Computed Properties of C12H10O. Cole, JP; Chen, DF; Kudisch, M; Pearson, RM; Lim, CH; Miyake, GM in [Cole, Justin P.; Chen, Dian-Feng; Kudisch, Max; Pearson, Ryan M.; Miyake, Garret M.] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA; [Lim, Chern-Hooi] New Iridium Inc, Boulder, CO 80303 USA published Organocatalyzed Birch Reduction Driven by Visible Light in 2020.0, Cited 43.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
The Birch reduction is a powerful synthetic methodology that uses solvated electrons to convert inert arenes to 1,4-cyclohexadienes-valuable intermediates for building molecular complexity. Birch reductions traditionally employ alkali metals dissolved in ammonia to produce a solvated electron for the reduction of unactivated arenes such as benzene (E-red < -3.42 V vs SCE). Photoredox catalysts have been gaining popularity in highly reducing applications, but none have been reported to demonstrate reduction potentials powerful enough to reduce benzene. Here, we introduce benzo[ghi]perylene imides as new organic photoredox catalysts for Birch reductions performed at ambient temperature and driven by visible light from commercially available LEDs. Using low catalyst loadings (<1 mol percent), benzene and other functionalized arenes were selectively transformed to 1,4-cyclohexadienes in moderate to good yields in a completely metal-free reaction. Mechanistic studies support that this unprecedented visible-light-induced reactivity is enabled by the ability of the organic photoredox catalyst to harness the energy from two visible-light photons to affect a single, high-energy chemical transformation. Computed Properties of C12H10O. About Diphenyl oxide, If you have any questions, you can contact Cole, JP; Chen, DF; Kudisch, M; Pearson, RM; Lim, CH; Miyake, GM or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem