An article Efficient hydrodeoxygenation of lignin-derived phenols and dimeric ethers with synergistic [Bmim]PF6-Ru/SBA-15 catalysis under acid free conditions WOS:000457794700017 published article about MODEL COMPOUNDS; IONIC LIQUIDS; SELECTIVE HYDRODEOXYGENATION; METAL NANOPARTICLES; HYDROGENATION; ALKYLATION; CONVERSION; ALKANES; CARBON; HYDROGENOLYSIS in [Yang, Shaoqi; Lu, Xingmei; Yao, Haoyu; Xin, Jiayu; Xu, Junli; Kang, Ying; Yang, Yongqing; Cai, Guangming; Zhang, Suojiang] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, Beijing 100190, Peoples R China; [Yang, Shaoqi; Lu, Xingmei; Zhang, Suojiang] Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China in 2019.0, Cited 52.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Name: Diphenyl oxide
Selective catalytic hydrotreatment of lignin-derived phenols and dimeric ethers into alkanes is crucial for utilization of lignin and its fragments. Herein, we developed an efficient catalytic system with well-dispersed metal nanoparticles supported on SBA-15 synergistic with an ionic liquid. The catalytic system could catalyze the hydrodeoxygenation (HDO) of various monomeric and dimeric lignin-derived phenols into the corresponding alkanes under acid free conditions. The synergistic [Bmim]PF6-Ru/SBA-15 (1-butyl-3-methylimidazolium hexafluorophosphate) catalysis exhibited the best HDO activity for ligninderived phenols and dimeric ethers with >99.0% conversion and maximum > 98.0% selectivity of the corresponding alkanes. The yield of cyclohexane from diphenyl ether was 97.7% with 100% conversion under 2 MPa H-2 at 130 degrees C for 6 h. The mechanism investigation confirmed that the Ru/SBA-15 catalyst and the anion of [Bmim] PF6 played crucial roles in the hydrogenation process and deoxidization process, respectively. The catalytic system was reused six times for HDO of diphenyl ether to test its stability.
Name: Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Yang, SQ; Lu, XM; Yao, HY; Xin, JY; Xu, JL; Kang, Y; Yang, YQ; Cai, GM; Zhang, SJ or send Email.
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