An article One-Pot Conversion of Lignin into Naphthenes Catalyzed by a Heterogeneous Rhenium Oxide-Modified Iridium Compound WOS:000515438100001 published article about C-O BONDS; TRANSFER HYDROGENOLYTIC CLEAVAGE; AROMATIC ETHER BONDS; BENZYL PHENYL ETHER; MODEL COMPOUNDS; RU CATALYST; METAL; HYDRODEOXYGENATION; EFFICIENT; ACID in [Li, Xinxin; Zhang, Bo; Pan, Xiaoli; Ren, Yujing; Wang, Hua; Li, Changzhi] Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China; [Li, Xinxin; Ji, Na] Tianjin Univ, Sch Environm Sci & Engn, Key Lab Biomass Derived Gas & Oil Chinese Petroch, Tianjin 300350, Peoples R China; [Ji, Jianwei] Shaanxi Sci Tech Univ, Shaanxi Key Lab Catalysis, Sch Chem & Environm Sci, 1 Dongyihuan Rd, Hanzhong 723001, Peoples R China; [Liu, Qiying] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China; [Liu, Qiying; Li, Changzhi] Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China in 2020.0, Cited 59.0. Computed Properties of C12H10O. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
The direct transformation of lignin into fuels and chemicals remains a huge challenge because of the recalcitrant and complicated structure of lignin. In this study, rhenium oxide-modified iridium supported on SiO2 (Ir-ReOx/SiO2) is employed for the one-pot conversion of various lignin model compounds and lignin feedstocks into naphthenes. Up to 100 % yield of cyclohexane from model compounds and 44.3 % yield of naphthenes from lignin feedstocks are achieved. 2 D HSQC NMR spectroscopy before and after the reaction confirms the activity of Ir-ReOx/SiO2 in the cleavage of the C-O bonds and hydrodeoxygenation of the depolymerized products. H-2 temperature-programmed reduction, temperature-programmed desorption of NH3, IR spectroscopy of pyridine adsorption, X-ray photoelectron spectroscopy, X-ray absorption fine structure analysis, and control experiments reveal that a synergistic effect between Ir and ReOx in Ir-ReOx/SiO2 plays a crucial role in the high performance; ReOx is mainly responsible for the cleavage of C-O bonds, whereas Ir is responsible for hydrodeoxygenation and saturation of the benzene rings. This methodology opens up an energy-efficient route for the direct conversion of lignin into valuable naphthenes.
Welcome to talk about 101-84-8, If you have any questions, you can contact Li, XX; Zhang, B; Pan, XL; Ji, JW; Ren, YJ; Wang, H; Ji, N; Liu, QY; Li, CZ or send Email.. Computed Properties of C12H10O
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,Ether | (C2H5)2O – PubChem