Ondrejkova, Alica; Lindroth, Rickard; Hilmersson, Goeran; Wallentin, Carl-Johan published the artcile< Utilizing a needle as a source of iron in synergistic dual photoredox catalytic generation of alkoxy radicals>, Related Products of 52244-70-9, the main research area is THF bromoketone preparation photoredox iron synergistic catalysis.
A visible-light mediated alkoxy radical generation is described, which allows for a structurally divergent oxidative C(sp3)-H bond functionalization. This protocol employs a photoredox/iron dual catalysis allowing for an unprecedented chemoselective single-step transformation of alc. derivatives giving access to two valuable sets of products, tetrahydrofurans and γ-bromoketones, under one set of conditions. Addition of iron, by slow corrosion of a needle, provides superior reaction efficiency as compared to various iron(III) complexes.
Chemical Communications (Cambridge, United Kingdom) published new progress about C-H bond activation. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Related Products of 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem