benzyl ether, Reprint Addresses Khodakov, AY (corresponding author), Univ Artois, Univ Lille, CNRS, Cent Lille,ENSCL,UCCS,UMR 8181, F-59000 Lille, France.; Ordomsky, VV (corresponding author), CNRS Solvay, UMI 3464, E2P2L, Shanghai 201108, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether
Catalytic N-alkylation of amines by alcohols to produce desired amines is an important catalytic reaction in industry. Various noble-metal-based homogeneous and heterogeneous catalysts have been reported for this process. The development of cheap non-noble-metal heterogeneous catalysts for the N-alkylation reaction would be highly desirable. Hereby, we propose the N-alkylation of amines by alcohols over a cheap and efficient heterogeneous catalyst-titanium hydroxide. This catalyst provides a selectivity higher than 90% to secondary amines for functionalized aromatic and aliphatic alcohols and amines with high catalytic activity and stability. Mild Bronsted acidity formed by the continuous rehydration of Lewis acidity excludes the side reactions and deactivation by adsorbed species. The mechanism of the reaction involves dehydration of alcohols to ethers with subsequent C-O bond cleavage by amine with the formation of secondary amine and recovery of alcohol.
Safety of Benzyl ether. Welcome to talk about 103-50-4, If you have any questions, you can contact Niu, F; Wang, QY; Yan, Z; Kusema, BT; Khodakov, AY; Ordomsky, VV or send Email.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem