Zhang, Wu; Shu, Xiaomin; Huan, Leitao; Cheng, Buqing; Huo, Haohua published their research in Organic & Biomolecular Chemistry in 2021. The article was titled 《Enantioselective β-C(sp3)-H arylation of amides via synergistic nickel and photoredox catalysis》.Reference of 1-Bromo-3-methoxybenzene The article contains the following contents:
An enantioselective benzylic β-C(sp3)-H arylation of amides RC(O)CH2CH2Ar (R = Me, phenylaminyl, [3-(trifluoromethyl)phenyl]aminyl, Ph, etc.; Ar = Ph, 4-methoxyphenyl, 3-chlorophenyl, etc.) via synergistic nickel and photoredox catalysis is reported. The C-H bond is activated by a bromine-radical-mediated C-H cleavage. This mild yet straightforward protocol provides arylation products (S)-RC(O)CH2CH(R1)Ar (R1 = 4-(trifluoromethyl)phenyl, 4-cyanophenyl, 3-bromophenyl, 1-benzothiophen-5-yl, etc.) in up to 96% yield and with up to 95% ee. After reading the article, we found that the author used 1-Bromo-3-methoxybenzene(cas: 2398-37-0Reference of 1-Bromo-3-methoxybenzene)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) is a compound useful in organic synthesis and other chemical processes. It is an intermediate used for pharmaceuticals, perfumes and agrochemicals.Reference of 1-Bromo-3-methoxybenzene
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem